Method for producing high-strength galvanized steel sheet
A method for producing a high-strength galvanized steel sheet having excellent fatigue resistance properties. The method includes an oxidation processing in which a steel sheet is heated at a temperature of 400 to 750° C. in an atmosphere having an O 2 concentration of 1000 ppm by volume or more and a H 2 O concentration of 1000 ppm by volume or more, and the steel sheet is heated at a temperature of 600 to 850° C. in an atmosphere having an O 2 concentration of less than 1000 ppm by volume and a H 2 O concentration of 1000 ppm by volume or more. The method also includes reduction-annealing in which the steel sheet is heated at a heating rate of 0.1° C./sec or more to a temperature of 650 to 900° C. in an atmosphere having a H 2 concentration of 5 to 30 vol % and a H 2 O concentration of 10 to 1000 ppm by volume.
1. A method for producing a high-strength galvanized steel sheet, the method comprising:
obtaining a steel sheet having a chemical composition including:
C: 0.3% or less, by mass %,
Si: 0.1 to 2.5%, by mass %,
Mn: 0.5 to 3.0%, by mass %,
P: 0.100% or less, by mass %,
S: 0.0100% or less, by mass %, and
Fe and incidental impurities;
performing oxidation processing on the steel sheet;
after the oxidation processing, performing reduction-annealing on the steel sheet; and
after the reduction-annealing, performing hot-dip galvanizing processing on the steel sheet,
wherein:
the oxidation processing is performed in such a manner that,
in a first stage, the steel sheet is heated at a temperature of 400 to 750° C. in an atmosphere having an O 2 concentration of 1000 ppm by volume or more and a H 2 O concentration of 1000 ppm by volume or more, and,
in a second stage, the steel sheet is heated at a temperature of 600 to 850° C. in an atmosphere having an O 2 concentration of less than 1000 ppm by volume and a H 2 O concentration of 1000 ppm by volume or more, and
the reduction-annealing is performed in such a manner that,
in a heating zone, the steel sheet is heated at a heating rate of 0.1° C./sec or more to a temperature of 650 to 900° C. in an atmosphere having a H 2 concentration of 5 to 30 vol % and a H 2 O concentration of 10 to 600 ppm by volume with a balance of N 2 and incidental impurities, and thereafter,
in a soaking zone, the steel sheet is soaked and held for 10 to 300 seconds with a temperature variation in the soaking zone of ±20° C. or less in an atmosphere having a H 2 concentration of 5 to 30 vol % and a H 2 O concentration of 700 to 5000 ppm by volume with a balance of N 2 and incidental impurities.
2. The method for producing a high-strength galvanized steel sheet according to claim 1 , wherein the heating rate is not more than 1.5° C./sec.
3. The method for producing a high-strength galvanized steel sheet according to claim 1 , wherein the chemical composition includes Mn: 2.3 to 3.0%, by mass %.
4. The method for producing a high-strength galvanized steel sheet according to claim 1 , wherein the chemical composition of the steel sheet further includes at least one of:
Al: 0.01 to 0.1%, by mass %,
Mo: 0.05 to 1.0%, by mass %,
Nb: 0.005 to 0.05%, by mass %,
Ti: 0.005 to 0.05%, by mass %,
Cu: 0.05 to 1.0%, by mass %,
Ni: 0.05 to 1.0%, by mass %,
Cr: 0.01 to 0.8%, by mass %,
B: 0.0005 to 0.005%, by mass %,
Sb: 0.001 to 0.10%, by mass %, and
Sn: 0.001 to 0.10%, by mass %.
5. The method for producing a high-strength galvanized steel sheet according to claim 1 , wherein the H 2 O concentration in the heating zone is 10 ppm by volume or more and less than 500 ppm by volume, and the H 2 O concentration in the soaking zone is more than 1000 ppm by volume and 5000 ppm by volume or less.
6. The method for producing a high-strength galvanized steel sheet according to claim 5 , wherein the chemical composition of the steel sheet further includes at least one of:
Al: 0.01 to 0.1%, by mass %,
Mo: 0.05 to 1.0%, by mass %,
Nb: 0.005 to 0.05%, by mass %,
Ti: 0.005 to 0.05%, by mass %,
Cu: 0.05 to 1.0%, by mass %,
Ni: 0.05 to 1.0%, by mass %,
Cr: 0.01 to 0.8%, by mass %,
B: 0.0005 to 0.005%, by mass %,
Sb: 0.001 to 0.10%, by mass %, and
Sn: 0.001 to 0.10%, by mass %.
