Absorbent articles with biocompostable properties

1. A disposable biocompostable absorbent sanitary article, comprising:

a fluid-permeable top layer;

a fluid-resistant back layer; and

an absorbent core;

wherein the fluid-permeable top layer is chemically and/or physically attached to the absorbent core, and wherein the absorbent core is chemically and/or physically attached to the fluid-resistant back layer;

wherein the absorbent core is positioned between the fluid-permeable top layer and the fluid-resistant back layer;

wherein the absorbent core includes a super absorbent polymer (SAP);

wherein the SAP includes an interior and surface crosslinked, charge modified starch-based biopolymer;

wherein the interior and surface crosslinked, charge modified starch-based biopolymer is biocompostable;

wherein the biobased carbon content of the interior and surface crosslinked, charge modified starch-based biopolymer is at least approximately 50%;

wherein the interior and surface crosslinked, charge modified starch-based biopolymer is not a graft polymer; and

wherein the interior and surface crosslinked, charge modified starch-based biopolymer includes at least one negatively charged moiety.

2. The article of claim 1 , wherein the SAP does not include a synthetic polymer.

3. The article of claim 1 , wherein the biobased carbon content of the interior and surface crosslinked, charge modified starch-based biopolymer is between approximately 84% and approximately 90%.

4. The article of claim 1 , wherein the SAP is further integrated into the fluid-permeable top layer.

5. The article of claim 1 , wherein the fluid-permeable top layer, the fluid-resistant back layer, and/or the absorbent core are biocompostable.

6. The article of claim 1 , wherein the interior and surface crosslinked, charge modified starch-based biopolymer has an absorbency under load (AUL) at 0.7 psi of between 5 g/g and 10 g/g in a saline solution.

7. The article of claim 1 , wherein the interior and surface crosslinked, charge modified starch-based biopolymer exhibits no cytotoxicity and is not a dermal irritant.

8. The article of claim 1 , wherein at least 85% of the particle sizes of the interior and surface crosslinked, charge modified starch-based biopolymer are between 100 and 650 micrometers.

9. The article of claim 1 , wherein the biobased carbon content of the interior and surface crosslinked, charge modified starch-based biopolymer is at least about 80%.

10. The article of claim 1 , further comprising a second SAP, wherein the second SAP is non-biocompostable, wherein the article includes a blend of the second SAP and the interior and surface crosslinked, charge modified starch-based biopolymer, and wherein between approximately 15% and approximately 25% of the blend is the interior and surface crosslinked, charge modified starch-based biopolymer.

11. The article of claim 10 , wherein the article has an acquisition time under load (ATUL) of between 60 seconds and 80 seconds for a first dose of 80 milliliters of 0.9% wt saline, an ATUL of between 85 and 105 seconds for a second dose of 80 milliliters of 0.9% wt saline, and an ATUL of between 155 and 175 seconds for a third dose of 80 milliliters of 0.9% wt saline, thereby yielding a first average acquisition rate of between 1.000 milliliter/second and 1.333 milliliters/second, a second average acquisition rate of between 0.7619 milliliters/second and 0.9411 milliliters/second, and a third average acquisition rate of between 0.4571 milliliters/second and 0.5161 milliliters/second.

12. The article of claim 1 , wherein the surface crosslinks of the interior and surface crosslinked, charge modified starch-based biopolymer are created through coating an interior crosslinked, charge modified starch-based biopolymer with one or more crosslinkers and thermally treating the coated interior crosslinked, charge modified starch-based biopolymer.

13. The article of claim 1 , wherein the interior and surface crosslinked, charge modified starch-based biopolymer is synthesized by producing a starch-based biopolymer through reactive extrusion using a charge modifying agent and a plasticizer, performing interior crosslinking on the starch-based biopolymer, coating the interior crosslinked starch-based biopolymer with a surface crosslinking agent, and thermally treating the interior crosslinked starch-based biopolymer to create surface crosslinks on the interior crosslinked, charge modified starch-based biopolymer.

14. The article of claim 1 , wherein epichlorohydrin is not used as a crosslinker during synthesis of the interior and surface crosslinked, charge modified starch-based biopolymer.

15. A disposable biocompostable absorbent sanitary article, comprising:

a fluid-permeable top layer;

a fluid-resistant back layer; and

an absorbent core;

wherein the fluid-permeable top layer is chemically and/or physically attached to the fluid-resistant back layer;

wherein the absorbent core is positioned between the fluid-permeable top layer and the fluid-resistant back layer;

wherein the absorbent core includes a super absorbent polymer (SAP) and absorbent fiber;

wherein the SAP includes an interior and surface crosslinked, charge modified starch-based modified biopolymer;

wherein the amylopectin content of the interior and surface crosslinked, charge modified starch-based biopolymer is less than about 80% w/w;

wherein the interior and surface crosslinked, charge modified starch-based biopolymer is not a graft polymer;

wherein the interior and surface crosslinked, charge modified starch-based biopolymer includes at least one negatively charged moiety; and

wherein the SAP further includes a second SAP, wherein the second SAP is non-biocompostable, wherein the article includes a blend of the second SAP and the interior and surface crosslinked, charge modified starch-based biopolymer, and wherein between approximately 15% and approximately 40% of the blend is the surface crosslinked, charge modified starch-based biopolymer.

16. The article of claim 15 , further comprising at least an intermediate layer, wherein the intermediate layer does not include the SAP.

