Bio-based and hydrophilic polyurethane prepolymer and foam made therefrom
A bio-based polyurethane foam manufactured by a process that involves cleaning a bio-based polyoxyalkylene glycol polyol by a method comprising the steps of adding an adsorbent to the bio-based polyoxyalkylene glycol polyol to create a mixture in the ratio of 0.5% to 5.0% adsorbent to bio-based polyoxyalkylene glycol polyol by weight, stirring the mixture in a gaseous nitrogen environment, replacing the gaseous nitrogen environment with a gaseous carbon dioxide environment, and filtering the mixture to separate impurities from the mixture and create a cleaned bio-based polyoxyalkylene glycol polyol; then mixing the cleaned bio-based polyoxyalkylene glycol polyol with a polyfunctional isocyanate to create a bio-based polyurethane prepolymer; and then foaming the bio-based polyurethane prepolymer by admixing with an excess of water to make the bio-based polyurethane foam.
1. A process for manufacturing a crosslinked biobased hydrophilic foam comprising the steps of:
adding a metal silicate adsorbent to a bio-based polyoxyalkylene glycol polyol comprising residual sodium metals, residual potassium metals, and water to create a mixture comprising 0.5% to 5.0% by weight adsorbent;
stirring the mixture in a gaseous nitrogen environment;
replacing the gaseous nitrogen environment with a gaseous carbon dioxide environment;
filtering the mixture to separate impurities from the mixture and to create a cleaned bio-based polyoxyalkylene glycol polyol, wherein the filtering step comprises utilizing said metal silicate adsorbent to sequester residual sodium metals and residual potassium metals from the mixture below 15 ppm combined metals and sequester water from the mixture below 0.1% by weight, further wherein the combined metals are a sum of said residual sodium metals and said residual potassium metals;
pre-mixing the cleaned bio-based polyoxyalkylene glycol polyol with an isocyanate to create a prepolymer mixture with the cleaned biobased polyoxyalkylene glycol polyol constituting from 31.80 to 67.95 weight percent of the prepolymer mixture; and
admixing water with the prepolymer mixture to yield the crosslinked biobased hydrophilic foam.
2. The process of claim 1 , wherein said biobased polyoxyalkylene glycol polyol is a polyoxyalkylene glycol derived from a starting material that is substantially a biobased and sustainable raw material.
3. The process of claim 1 , wherein said biobased polyoxyalkylene glycol polyol is polymerized from 100% biobased ethylene oxide.
4. The process of claim 1 , wherein the cleaned bio-based polyoxyalkylene glycol polyol is capped with sufficient isocyanate to react all theoretically available hydroxyl functionalities of the cleaned bio-based polyoxyalkylene glycol polyol to create the polyurethane prepolymer that is thereafter admixed with water to create the hydrophilic foam.