Compound having isocyanuric skeleton and composition in which said compound is included
The invention aims to provide a novel compound to be suitably used for antifouling agents. The compound of the invention is represented by the following formula (1): wherein R 1 is a monovalent organic group containing a polyether chain; X 1 and X 2 are each individually a monovalent group; and the polyether chain is a chain represented by the following formula: —(OC 6 F 12 ) m11 —(OC 5 F 10 ) m12 —(OC 4 F 8 ) m13 —(OC 3 X 10 6 ) m14 —(OC 2 F 4 ) m15 —(OCF 2 ) m16 —, wherein m11, m12, m13, m14, m15, and m16 are each individually an integer of 0 or 1 or greater; X 10 s are each individually H, F, or Cl; and the repeating units are present in any order.
1. A compound represented by the following formula (1):
wherein R 1 is a monovalent organic group containing a polyether chain other than those containing a urethane bond; X 1 is a monovalent Si-containing crosslinkable group and X 2 is a monovalent group; and the polyether chain is at least one chain selected from the group consisting of:
a chain represented by the following formula:
—(OCF 2 CF 2 CX 11 2 ) n11 (OCF 2 CF(CF 3 )) n12 (OCF 2 CF 2 ) n13 (OCF 2 ) n14 (OC 4 F 8 ) n15 —
wherein n11, n12, n13, n14, and n15 are each individually an integer of 0 or 1 or greater; X 11 s are each individually H, F, or Cl; and the repeating units are present in any order; and
a chain represented by the following formula:
—(OC 2 F 4 —R 11 ) f —
wherein R 11 is a group selected from OC 2 F 4 , OC 3 F 6 , and OC 4 F 8 ; and f is an integer of 2 to 100.
2. The compound according to claim 1 ,
wherein X 2 is a monovalent organic group containing a polyether chain, and the polyether chain of X 2 is at least one chain selected from the group consisting of:
a chain represented by the following formula:
—(OCF 2 CF 2 CX 11 2 ) n11 (OCF 2 CF(CF 3 )) n12 (OCF 2 CF 2 ) n13 (OCF 2 ) n14 (OC 4 F 8 ) n15 —
wherein n11, n12, n13, n14, and n15 are each individually an integer of 0 or 1 or greater; X 11 s are each individually H, F, or Cl; and the repeating units are present in any order; and
a chain represented by the following formula:
—(OC 2 F 4 —R 11 ) f —
wherein R 11 is a group selected from OC 2 F 4 , OC 3 F 6 , and OC 4 F 8 ; and f is an integer of 2 to 100.
3. The compound according to claim 1 ,
wherein X 2 is a monovalent crosslinkable group.
4. The compound according to claim 1 ,
wherein X 1 contains a polyether chain, and the polyether chain of X 1 is at least one chain selected from the group consisting of:
a chain represented by the following formula:
—(OCF 2 CF 2 CX 11 2 ) n11 (OCF 2 CF(CF 3 )) n12 (OCF 2 CF 2 ) n13 (OCF 2 ) n14 (OC 4 F 8 ) n15 —
wherein n11, n12, n13, n14, and n15 are each individually an integer of 0 or 1 or greater; X 11 s are each individually H, F, or Cl; and the repeating units are present in any order; and
a chain represented by the following formula:
—(OC 2 F 4 —R 11 ) f —
wherein R 11 is a group selected from OC 2 F 4 , OC 3 F 6 , and OC 4 F 8 ; and f is an integer of 2 to 100.
5. The compound according to claim 1 ,
wherein X 2 is a monovalent crosslinkable group containing a polyether chain, and the polyether chain of X 2 is at least one chain selected from the group consisting of:
a chain represented by the following formula:
—(OCF 2 CF 2 CX 11 2 ) n11 (OCF 2 CF(CF 3 )) n12 (OCF 2 CF 2 ) n13 (OCF 2 ) n14 (OC 4 F 8 ) n15 —
wherein n11, n12, n13, n14, and n15 are each individually an integer of 0 or 1 or greater; X 11 s are each individually H, F, or Cl; and the repeating units are present in any order; and
a chain represented by the following formula:
—(OC 2 F 4 —R 11 ) f —
wherein R 11 is a group selected from OC 2 F 4 , OC 3 F 6 , and OC 4 F 8 ; and f is an integer of 2 to 100.
6. The compound according to claim 1 ,
wherein X 1 contains a polyether chain and X 2 is a monovalent crosslinkable group containing a polyether chain, and the polyether chain of both X 1 and X 2 is at least one chain selected from the group consisting of:
a chain represented by the following formula:
—(OCF 2 CF 2 CX 11 2 ) n11 (OCF 2 CF(CF 3 )) n12 (OCF 2 CF 2 ) n13 (OCF 2 ) n14 (OC 4 F 8 ) n15 —
wherein n11, n12, n13, n14, and n15 are each individually an integer of 0 or 1 or greater; X 11 s are each individually H, F, or Cl; and the repeating units are present in any order; and
a chain represented by the following formula:
—(OC 2 F 4 —R 11 ) f —
wherein R 11 is a group selected from OC 2 F 4 , OC 3 F 6 , and OC 4 F 8 ; and f is an integer of 2 to 100.
7. The compound according to claim 1 ,
wherein X 2 is at least one selected from the group consisting of H, an alkyl group, a halogenated alkyl group, an alkyl ester group, a halogenated alkyl ester group, an alkyl ether group, a halogenated alkyl ether group, an alkyl amide group, a halogenated alkyl amide group, a uril group, a halogenated uril group, a urea group, a halogenated urea group, —OCOOR j , wherein R j is an alkyl group or a halogenated alkyl group, —CONR k COR l , wherein R k and R l are each individually H, an alkyl group, or a halogenated alkyl group, a glycan-containing group, an alkylene polyether group, an arene group, a halogenated arene group, a heterocycle-containing group, an aryl group, a halogenated aryl group, a silicone residue other than those containing a reactive group, and a silsesquioxane residue other than those containing a reactive group.