Bonding of substrates induced by ionizing radiation
A reactive polymer composition is provided, containing a (co)polymer that forms one or more reactive moities, either directly or indirectly, upon application of an ionizing radiation; and a multifunctional curing coagent, along with systems and methods for bonding substrates to one another using such a composition.
1. A system for bonding materials having different coefficients of thermal expansion, comprising:
a first substrate having at least one surface containing a first reactive polymer composition;
a second substrate, optionally having at least one surface containing a second reactive polymer composition;
wherein the first substrate and the second substrate are different from one another and have different coefficients of thermal expansion from one another, wherein the first reactive polymer composition and the second reactive polymer composition may be the same or different, and each comprises a (co)polymer that forms one or more reactive moieties selected from the group consisting of free-radicals, cations, anions, carbenes, and nitrenes, either directly or indirectly, upon application of an ionizing radiation and a multifunctional curing coagent to reduce oxygen inhibition, minimize or curb chain scission, or both, wherein the multifunctional curing coagent is a di-, tri-, or tetra-functional alcohol compound; and
a source of ionizing radiation.
2. The system of claim 1 , wherein the one or more reactive moieties are one or more free-radicals.
3. The system of claim 1 , wherein the alcohol compound is a tetra-functional alcohol.
4. The system of claim 1 , wherein the first reactive polymer composition comprises a (co)polymer formed from one or more monomers selected from the group consisting of acrylates, methacrylates, olefins, ethers, styrenes, fluoroolefins, esters, carbonates, urethanes, vinyl chlorides, vinyl chloride acetates, amides, imides, acetals, methylpentenes, sulfones, acrylics, styrene acrylics, and acrylonitriles.
5. A method for bonding materials having different coefficients of thermal expansion, comprising:
providing a first substrate and a second substrate to be bonded together, wherein the first and second substrates are different from one another and have different coefficients of thermal expansion from one another;
providing a first reactive polymer composition comprising a (co)polymer that forms one or more reactive moieties selected from the group consisting of free-radicals, cations, anions, carbenes, and nitrenes, either directly or indirectly, upon application of an ionizing radiation and a multifunctional curing coagent to reduce oxygen inhibition, minimize or curb chain scission, or both, wherein the multifunctional curing coagent is a di-, tri-, or tetra-functional alcohol compound, wherein the first reactive polymer composition is in contact with at least one of the first and second substrates;
placing the first and second substrates in close proximity to one another; and
applying the ionizing radiation, thus forming the one or more reactive moieties in the first reactive polymer composition which react to form a bond between the first and second substrates.
6. The method of claim 5 , wherein the one or more reactive moieties are one or more free-radicals.
7. The method of claim 5 , wherein the alcohol compound is a tetra-functional alcohol.
8. The method of claim 5 , wherein the first reactive polymer composition comprises a (co)polymer formed from one or more monomers selected from the group consisting of acrylates, methacrylates, olefins, ethers, styrenes, fluoroolefins, esters, carbonates, urethanes, vinyl chlorides, vinyl chloride acetates, amides, imides, acetals, methylpentenes, sulfones, acrylics, styrene acrylics, and acrylonitriles.
9. A method for bonding materials having different coefficients of thermal expansion, comprising:
providing a first substrate and a second substrate to be bonded together, wherein the first and second substrates are different from one another and have different coefficients of thermal expansion from one another;
providing a first reactive polymer composition comprising a (co)polymer that forms one or more reactive moieties selected from the group consisting of free-radicals, cations, anions, carbenes, and nitrenes, either directly or indirectly, upon application of an ionizing radiation and a multifunctional curing coagent to reduce oxygen inhibition, minimize or curb chain scission, or both, wherein the multifunctional curing coagent is a di-, tri-, or tetra-functional alcohol compound;
placing the first and second substrates in close proximity to one another and having the first reactive polymer composition therebetween; and
applying the ionizing radiation, thus forming the one or more reactive moieties in the first reactive polymer composition which react to form a bond between the first and second substrates.
10. The method of claim 9 , wherein the one or more reactive moieties are one or more free-radicals.
11. The method of claim 9 , wherein the alcohol compound is a tetra-functional alcohol.
12. The method of claim 9 , wherein the first reactive polymer composition comprises a (co)polymer formed from one or more monomers selected from the group consisting of acrylates, methacrylates, olefins, ethers, styrenes, fluoroolefins, esters, carbonates, urethanes, vinyl chlorides, vinyl chloride acetates, amides, imides, acetals, methylpentenes, sulfones, acrylics, styrene acrylics, and acrylonitriles.