Compound for organic electric element, organic electric element using same, and electronic device comprising same

1. An organic electric element comprising:

a first electrode, a second electrode, and an organic material layer formed between the first electrode and the second electrode, wherein the organic material layer comprises an emitting layer and wherein the emitting layer comprises a first host compound represented by Formula 1 and a second host compound represented by Formula 2:

wherein:

1) Ar 1 , Ar 2 , Ar 3 , and Ar 4 are each independently selected from the group consisting of a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one hetero atom of O, N, S, Si or P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; and a C 6 -C 30 aryloxy group wherein Ar 2 and Ar 3 may combine to each other to form a ring,

2) a is an integer of 0 to 4, b is an integer of 0 to 3, c and e are integer of 0 to 10, and d is an integer of 0 to 2,

3) R 1 , R 2 , R 3 , R 4 and R 5 are the same or different from each other, and are each independently selected from the group consisting of deuterium; halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one heteroatom of O, N, S, Si or P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; and a C 6 -C 30 aryloxy group; or in case a, b, c, and e are each an integer of 2 or more and d is 2, R 1 , R 2 , R 3 , R 4 and R 5 are each in plural being the same or different, and a plurality of R 1 s or a plurality of R 2 s or a plurality of R 3 s or a plurality of R 4 s or a plurality of R 5 s may combine to each other to form a ring,

4) L 1 and L 2 are each independently selected from the group consisting of a single bond, a C 6 -C 60 arylene group, a fluorenylene group, a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring, and a C 2 -C 60 heterocyclic group,

5) A and B are each independently a C 6 -C 60 aryl group or a C 2 -C 20 heterocyclic group, wherein both A and B are a substituted or unsubstituted C 6 aryl group (phenyl group), d is 2 and R 4 s combine to each other to form an aromatic or hetero ring,

6) i and j are independently 0 or 1, with the proviso that i+j is 1 or more, and when i or j is 0, it means a direct bond,

7) X 1 and X 2 are independently NR′, O, S, or CR′R″, wherein R′ and R″ are independently hydrogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 3 -C 60 heterocyclic group; or a C 1 -C 50 alkyl group and wherein R′ and R″ may combine to each other to form a Spiro,

8) n is an integer of 1 or 2, and when n is 2, two Ar 2 's are the same or different from each other, and two Ar 3 s are each the same or different from each other,

wherein, the aryl group, fluorenyl group, arylene group, heterocyclic group, fused ring group, alkyl group, alkenyl group, alkoxy group and aryloxy group may be substituted with one or more substituents selected from the group consisting of deuterium; halogen; a silane group substituted or unsubstituted with a C 1 -C 20 alkyl group or a C 6 -C 20 aryl group; a siloxane group; a boron group; a germanium group; a cyano group; a nitro group; a C 1 -C 20 alkylthio group; a C 1 -C 20 alkoxyl group; a C 1 -C 20 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 6 -C 20 aryl group; a C 6 -C 20 aryl group substituted with deuterium; a fluorenyl group; a C 2 -C 20 heterocyclic group; a C 3 -C 20 cycloalkyl group; a C 7 -C 20 arylalkyl group and a C 8 -C 20 ) arylalkenyl group, wherein the substituents may combine each other and form a saturated or unsaturated ring, wherein the term ‘ring’ means a C 3 -C 60 aliphatic ring or a C 6 -C 60 aromatic ring or a C 2 -C 60 heterocyclic ring or a fused ring formed by the combination thereof.

2. The organic electric element according to claim 1 , wherein the first host compound represented by Formula 1 is represented by Formula 3 or 4:

wherein R 1 , R 2 , L 1 , Ar 1 , Ar 2 , Ar 3 , a and b are the same as defined in claim 1 .

3. The organic electric element according to claim 1 , wherein L 1 and L 2 are selected from the group consisting of the following Formulas (A-1) to (A-12):

wherein:

1) a′, c′, d′ and e′ are an integer of 0 to 4, b′ is an integer of 0 to 5, f′ and g′ are an integer of 0 to 3, and h′ is an integer of 0 to 1,

2) R 6 , R 7 and R 8 are the same or different from each other, and are each independently selected from the group consisting of deuterium; halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one heteroatom of O, N, S, Si or P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; and a C 6 -C 30 aryloxy group;

wherein in case f′ and g′ are an integer of 2 or more, R 6 , R 7 and R 8 are in plural being the same or different from each other, and a plurality of R 6 s or a plurality of R 6 s or plurality of R 8 s may combine to each other to form an aromatic or a heteroaromatic ring, and wherein two adjacent R 6 and R 7 , or R 7 and R 8 may combine to form an aromatic or heteroaromatic ring,

3) Y is NR′, O, S or CR′R″, wherein R′ and R″ are the same as defined above, and

4) Z 1 , Z 2 and Z 3 are independently CR′ or N, and at least one of Z 1 , Z 2 and Z 3 is N.

