Printing systems

1. A printing system, comprising:

a first excimer irradiation source positioned to irradiate a media substrate, wherein the first excimer irradiation source has power metrics and is posited at a distance from the media substrate to provide electromagnetic radiation at the surface of the media substrate at a surface power density of from 20 mW/cm 2 to 80 mW/cm 2 and

an inkjet print head positioned with respect to the excimer irradiation source to form a printed image on the media substrate after irradiation with the excimer irradiation source.

2. The printing system of claim 1 , further comprising a second excimer irradiation source positioned to treat the printed image after application to the media substrate.

3. The printing system of claim 2 , wherein the first excimer irradiation source, the second excimer irradiation source, or both have a width that is 75% or more as wide as the print media.

4. The printing system of claim 2 , wherein the first excimer irradiation source, the second excimer irradiation source, or both are positioned at a distance from 0.5 millimeters (mm) to 5 mm from the media substrate.

5. The printing system of claim 2 , wherein the first excimer irradiation source, the second excimer irradiation source, or both emit electromagnetic radiation at a wavelength ranging from 108 nm to 222 nm.

6. The printing system of claim 1 , wherein the first excimer irradiation source and the inkjet printhead are attached to a carriage to pass the first excimer irradiation source over a portion of the media substrate to pretreat the media substrate prior to passing the inkjet printhead over the media substrate to form the printed image on the portion of the media substrate.

7. The printing system of claim 1 , further comprising an ink reservoir in fluid communication with the inkjet print head, the ink reservoir comprising a pigment-based inkjet ink, wherein the pigment-based inkjet ink comprises an anionic pigment material.

8. A method of forming a printed image on a media substrate, comprising:

pre-treating a portion of a surface of a media substrate with electromagnetic radiation emitted from a first excimer irradiation source, wherein the first excimer irradiation source has power metrics and is posited at a distance from the media substrate to provide electromagnetic radiation at the surface of the media substrate at a surface power density of from 20 MW/cm 2 to 80 mW/cm 2 ; and

jetting an inkjet ink from an inkjet print ad onto the media substrate to form a printed image on the portion.

9. The method of claim 8 , further comprising post-treating the printed image with electromagnetic radiation emitted from a second excimer irradiation source.

10. The method of claim 9 , wherein the first excimer irradiation source emits electromagnetic radiation at a different wavelength than the second excimer irradiation source.

11. The method of claim 9 , wherein pre-treating, post-treating, or both is performed for a time period ranging from 0.1 second to 60 seconds.

12. A system for a printed article, the printed article comprising:

a media substrate having a modified surface formed by exposure to electromagnetic radiation emitted from a first excimer irradiation source to form cationic species, acid groups, oxygen containing groups, or a combination thereof on the surface, wherein the media substrate is substantially devoid of printed fixer,

wherein the first excimer irradiation source has power metrics and is posited at a distance from the media substrate to provide electromagnetic radiation at the surface of the media substrate at a surface power density of from 20 mW/cm 2 to 80 mW/cm 2 ; and

a digitally printed image on the modified surface, including pigment particles in contact with the modified surface of the media substrate.

13. The system for a printed article of claim 12 , wherein the media substrate is a polyolefin media substrate, a plain paper media substrate, or a coated offset media substrate.

14. The system for a printed article of claim 12 , wherein the digitally printed image is formed with a curable inkjet ink that has been cured by exposure to electromagnetic radiation emitted from a second excimer irradiation source, and wherein the curable inkjet ink is devoid of a photoinitiator.