Structural lithium-ion batteries with carbon fiber electrodes
Described are structural electrode and structural batteries having high energy storage and high strength characteristics and methods of making the structural electrodes and structural batteries. The structural batteries provided can include a liquid electrolyte and carbon fiber-reinforced polymer electrodes comprising metallic tabs. The structural electrodes and structural batteries provided can be molded into a shape of a function component of a device such as ground vehicle or an aerial vehicle.
1. A structural battery for a device comprising:
one or more carbon fiber-reinforced polymer electrodes comprising two or more carbon fiber sheets, one or more metallic tabs, and a polymer, and
a liquid electrolyte,
wherein the structural battery is molded into a shape of a functional component of a device.
2. The structural battery of claim 1 , wherein at least a portion of the shape of the functional component comprises an exterior surface of the device.
3. The structural battery of claim 2 , wherein the exterior surface of the device is functional.
4. The structural battery of claim 2 , wherein the exterior surface is configured to increase the aerodynamic performance of the device.
5. The structural battery of claim 1 , wherein the device is a ground vehicle or an aerial vehicle.
6. The structural battery of claim 1 , wherein the functional component comprises one or more of a component of: a wing, a boom, a body, a chassis, or a door of a device.
7. The structural battery of claim 1 , further comprising a surface coating on one or more surfaces of the one or more carbon fiber-reinforced polymer electrodes.
8. The structural battery of claim 7 , wherein the surface coating comprises an active material comprising one or more of graphite, silicon, mesoporous carbon microbeads, lithium titanate, lithium cobalt oxide, lithium nickel-manganese-cobalt oxide, or lithium iron phosphate.
9. The structural battery of claim 1 , further comprising one or more separators between two or more electrodes of the structural battery.
10. The structural battery of claim 1 , wherein the structural battery is a single-sided battery comprising layers in the order of a carbon fiber-reinforced anode, a separator, and a cathode coating on a layer of aluminum.
11. The structural battery of claim 1 , wherein the structural battery is a double-sided battery comprising layers in the order of a carbon fiber-reinforced anode, a separator, a double-sided cathode coating, a separator, and a carbon fiber-reinforced anode.
12. The structural battery of claim 1 , wherein the liquid electrolyte comprises one or more of lithium hexafluorophosphate, lithium tetrafluoroborate, lithium perchlorate, lithium bis(trifluoromethylsulfonyl)imide, lithium trifluoromethanesulfonate, ethylene carbonate, ethyl methyl carbonate, propylene carbonate, dimethyl carbonate, or diethyl carbonate.
13. The structural battery of claim 1 , wherein the one or more metallic tabs comprise aluminum, copper, or nickel.
14. The structural battery of claim 1 , wherein an edge of the one or more carbon fiber-reinforced polymer electrodes is abraded using physical abrasion or chemical abrasion to expose a portion of the carbon fiber of the electrode.
15. The structural battery of claim 1 , wherein the polymer comprises a liquid acrylate monomer and an initiator.
16. The structural battery of claim 15 , wherein the liquid acrylate monomer comprises ethoxylated (4) pentaerythritol tetraacrylate, tetraethylene glycol dimethacrylate, ethoxylated (30) bisphenol-A diacrylate, propoxylated (3) glyceryl triacrylate, methoxy polyethylene glycol (500) monoacrylate, or any combination thereof.
17. The structural battery of claim 15 , wherein the initiator is tert-butyl peroxide.
18. The structural battery of claim 15 , wherein the initiator comprises more than 0.1 wt % of an initiator-liquid monomer mixture.
19. The structural battery of claim 15 , wherein the initiator comprises less than 5 wt % of an initiator-liquid monomer mixture.
20. The structural battery of claim 1 , wherein the polymer comprises a resin and a hardener.