17. The article of claim 15 , wherein the interior and surface crosslinked, charge modified starch-based biopolymer is biocompostable such that the SAP is operable to exhibit at least 90% degradation within 180 days when compared to analytical grade cellulose in a test directed by ASTM D5338 or an equivalent biodegradation test.

18. The article of claim 15 , further comprising at least one adhesive between layers of the biocompostable absorbent sanitary article, and/or further comprising an external adhesive, wherein the at least one adhesive and/or the external adhesive are biocompostable such that the at least one adhesive and/or the external adhesive is operable to exhibit at least 90% degradation within 180 days relative to an analytical grade cellulose control.

19. The article of claim 15 , wherein the absorbent core is folded at least once such that the absorbent core forms a central longitudinal.

20. The article of claim 15 , wherein an alcohol is not used in a charge modification step of an extrusion process in making the interior and surface crosslinked, charge modified starch-based biopolymer.

21. The article of claim 15 , wherein biobased carbon content of the interior and surface crosslinked, charge modified starch-based biopolymer is at least 80%.

22. The article of claim 15 , wherein the interior and surface crosslinked, charge modified starch-based modified biopolymer has a free swell capacity (FSC) of at least 25 g/g in a 0.9% saline solution, a centrifuge retention capacity (CRC) of at least about 16 g/g in a 0.9% saline solution, and an absorbency under load (AUL) at 0.7 psi of at least about 6 g/g in a 0.9% saline solution.

23. The article of claim 1 , wherein the interior and surface crosslinked, charge modified starch-based biopolymer has a charge density of at least 6 meq/g.

24. The article of claim 15 , wherein between approximately 15% and approximately 25% of the blend is the interior and surface crosslinked, charge modified starch-based biopolymer.

25. A disposable biocompostable absorbent sanitary article, comprising:

a fluid-permeable topsheet;

a fluid-resistant backsheet;

an acquisition distribution layer; and

an absorbent core;

wherein the fluid-permeable topsheet is chemically and/or physically attached to the absorbent core, and wherein the absorbent core is chemically and/or physically attached to the fluid-resistant backsheet;

wherein the absorbent core is positioned between the fluid-permeable topsheet and the fluid-resistant backsheet;

wherein the absorbent core includes at least cellulose fluff pulp and an integrated super absorbent polymer (SAP);

wherein the SAP includes an interior and surface crosslinked, charge modified starch-based biopolymer;

wherein the interior and surface crosslinked, charge modified starch-based biopolymer is biocompostable such that the interior and surface crosslinked, charge modified starch-based biopolymer is operable to exhibit at least 90% degradation within 180 days when compared to a cellulose control;

wherein the SAP further includes a second SAP, wherein the second SAP is non-biocompostable, wherein the article includes a blend of the second SAP and the interior and surface crosslinked, charge modified starch-based biopolymer, wherein between approximately 15% and approximately 50% of the blend is the surface crosslinked, charge modified starch-based biopolymer;

wherein the surface crosslinks on the interior and surface crosslinked, charge modified starch-based biopolymer are created through coating an interior crosslinked starch-based biopolymer with one or more crosslinkers and thermally treating the coated interior crosslinked starch-based biopolymer; and

wherein the interior and surface crosslinked, charge modified starch-based biopolymer includes at least one negatively charged moiety.

26. A disposable biocompostable absorbent sanitary article, comprising:

a fluid-permeable top layer;

a fluid-resistant back layer; and

an absorbent core including a super absorbent polymer (SAP);

wherein the fluid-permeable top layer is chemically and/or physically attached to the absorbent core, wherein the absorbent core is chemically and/or physically attached to the fluid-resistant back layer;

wherein the absorbent core is positioned between the fluid-permeable top layer and the fluid-resistant back layer;

wherein the SAP includes an interior and surface crosslinked, charge modified starch-based biopolymer and a second SAP, wherein the second SAP is non-biocompostable and is physically blended with the interior and surface crosslinked, charge-modified starch-based biopolymer to create a blend of the interior and surface crosslinked, charge modified starch-based biopolymer and the second SAP;

wherein the interior and surface crosslinked, charge modified starch-based biopolymer is biocompostable such that the interior and surface crosslinked, charge modified starch-based biopolymer is operable to exhibit at least 90% degradation within 180 days when compared to a cellulose control; and

wherein the article has an acquisition time under load (ATUL) of between 60 seconds and 80 seconds for a first dose of 80 milliliters of 0.9% wt saline, an ATUL of between 85 and 105 seconds for a second dose of 80 milliliters of 0.9% wt saline, and an ATUL of between 155 and 205 seconds for a third dose of 80 milliliters of 0.9% wt saline, thereby yielding a first average acquisition rate of between 1.000 milliliter/second and 1.333 milliliters/second, a second average acquisition rate of between 0.7619 milliliters/second and 0.9411 milliliters/second, and a third average acquisition rate of between 0.3902 milliliters/second and 0.5161 milliliters/second.

27. The article of claim 26 , wherein the absorbent core is constructed without fluff.

28. The article of claim 26 , wherein the article includes an airlaid core.

29. The article of claim 26 , wherein the interior and surface crosslinked, charge modified starch-based biopolymer has a free swell capacity (FSC) of at least about 13 g/g in defibrinated sheep's blood or a centrifuge retention capacity (CRC) of at least about 12 g/g in defibrinated sheep's blood.

30. The article of claim 26 , wherein between approximately 25% and approximately 50% of the blend is the interior and surface crosslinked, charge-modified starch-based biopolymer.