Compound for organic electric element, organic electric element using same, and electronic device thereof

1. An organic electric element comprising a first electrode, a second electrode, and an organic material layer formed between the first electrode and the second electrode,

wherein the organic material layer comprises an emitting layer, and the emitting layer is a phosphorescent light emitting layer and comprises a first host compound represented by Formula (1) and a second host compound represented by Formula (2):

wherein:

1) Ar 1 , Ar 2 , Ar 3 and Ar 4 are each independently selected from the group consisting of a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one hetero atom of O, N, S, Si and P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; a C 6 -C 30 aryloxy group;

2) c and e are integer of 0 to 10, d is an integer of 0 to 2, and R 3 , R 4 and R 5 are the same or different from each other and are each independently selected from the group consisting of deuterium; halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one heteroatom of O, N, S, Si and P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; a C 6 -C 30 aryloxy group; and —L′-N(R a )(R b ), wherein, L′ is selected from the group consisting of a single bond; a C 6 -C 60 arylene group; a fluorenylene group; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; and a C 2 -C 60 heterocyclic, and R a and R b are independently selected from the group consisting of a C 6 -C 60 aryl group; a fluorenyl group; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; and a C 2 -C 60 heterocyclic group containing at least one hetero atom of O, N, S, Si and P,

or in case c, d and e are 2 or more, R 3 , R 4 and R 5 are each in plural being the same or different and a plurality of R 3 or a plurality of R 4 or a plurality of R 5 combine to each other to form a ring,

3) L 1 , L 2 , L 3 are L 4 each independently selected from the group consisting of a single bond; a C 6 -C 60 arylene group; and a fluorenylene group; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; and a C 2 -C 60 heterocyclic group;

4) A and B are each independently a C 6 -C 60 aryl group or a C 2 -C 20 heterocyclic group, wherein in case both A and B are a substituted or unsubstituted C 6 aryl group (phenyl group), d is 2, and R 4 s are bonded to each other to form a ring to form an aromatic or hetero ring,

5) i and j are independently 0 or 1, with the proviso that i+j is 1 or more, and when i or j is 0, it means a direct bond,

6) X 1 and X 2 are independently NR′, O, S, or CR′R″, wherein R′ and R″ are independently hydrogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 3 -C 60 heterocyclic group; or a C 1 -C 50 alkyl group, and R′ and R″ may combine to each other to form a spiro ring,

wherein, the aryl group, fluorenyl group, arylene group, heterocyclic group, fused ring group, alkyl group, alkenyl group, alkoxy group and aryloxy group may be substituted with one or more substituents selected from the group consisting of deuterium; halogen; a silane group substituted or unsubstituted with C 1 -C 20 alkyl group or C 6 -C 20 aryl group; siloxane group; boron group; germanium group; cyano group; nitro group; —L′-N(R a )(R b ); a C 1 -C 20 alkylthio group; C 1 -C 20 alkoxyl group; C 1 -C 20 alkyl group; C 2 -C 20 alkenyl group; C 2 -C 20 alkynyl group; C 6 -C 20 aryl group; C 6 -C 20 aryl group substituted with deuterium; a fluorenyl group; C 2 -C 20 heterocyclic group; C 3 -C 20 cycloalkyl group; C 7 -C 20 arylalkyl group; and C 8 -C 20 arylalkenyl group; wherein the substituents may combine each other and form a saturated or unsaturated ring, wherein the term ‘ring’ means C 3 -C 60 aliphatic ring or C 6 -C 60 aromatic ring or a C 2 -C 60 heterocyclic ring or a fused ring formed by the combination of thereof.

2. The organic electric element according to claim 1 , wherein the first host compound represented by Formula (1) is represented by any one of the following Formulas (3) to (5):

wherein:

1) L 1 , L 3 , L 4 , Ar 2 and Ar 3 are the same as defined in Formula (1),

2) X 3 is O or S,

3) a is an of 0 to 4, b is an integer of 0 to 3, and R 1 and R 2 are the same or different from each other, and are each independently selected from the group consisting of deuterium; halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one heteroatom of O, N, S, Si and P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; a C 6 -C 30 aryloxy group; and —L′-N(R a )(R b ); or in case a and b are 2 or more, R 1 and R 2 are each in plural being the same or different, and a plurality of R 1 or a plurality of R 2 combine to each other to form a ring.

3. The organic electric element according to claim 1 , wherein the compound represented by Formula (1) is represented by any one of the following Formulas (6) to (14):

wherein L 1 , L 3 , L 4 , Ar 2 , Ar 3 , R 1 , R 2 , a and b are the same as defined in claim 2 .

