Method for purifying reclaimed polymers
A method for purifying a reclaimed polymer is disclosed. In one embodiment, the method involves obtaining reclaimed polymer, contacting the reclaimed polymer with a first fluid solvent to produce an extracted reclaimed polymer; then dissolving the extracted reclaimed polymer in a solvent to produce a first solution comprising polymer. The first solution is settled and then filtered. A purer polymer is separated from the resulting solution.
1. A method for purifying a reclaimed polymer comprising:
a. obtaining the reclaimed polymer wherein the reclaimed polymer is selected from the group consisting of post-consumer use polymers, post-industrial use polymers, and combinations thereof;
b. contacting the reclaimed polymer at a temperature from about 80° C. to about 280° C. and at a pressure from about 150 psig (1.03 MPa) to about 8,000 psig (55.16 MPa) with a first fluid solvent having a standard boiling point less than about 70° C., to produce an extracted reclaimed polymer;
c. dissolving the extracted reclaimed polymer in a solvent selected from the group consisting of the first fluid solvent, a second fluid solvent, and mixtures thereof, at a temperature from about 90° C. to about 280° C. and a pressure from about 200 psig (1.38 MPa) to about 9,000 psig (62.05 MPa) to produce a first solution comprising polymer, at least one dissolved contaminant, and at least one suspended contaminant;
d. settling the first solution comprising polymer, at least one dissolved contaminants, and at least one suspended contaminant at a temperature from about 90° C. to about 280° C. and at a pressure from about 200 psig (1.38 MPa) to about 9,000 psig (62.05 MPa) to produce a second solution comprising polymer, at least one dissolved contaminant, and less of the at least one suspended contaminant;
e. filtering the second solution at a temperature from about 90° C. to about 280° C. and at a pressure from about 200 psig (1.38 MPa) to about 9,000 psig (62.05 MPa) to produce a third solution comprising purer polymer, at least one dissolved contaminant, and even less of the at least one suspended contaminant; and
f. separating the purer polymer from the third solution; and
wherein the second fluid solvent has the same chemical composition or a different chemical composition as the first fluid solvent.
2. The method of claim 1 , wherein the purer polymer is separated from the third solution at a temperature from about 0° C. to about 280° C. and a pressure from about 0 psig (0 MPa) to 2,000 psig (13.79 MPa).
3. The method of claim 1 , wherein the reclaimed polymer is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 0.5%.
4. The method of claim 1 , wherein the reclaimed polymer is post-consumer recycle derived polymer.
5. The method of claim 1 , wherein the reclaimed polymer is polystyrene.
6. The method of claim 1 , wherein the reclaimed polymer is poly(dimethylsiloxane).
7. The method of claim 1 , wherein the reclaimed polymer is a polypropylene homopolymer or a primarily polypropylene copolymer.
8. The method of claim 1 , wherein the polymer is a polyethylene homopolymer or a primarily polyethylene copolymer.
9. The method of claim 1 , wherein the fluid solvent has a standard boiling point less than about 0° C. and greater than about −45° C. and a standard enthalpy change of vaporization of less than about +25 kJ/mol.
10. The method of claim 1 , wherein the fluid solvent is selected from the group consisting of olefinic hydrocarbons, aliphatic hydrocarbons, and mixtures thereof.
11. The method of claim 1 , wherein the aliphatic hydrocarbon is selected from the group consisting of C 1 -C 6 aliphatic hydrocarbons and mixtures thereof.
12. The method of claim 1 , wherein the aliphatic hydrocarbons and mixtures thereof is comprised of primarily C 4 aliphatic hydrocarbons.
13. The method of claim 1 , wherein the fluid solvent comprises C 4 liquefied petroleum gas.
14. The method of claim 13 , wherein the fluid solvent comprises n-butane, butane isomers, or mixtures thereof.
15. The method of claim 1 , wherein the fluid solvent comprises n-pentane, isomers of pentane, or mixtures thereof.
16. The method of claim 1 , wherein the temperature in the contacting, dissolving, settling and filtering steps is from about 110° C. to about 220° C.
17. The method of claim 1 , wherein the pressure in the contacting step is from about 400 psig (2.76 MPa) to about 2,400 psig (16.55 MPa).
18. The method of claim 1 , wherein the pressure in the contacting step is less than about 1,100 psig (7.58 MPa).
19. The method of claim 1 , wherein the pressure in the dissolving, settling, and filtering steps is from about 400 psig (2.76 MPa) to about 2,600 (17.93 MPa).
20. A method for purifying a reclaimed polymer comprising:
a. obtaining the reclaimed polymer wherein the reclaimed polymer is selected from the group consisting of post-consumer use polymers, post-industrial use polymers, and combinations thereof;
b. contacting the reclaimed polymer at a temperature from about 80° C. to about 280° C. and at a pressure from about 150 psig (1.03 MPa) to about 8,000 psig (55.16 MPa) with a first fluid solvent having a standard boiling point less than about 70° C., to produce an extracted reclaimed polymer;
c. dissolving the extracted reclaimed polymer in a solvent selected from the group consisting of the first fluid solvent, a second fluid solvent, and mixtures thereof, at a temperature from about 90° C. to about 280° C. and a pressure from about 200 psig (1.38 MPa) to about 9,000 psig (62.05 MPa) to produce a first solution comprising polymer, at least one dissolved contaminant, and at least one suspended contaminant;
d. settling the first solution comprising polymer, at least one dissolved contaminants, and at least one suspended contaminant at a temperature from about 90° C. to about 280° C. and at a pressure from about 200 psig (1.38 MPa) to about 9,000 psig (62.05 MPa) to produce a second solution comprising polymer, at least one dissolved contaminant, and less of the at least one suspended contaminant;
e. filtering the second solution at a temperature from about 90° C. to about 280° C. and at a pressure from about 200 psig (1.38 MPa) to about 9,000 psig (62.05 MPa) to produce a third solution comprising purer polymer, at least one dissolved contaminant, and even less of the at least one suspended contaminant; and
f. purifying by further filtering the third solution at a temperature from about 90° C. to about 280° C. and at a pressure from about 200 psig (1.38 MPa) to about 9,000 psig (62.05 MPa) by contacting the third solution with one or more solid media to produce a fourth solution comprising purer polymer; and
g. separating the purer polymer from the fourth solution; and
wherein the second fluid solvent has the same chemical composition or a different chemical composition as the first fluid solvent.