Luminescent rare earth element compound and dichroic phosphor composition containing same
The present invention relates to a luminescent rare earth compound and dichroism fluorescent composition thereof, and more particularly, the luminescent rare earth compound is a luminescent rare earth compound excited by shortwave UV (Ultra-Violet). The luminescent rare earth compound and/or products applied with the luminescent rare earth compound according to the present invention can emit strong red and green colors by being excited at 240-330 nm range of wavelengths, while not being excited at 360-380 nm range of wavelengths, and showing no colors under visible light. Furthermore, the compound may be variably utilized to printed materials and plastic mold products because of possessing high heat resistance, high light resistance and high dispersibility of medium light. In addition, compositions emitting respectively different colors at mutually different wavelength ranges can be provided by mixing the luminescent rare earth compound according to the present invention with other excited luminescent compounds.
1. A luminescent rare earth compound consisting of:
Eu 0.6 Y 0.4 (Benzoic acid) 3 , or
Eu 0.5 Y 0.5 (1,2,4,5-Benzene-tetracarboxylic acid) 0.75 .
2. The luminescent rare earth compound of claim 1 , wherein the compound is not excited at a wavelength of 360-380 nm range and is excited at a wavelength of 240-330 nm range.
3. The luminescent rare earth compound of claim 1 , wherein the compound emits red and green colors.
4. A dichroism fluorescent composition comprising:
a luminescent rare earth compound comprising Eu 0.6 Y 0.4 (Benzoic acid) 3 , Eu 0.2 Y 0.8 (1,3,5-Benzene-tricarboxylic acid) 1 , Eu 0.5 Y 0.5 (1,2,4,5-Benzene-tetracarboxylic acid) 0.75 , Eu(Pyridine-2-carboxylic acid) 3 , or Eu(Pyridine-4-carboxylic acid) 3 ; and
near ultraviolet excited rare earth compound having a structure of the following chemical formula II,
where, P and Q are rare earth metals independently selected from Ce, Nd, Sm, Eu, Gd, Tb, La and Y, and where R is alkaline earth metal selected from Ca (Calcium), Sr (strontium), and Ba (barium), and L 1, L 2, L 3, L 4 and L 5 are independently selected from hydrogen, C 1-8 aryl group, halogen group and C 1-8 alkoxy group, the a and b are respectively a real number greater than 0, and 0<a+b≤1.
5. The dichroism fluorescent composition of claim 4 , wherein the composition emits a red color when excited with light at 360-380 nm range wavelength, and emits red and green colors when excited with light at 240-330 nm range wavelength.
6. The dichroism fluorescent composition of claim 4 , wherein the composition further comprises at least one fluorescent substance selected from Red 620 (CAS No. 1417311-00-2), Yellow 565 (CAS No. 28683-92-3), Green 555 (CAS No. 1466444-84-7), Green 550 (CAS No. 1151-84-4), or Blue-green 510 (CAS No. 1461703-41-2).