IP Library › Granted Patent US 10,955,567
Granted Patent B2
US 10,955,567 · App. 15/771,163 · Granted Mar 23, 2021

Scintillating nanocomposites

Inventors: Aneta Wiatrowska (Wroclaw, PL); Herfried Karl Wieczorek (Aachen, DE); Cornelis Reinder Ronda (Aachen, DE); Wilhelmus Cornelis Keur (Weert, NL); Malgorzata Nachman (Stargard Szczecinski, PL)
Assignee: KONINKLIJKE PHILIPS N.V.
G01T1/2033C09K11/02C09K11/025C09K11/7721C09K11/7774G01T1/1606G01T1/203G21K4/00B82Y15/00B82Y20/00B82Y40/00
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Quick Facts
Patent No.
US 10,955,567
App. No.
15/771,163
Granted
Mar 23, 2021
Kind
B2
Abstract

An improved scintillator nanocomposite comprising nanoparticles with scintillating properties and a diameter between 10 and 50 nanometer and a first matrix material comprises is obtained by introducing the nanoparticles into a dispersing medium to form a stable suspension. The dispersing medium is a precursor to the first matrix material, which is cured to form the first matrix material.

Claims (33)

1. A method for producing a scintillator nanocomposite, the method comprising:

introducing nanoparticles into a first dispersing medium to form a stable suspension, wherein the first dispersing medium is a precursor for a first matrix material; and

curing the first dispersing medium to form the first matrix material,

wherein the scintillator nanocomposite comprises the nanoparticles with scintillating properties and a diameter between 10 and 50 nanometer and the first matrix material.

2. The method according to claim 1 , wherein the nanoparticles are garnet nanoparticles.

3. The method according to claim 1 , wherein the first matrix material is a polymeric material.

4. The method according to claim 1 , wherein the dispersing medium is a glycol.

5. The method according to claim 1 , wherein a second dispersing medium is mixed with the first dispersing medium prior to introducing the nanoparticles or to the stable suspension, wherein the second dispersing medium is a precursor for a second matrix material.

6. The method according to claim 5 , wherein the second matrix material is a polymeric material, preferably a polymeric material selected from the group of polyurethane, polyester, such as polybutylene terephthalate, unsaturated polyester resin, aromatic polyamide, aromatic polyimide, polystyrene or polysulfone.

7. The method according to claim 6 , wherein the curing results in a co-polymer of the first matrix material and the second matrix material.

8. The method according to claim 1 , wherein the curing is performed at elevated temperature, and/or at elevated pressure greater than 20 bar, and/or for at least 24 hours.

9. A scintillator nanocomposite comprising:

nanoparticles with scintillating properties and a diameter between 10 and 50 nanometer; and

a first matrix material; and

wherein the nanoparticles are introduced into a first dispersing medium to form a stable suspension; and

wherein the first matrix material is formed by curing the first dispersing medium.

10. The scintillator nanocomposite according to claim 9 , wherein the first matrix material is polyurethane.

11. A product comprising the scintillator nanocomposite according to claim 9 .

12. A method to produce a transparent scintillator comprising:

melting a nanocomposite obtained with a method comprising introducing the nanoparticles into a first dispersing medium to form a stable suspension, wherein the first dispersing medium is a precursor for the first matrix material;

curing the first dispersing medium to form the first matrix material; and

injection molding the molten nanocomposite; and

wherein the scintillator nanocomposite comprises the nanoparticles with scintillating properties and a diameter between 10 and 50 nanometer and the first matrix material.

13. A transparent scintillator obtainable by the method according to claim 12 .

14. A radiation detector comprising the transparent scintillator according to claim 13 .

15. An imaging system comprising the radiation detector according to claim 14 .

16. The method according to claim 2 , wherein the nanoparticles are Cerium-doped nanoparticles.

17. The method according to claim 2 , wherein the nanoparticles are chosen from the group of Y 3 Al 5 O 12 :Ce nanoparticles, (Lu,Gd) 3 Al 5 O 12 :Ce nanoparticles or (LGGAG:Ce) nanoparticles.

18. The method according to claim 3 , wherein the polymeric material comprises a polymeric material selected from the group of polyurethane, polyester, polybutylene terephthalate, unsaturated polyester resin, aromatic polyamide, aromatic polyimide, polystyrene or polysulfone.

19. The method according to claim 4 , wherein the glycol comprises a 1, 4 butanediol.

20. The method according to claim 8 ,

wherein the elevated temperature is between 220 degrees Celsius and 250 degrees Celsius; and/or

wherein the elevated pressure is about 40 bar.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 27, 2018
From: WIATROWSKA, ANETA; WIECZOREK, HERFRIED KARL; RONDA, CORNELIS REINDER; KEUR, WILHELMUS CORNELIS; NACHMAN, MALGORZATA
To: KONINKLIJKE PHILIPS N.V.
Reel/Frame 045650/0834 →
Priority Claims (1)
EP 15195392 · Nov 19, 2015 · regional
Continuity (1)
Related Publication 20180306933A1 · Oct 25, 2018