4. The organic electric element according to claim 1 , wherein the first host compound represented by Formula (1) is represented by any one of the following Formulas (15) to (23):

wherein L 1 , L 3 , L 4 , Ar 2 , Ar 3 , X 3 , R 1 , R 2 , a and b are the same as defined in claim 2 .

5. The organic electric element according to claim 1 , wherein Ar 1 , Ar 2 and Ar 3 in Formula (1) are all C 6 -C 24 aryl groups, and L 1 , L 3 and L 4 are single bonds or all C 6 -C 24 aryl groups.

6. The organic electric element according to claim 1 , wherein the first host compound represented by Formula (1) is represented by any one of the following Formulas (24) to (26):

wherein:

1) L 1 , L 3 , L 4 , Ar 2 and Ar 3 are the same as defined in claim 1 ,

2) Ar 5 and Ar 6 are each independently selected from the group consisting of a C 6 -C 60 aryl group; a C 2 -C 60 heterocyclic group including at least one heteroatom of O, N, S, Si and P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; a C 6 -C 30 aryloxy group; and —L′-N(R a )(R b ).

7. The organic electric element according to claim 1 , wherein L 1 , L 3 and L 4 in Formula (1) are selected from the group consisting of the following Formulas (A-1) to (A-12):

wherein:

1) a′, c′, d′ and e′ are each an integer of 0 to 4, b′ is an integer of 0 to 6, f′ and g′ are each an integer of 0 to 3, and h′ is an integer of 0 to 1,

2) R 6 , R 7 and R 8 are the same or different from each other, and are each independently selected from the group consisting of deuterium; halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one heteroatom of O, N, S, Si and P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; a C 6 -C 30 aryloxy group; and —L′-N(R a )(R b ); or wherein f′ and g′ are 2 or more, R 6 , R 7 and R 8 are each in plural being the same as or different from each other, and a plurality of R 6 or a plurality of R 7 or adjacent R 6 and R 7 may combine to each other to form an aromatic or a heteroaromatic ring,

3) Y is NR′, O, S or CR′R″, and R′ and R″ are the same as defined in claim 1 ,

4) Z 1 , Z 2 and Z 3 are each independently CR′ or N, and at least one is N.

8. The organic electric element according to claim 1 , wherein at least one of L 1 , L 3 , and L 4 in Formula (1) is a phenyl group and is substituted on a m(meta)-position.

9. The organic electric element according to claim 1 , wherein the second host compound represented by Formula (2) comprises a compound represented by the following Formula (27) or (28):

wherein R 3 , R 4 , R 5 , Ar 4 , L 2 , c, d, e, A, B, X 1 and X 2 are the same as defined in claim 1 .

10. The organic electric element according to claim 1 , wherein A and B in Formula (2) are selected from the group consisting of the following Formulas (B-1) to (B-7):

wherein:

1) Z 4 to Z 50 are CR′ or N,

2) R′ is the same as defined in Formula (2),

3) * indicates the position to be condensed.

11. The organic electric element according to claim 1 , wherein d in Formula (2) is 2, and R 4 s are bonded to form a ring to form an aromatic group or a heterocyclic ring.

12. The organic electric element according to claim 1 , wherein the second host compound represented by Formula (2) includes a compound represented by any of the following Formulas (29) to (48):

wherein Ar 4 , L 2 , X 1 , X 2 , R 3 , R 4 , R 5 , c, d, and e are the same as defined in claim 1 .

13. The organic electric element according to claim 1 , wherein the second host compound represented by Formula (2) comprises any of compound represented by the following Formulas (49) to (55):

wherein R 3 , R 4 , R 5 , Ar 4 , L 2 , c, d, e, A, B, R′ and R″ are the same as defined in claim 1 .

14. The organic electric element according to claim 1 , wherein the first host compound represented by Formula (1) is one of the following Compounds 1-1′ to 1-82′:

15. The organic electric element according to claim 1 , wherein the second host compound represented by Formula (2) is one of the following compounds 3-1 to 3-100:

16. The organic electric element according to claim 1 , wherein the compounds represented by Formula (1) and (2) are mixed in a ratio of 1:9 to 9:1 to be included in the emitting layer.

17. The organic electric element according to claim 1 , wherein the compound represented by Formula (1) and (2) are mixed in a ratio of 1:9 to 5:5 to be included in the emitting layer.

18. The organic electric element according to claim 1 , wherein the compound represented by Formula (1) and (2) are mixed in a ratio of 2:8 or 3:7 to be included in the emitting layer.

19. An electronic device comprising a display apparatus comprising the organic electric element according to claim 1 ; and a driving part configured to drive the display apparatus.

20. The electronic device according to claim 19 , wherein the organic electric element is an OLED, an organic solar cell, an organic photo conductor, an organic transistor, or a device for monochromic or white illumination.