IP Library › Granted Patent US 10,978,358
Granted Patent B2
US 10,978,358 · App. 16/531,718 · Granted Apr 13, 2021

Processing system for a catalytic layer of a noble metal formed on a surface of a substrate

Inventors: Mitsuo Sano (Yokohama, JP); Keiichiro Matsuo (Yokohama, JP); Susumu Obata (Yokohama, JP); Kazuhito Higuchi (Yokohama, JP); Kazuo Shimokawa (Yokohama, JP)
Assignee: KABUSHIKI KAISHA TOSHIBA
H01L22/12G01N23/223H01L21/30604G01N2223/61
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Quick Facts
Patent No.
US 10,978,358
App. No.
16/531,718
Granted
Apr 13, 2021
Kind
B2
Abstract

According to one embodiment, in a processing system and determining method, a X-ray intensity of character X-rays generated by irradiating a catalytic layer of a noble metal formed on a surface of a substrate with X-rays is detected. In the processing system and the determining method, either the detected X-ray intensity or a parameter calculated using the X-ray intensity is obtained as a determination parameter. In the processing system and the determining method, based at least on the determination parameter, whether or not the catalytic layer has been formed into a state suitable for etching the surface of the substrate is determined.

Claims (38)

1. A processing system comprising one or more processing devices, the one or more processing devices being configured to:

detect an X-ray intensity of character X-rays that are generated by irradiating a catalytic layer of a noble metal formed on a surface of a substrate with X-rays;

obtain, as a first determination parameter, any one of the detected X-ray intensity and a parameter calculated using the X-ray intensity; and

determine, based at least on the first determination parameter, whether or not the catalytic layer has been formed into a state suitable for etching the surface of the substrate,

detect, using a laser microscope or a scanning electron microscope, a detection parameter in association with the catalytic layer;

obtain, as a second determination parameter, the detection parameter from the laser microscope or the scanning electron microscope or a parameter calculated using the detection parameter; and

determine, based on the second determination parameter in addition to the first determination parameter, whether or not the catalytic layer has been formed into a form suitable for the etching.

2. The processing system according to claim 1 , wherein the one or more processing devices are configured to:

calculate, from the detected X-ray intensity, a deposition amount of the noble metal per unit area in the catalytic layer; and

obtain, as the first determination parameter, the calculated deposition amount.

3. The processing system according to claim 1 , wherein the one or more processing devices are configured to determine, based on whether or not the first determination parameter is within a predetermined range, whether or not the catalytic layer is formed into a state suitable for the etching.

4. The processing system according to claim 1 , wherein the one or more processing devices are configured to determine, based on whether or not the second determination parameter is within a predetermined range, whether or not the catalytic layer has been formed into a form suitable for the etching.

5. The processing system according to claim 1 , wherein the one or more processing devices are configured to:

detect, as the detection parameter, using the laser microscope, a thickness of the catalytic layer; and

obtain, as the second determination parameter, the detected thickness of the catalytic layer.

6. The processing system according to claim 1 , wherein the one or more processing devices are configured to obtain, as the second determination parameter, a parameter calculated using both the X-ray intensity and the detection parameter from the laser microscope or the scanning electron microscope.

7. The processing system according to claim 6 , wherein the one or more processing devices are configured to:

detect, as the detection parameter, using the laser microscope, a thickness of the catalytic layer;

calculate, using both the X-ray intensity and the detected thickness of the catalytic layer, a density of the catalytic layer; and

obtain, as the second determination parameter, the calculated density of the catalytic layer.

8. A processing system comprising one or more processing devices, the one or more processing devices being configured to:

detect an X-ray intensity of character X-rays that are generated by irradiating a catalytic layer of a noble metal formed on a surface of a substrate with X-rays;

obtain, as a first determination parameter, any one of the detected X-ray intensity and a parameter calculated using the X-ray intensity;

determine, based at least on the first determination parameter, whether or not the catalytic layer has been formed into a state suitable for etching the surface of the substrate; and

perform, if it is determined that the catalytic layer has not been formed into a state suitable for the etching, at least one of: a notification that the catalytic layer is not in a suitable state and a change of conditions for forming the catalytic layer of the noble metal onto the substrate.

9. The processing system according to claim 8 , wherein the one or more processing devices are configured to:

detect, using a laser microscope or a scanning electron microscope, a detection parameter in association with the catalytic layer; and

obtain, as the first determination parameter, a parameter calculated using both the X-ray intensity and the detection parameter detected using the laser microscope or the scanning electron microscope.

10. The processing system according to claim 9 , wherein the one or more processing devices are configured to:

detect, as the detection parameter, using the laser microscope, a thickness of the catalytic layer;

calculate, using both the X-ray intensity and the detected thickness of the catalytic layer, a density of the catalytic layer; and

obtain, as the first determination parameter, the calculated density of the catalytic layer.

11. A processing system comprising one or more processing devices, the one or more processing devices being configured to:

detect an X-ray intensity of character X-rays that are generated by irradiating a catalytic layer of a noble metal formed on a surface of a substrate with X-rays;

calculate, from the detected X-ray intensity, a deposition amount of the noble metal per unit area in the catalytic layer;

detect a thickness of the catalytic layer by using a laser microscope;

calculate, using both the calculated deposition amount and the detected thickness of the catalytic layer, a density of the catalytic layer; and

determine, based at least on the calculated density, whether or not the catalytic layer has been formed into a state suitable for etching the surface of the substrate.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 5, 2019
From: SANO, MITSUO; MATSUO, KEIICHIRO; OBATA, SUSUMU; HIGUCHI, KAZUHITO; SHIMOKAWA, KAZUO
To: KABUSHIKI KAISHA TOSHIBA
Reel/Frame 049959/0749 →
Priority Claims (1)
JP JP2018-150241 · Aug 9, 2018 · national
Continuity (1)
Related Publication 20200051873A1 · Feb 13, 2020