Low alloy high strength thick-walled seamless steel pipe for oil country tubular goods
A low alloy high strength thick-walled seamless steel pipe for oil country tubular goods is provided having a wall thickness of 40 mm or more and a yield strength of 758 MPa or more, the steel pipe including a composition containing, in terms of mass %, C: 0.25 to 0.31%, Si: 0.01 to 0.35%, Mn: 0.55 to 0.70%, P: 0.010% or less, S: 0.001% or less, O: 0.0015% or less, Al: 0.015 to 0.040%, Cu: 0.02 to 0.09%, Cr: 0.8 to 1.5%, Mo: 0.9 to 1.6%, V: 0.04 to 0.10%, Nb: 0.005 to 0.05%, B: 0.0015 to 0.0030%, Ti: 0.005 to 0.020%, and N: 0.005% or less, and having Ti/N of 3.0 to 4.0, with the balance being Fe and inevitable impurities, wherein a cumulative frequency rate at a measurement point at which a Mo segregation degree by a predetermined expression is 1.5 or more is 1% or less.
1. A seamless steel pipe for oil country tubular goods having a wall thickness of 40 mm or more and a yield strength of 758 MPa or more, the steel pipe comprising a composition containing, in terms of mass %,
C: 0.25 to 0.31%,
Si: 0.01 to 0.35%,
Mn: 0.55 to 0.70%,
P: 0.010% or less,
S: 0.001% or less,
O: 0.0015% or less,
Al: 0.015 to 0.040%,
Cu: 0.02 to 0.09%,
Cr: 0.8 to 1.5%,
Mo: 0.9 to 1.6%,
V: 0.04 to 0.10%,
Nb: 0.005 to 0.05%,
B: 0.0015 to 0.0030%,
Ti: 0.005 to 0.020%,
N: 0.005% or less, and
Ca: 0.0005 to 0.0030%,
and having a value of a ratio of the Ti content to the N content (Ti/N) of 3.0 to 4.0,
with the balance being Fe and inevitable impurities,
wherein a cumulative frequency rate is 1% or less in view of measurement points at which a Mo segregation degree is 1.5 or more which is measured in an overall thickness of a longitudinal orthogonal cross section of the pipe, as defined by the following expression (A); and
the steel pipe has a value (σ 0.7 /σ 0.4 ), as a ratio of a stress at a strain of 0.7% to a stress at a strain of 0.4% in a stress-strain curve, of 1.02 or less:
Mo segregation degree=(EPMA Mo value)/(EPMA Mo ave.) (A)
wherein
EPMA means to Electron Probe Micro Analyzer;
the (EPMA Mo value) is a Mo concentration value (mass %) of an individual measurement point at the time of the EPMA quantitative planar analysis measurement; and
the (EPMA Mo ave.) is an average Mo concentration (mass %) of all of the measurement points at the time of the EPMA quantitative planar analysis measurement, and
wherein the seamless steel pipe has the number of oxide-based non-metallic inclusions in steel comprising of Ca and Al and having a maximum bulk size of 5 μm or more, whose composition ratio satisfies, in terms of mass %, the following equation (1), of 20 or less per 100 mm 2 :
(CaO)/(Al 2 O 3 )≥4.0 (1).
2. The seamless steel pipe for oil country tubular goods according to claim 1 , which further contains, in addition to the composition, one or more selected from, in terms of mass %,
W: 0.1 to 0.2%, and
Zr: 0.005 to 0.03%.