Thermoplastic resin sheets and formed articles
[Problem] It is intended to provide a formed article for food which has excellent antistatic properties and water repellency without impairing its original external appearance and mechanical properties thereof even in a deep-drawn part having a high drawing ratio at forming or even through high temperature forming. [Solution] A multi-layer sheet is prepared having a multi-layer configuration with two or more types of two or more layers, including a main layer which contains a thermoplastic resin, talc and white pigment, and a skin layer of an antistatic resin composition which contains at least one type of thermoplastic resin and an antistatic agent on an opposite side. By thermoforming the sheet including the resin composition, a formed article which has excellent antistatic properties and water repellency effective for preventing contamination and adhesion of soup powder can be obtained. The polymer antistatic agent desirably contains a fatty acid ester sulfonate salt as a main component, has a surface resistivity of 10 13 Ω/□ or less, and has a water droplet contact angle of 90° or more. The multi-layer sheet is desirably prepared by co-extrusion.
1. A thermoplastic resin sheet that is configured to form a deep-drawn formed article consisting of the thermoplastic resin sheet by thermoforming the thermoplastic resin sheet,
wherein the thermoplastic resin sheet consists of two layers, the two layers are a skin layer and a main layer,
the skin layer comprises:
a thermoplastic resin; and
an antistatic agent comprising 90% by weight or more and less than 100% by weight of a sulfonate salt,
the main layer comprises:
a thermoplastic resin; and
an inorganic additive having an average particle size in a range of 20 μm or less, a thickness of the thermoplastic resin sheet is in a range from 0.1 mm to 3.0 mm,
the thickness of the skin layer is in a range from 15 to 35 μm,
each of the thermoplastic resin in the skin layer and the thermoplastic resin in the main layer is a polyolefinic polymer, and
when the thermoplastic resin sheet is deep-drawn stretched by thermoforming, the inorganic additive contained in the main layer forms a projection shape on a surface of the skin layer so as to increase water repellency of the skin layer.
2. The thermoplastic resin sheet according to claim 1 , wherein a contact angle of a water droplet on the skin layer is in a range of 90° or more when the thermoplastic resin sheet is deep-drawn by the thermoforming.
3. The thermoplastic resin sheet according to claim 1 , wherein surface resistivity of the skin layer is in a range of 9×10 13 Ω or less.
4. A deep-drawn formed article consisting of a thermoplastic resin sheet,
wherein the deep-drawn formed article is obtained by thermoforming the thermoplastic resin sheet, and
wherein the thermoplastic resin sheet consists of two layers, the two layers being a skin layer and a main layer,
the skin layer comprises:
a thermoplastic resin; and
an antistatic agent comprising 90% by weight or more and less than 100% by weight of a sulfonate salt,
the main layer comprises:
a thermoplastic resin; and
an inorganic additive having an average particle size in a range of 20 μm or less, a thickness of the thermoplastic resin sheet is in a range from 0.1 mm to 3.0 mm,
a thickness of the skin layer is in a range from 15 to 35 μm,
each of the thermoplastic resin in the skin layer and the thermoplastic resin in the main layer is polyolefinic polymer, and
the inorganic additive contained in the main layer forms a projection shape on a surface of the skin layer so as to increase water repellency of the skin layer, the projection shape having been formed when the thermoplastic resin sheet is deep-drawn by the thermoforming.
5. The deep-drawn formed article according to claim 4 ,
wherein a contact angle of a water droplet on the skin layer after deep drawing by the thermoforming is in a range of 90° or more.
6. The deep-drawn article according to claim 4 , wherein the antistatic agent is present in the skin layer in an amount of 0.01 to 5.0 parts by weight per 100 parts by weight of the thermoplastic resin of the skin layer.
7. The deep-drawn article according to claim 4 , wherein the polyolefinic polymer is a polypropylene-based polymer.
8. The deep-drawn article according to claim 4 ,
wherein the polyolefinic polymer is at least one polymer selected from the group consisting of polypropylene; a binary or more block, random, or graft copolymer made from more than half weight of propylene and one or more monomers selected from the group consisting of α-olefins other than propylene, a vinyl ester, an aromatic vinyl monomer, and a vinylsilane; and combinations thereof.
9. The deep-drawn article according to claim 4 , wherein the sulfonate salt is a sodium sulfonate salt.
10. The deep-drawn article according to claim 4 , wherein a thickness of the main layer is in a range from 0.1 mm to 2.0 mm.