7. The method for producing a high-strength galvanized steel sheet according to claim 1 , wherein the oxidation processing is performed in a direct fired furnace (DFF) or a non-oxidation furnace (NOF), and an air ratio in the first stage is 1.0 or more and less than 1.3 and an air ratio in the second stage is 0.7 or more and less than 0.9.
8. The method for producing a high-strength galvanized steel sheet according to claim 7 , wherein the chemical composition of the steel sheet further includes at least one of:
Al: 0.01 to 0.1%, by mass %,
Mo: 0.05 to 1.0%, by mass %,
Nb: 0.005 to 0.05%, by mass %,
Ti: 0.005 to 0.05%, by mass %,
Cu: 0.05 to 1.0%, by mass %,
Ni: 0.05 to 1.0%, by mass %,
Cr: 0.01 to 0.8%, by mass %,
B: 0.0005 to 0.005%, by mass %,
Sb: 0.001 to 0.10%, by mass %, and
Sn: 0.001 to 0.10%, by mass %.
9. The method for producing a high-strength galvanized steel sheet according to claim 1 , wherein, in the soaking zone for the reduction-annealing, a difference in the H 2 O concentration between upper and lower sections is 2000 ppm by volume or less.
10. The method for producing a high-strength galvanized steel sheet according to claim 9 , wherein the chemical composition of the steel sheet further includes at least one of:
Al: 0.01 to 0.1%, by mass %,
Mo: 0.05 to 1.0%, by mass %,
Nb: 0.005 to 0.05%, by mass %,
Ti: 0.005 to 0.05%, by mass %,
Cu: 0.05 to 1.0%, by mass %,
Ni: 0.05 to 1.0%, by mass %,
Cr: 0.01 to 0.8%, by mass %,
B: 0.0005 to 0.005%, by mass %,
Sb: 0.001 to 0.10%, by mass %, and
Sn: 0.001 to 0.10%, by mass %.
11. The method for producing a high-strength galvanized steel sheet according to claim 1 , wherein the hot-dip galvanizing processing is performed in a hot-dip galvanizing bath having a chemical composition containing an effective Al concentration in the bath of 0.095 to 0.175 mass %, with a balance of Zn and incidental impurities.
12. The method for producing a high-strength galvanized steel sheet according to claim 11 , wherein the chemical composition of the steel sheet further includes at least one of:
Al: 0.01 to 0.1%, by mass %,
Mo: 0.05 to 1.0%, by mass %,
Nb: 0.005 to 0.05%, by mass %,
Ti: 0.005 to 0.05%, by mass %,
Cu: 0.05 to 1.0%, by mass %,
Ni: 0.05 to 1.0%, by mass %,
Cr: 0.01 to 0.8%, by mass %,
B: 0.0005 to 0.005%, by mass %,
Sb: 0.001 to 0.10%, by mass %, and
Sn: 0.001 to 0.10%, by mass %.
13. The method for producing a high-strength galvanized steel sheet according to claim 1 ,
wherein the hot-dip galvanizing processing is performed in a hot-dip galvanizing bath having a chemical composition containing an effective Al concentration in the bath of 0.095 to 0.115 mass %, with a balance of Zn and incidental impurities, and
thereafter alloying processing is performed for 10 to 60 seconds at a temperature T (° C.), which satisfies the following formula:
−50 log([H 2 O])+650≤ T≤− 40 log([H 2 O])+680
where [H 2 O] represents a H 2 O concentration (ppm by volume) in the soaking zone during the reduction-annealing.
14. The method for producing a high-strength galvanized steel sheet according to claim 13 , wherein the chemical composition of the steel sheet further includes at least one of:
Al: 0.01 to 0.1%, by mass %,
Mo: 0.05 to 1.0%, by mass %,
Nb: 0.005 to 0.05%, by mass %,
Ti: 0.005 to 0.05%, by mass %,
Cu: 0.05 to 1.0%, by mass %,
Ni: 0.05 to 1.0%, by mass %,
Cr: 0.01 to 0.8%, by mass %,
B: 0.0005 to 0.005%, by mass %,
Sb: 0.001 to 0.10%, by mass %, and
Sn: 0.001 to 0.10%, by mass %.