4. The organic electric element according to claim 1 , wherein the first host compound represented by Formula 1 is represented by any of the following Formulas 5 to 8:

wherein

1) R 1 , R 2 , Ar 1 , Ar 2 , Ar 3 , a, b, R′ and R″ are the same as defined in claim 1 ,

2) R 6 and R 7 are the same or different from each other, and are each independently selected from the group consisting of deuterium; halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one heteroatom of O, N, S, Si or P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; and a C 6 -C 30 aryloxy group; or in case f′ and g′ are 2 or more, R 6 and R 7 are each in plural being the same or different, and a plurality of R 6 s or a plurality of R 7 s or a plurality of R 8 s or adjacent R 6 and R 7 , or adjacent R 7 and R 8 may combine to each other to form an aromatic or a heteroaromatic ring,

3) a′, c′ and d′ are each an integer of 0 to 4, and f′ and g′ are each an integer of 0 to 3, and

4) Y is NR′, O, S or CR′R″.

5. The organic electric element according to claim 1 , wherein the first host compound represented by Formula 1 is represented by any of the following Formulas 9 to 20:

wherein, R 1 , R 2 , L 1 , Ar 1 , Ar 2 , Ar 3 , a and b are the same as defined in claim 1 .

6. The organic electric element according to claim 1 , wherein the first host compound represented by Formula 1 comprises a compound represented by the following Formula 21 or 22:

wherein R 1 , R 2 , L 1 , Ar 1 , Ar 2 , Ar 3 , a and b are the same as defined in claim 1 .

7. The organic electric element according to claim 1 , wherein n is 1 in Formula 1.

8. The organic electric element according to claim 1 , wherein n is 2 in Formula 1.

9. The organic electric element according to claim 1 , wherein the first host compound represented by Formula 1 comprises a compound represented by the following Formula 23:

wherein

1) R 1 , R 2 , L 1 , Ar 1 , Ar 2 , a, b and n are the same as defined in claim 1 ,

1) f is an integer of 0 to 3, and g is an integer of 0 to 4,

3) R 9 and R 10 are the same or different from each other, and are each independently selected from the group consisting of deuterium; halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one heteroatom of O, N, S, Si or P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; and a C 6 -C 30 aryloxy group; or in case f and g are 2 or more, R 9 and R 10 are each in plural being the same or different, and a plurality of R 9 s or a plurality of R 10 s or adjacent R 9 and R 10 may combine to each other to form an aromatic or a heteroaromatic ring,

4) Y is NR′, O, S or CR′R″, and

5) R′ and R″ are the same as defined in claim 1 .

10. The organic electric element according to claim 1 , wherein the second host compound represented by Formula 2 is represented by the following Formula 24 or 25:

wherein R 3 , R 4 , R 5 , Ar 4 , L 2 , c, d, e, A, B, X 1 and X 2 are the same as defined in claim 1 .

11. The organic electric element according to claim 1 , wherein A and B in Formula 2 are selected from the group consisting of the following Formulas (B-1) to (B-7):

wherein,

1) Z 4 to Z 50 are each CR′ or N,

2) R′ is the same as defined in claim 1 , and

3) * indicates the position to be condensed.

12. The organic electric element according to claim 1 , wherein R 4 in Formula 2 comprises a compound forming an aromatic ring or a heteroaromatic ring.

13. The organic electric element according to claim 1 , wherein the second host compound represented by Formula 2 comprises a compound represented by any of the following Formulas 26 to 45:

wherein,

Ar 4 , X 1 , X 2 , R 3 , R 4 , R 5 , L 2 , c, d, and e are the same as defined in claim 1 .

14. The organic electric element according to claim 1 , wherein the second host compound represented by Formula 2 comprises any one of compounds represented by the following Formulas 46 to 52:

wherein,

R 3 , R 4 , R 5 , Ar 4 , L 2 , c, d, e, A, B, R′ and R″ are the same as defined in claim 1 .

15. The organic electric element according to claim 1 , wherein the first host compound represented by Formula 1 is one of the following Compounds 1-1 to 1-68 and Compounds 2-1 to 2-68:

16. The organic electric element according to claim 1 , wherein the second host compound represented by Formula 2 comprises one of the following Compounds 3-1 to 3-84:

17. The organic electric element according to claim 1 , wherein the emitting layer is a phosphorescent light emitting layer.

18. The organic electric element according to claim 1 , wherein the compounds represented by Formula 1 and 2 are mixed in a ratio of 1:9 to 9:1 to be included in the emitting layer.

19. The organic electric element according to claim 1 , wherein the compounds represented by Formula 1 and 2 are mixed in a ratio of 1:9 to 5:5 to be included in the emitting layer.

20. The organic electric element according to claim 1 , wherein the compounds represented by Formula 1 and 2 are mixed in a ratio of 2:8 or 3:7 to be included in the emitting layer.

21. An electronic device comprising a display apparatus comprising the organic electric element according to claim 4 ; and a driving part configured to drive the display apparatus.

22. The electronic device according to claim 21 , wherein the organic electric element is an OLED, an organic solar cell, an organic photo conductor, an organic transistor, or a device for monochromic or white illumination.