Electrolyte of rechargeable lithium battery and rechargeable lithium battery including same
Aspects of embodiments of the present disclosure provide an electrolyte for a rechargeable lithium battery, and a rechargeable lithium battery including the same. The electrolyte includes a non-aqueous organic solvent, a lithium salt, and additive represented by Chemical Formula 1: In Chemical Formula 1, X1 is CH or a nitrogen atom (N), and R a is a substituted or unsubstituted alkyl group. The additive may decompose under reducing voltages on the surface of the negative electrode to thereby form a polysulfonate-based passivation film to suppress or reduce gas generation and battery swelling.
1. An electrolyte for a rechargeable lithium battery, comprising:
a non-aqueous organic solvent;
a lithium salt; and
an additive represented by Chemical Formula 1:
wherein in Chemical Formula 1,
X1 is CH or a nitrogen atom (N), and R a is a substituted or unsubstituted alkyl group.
2. The electrolyte for a rechargeable lithium battery of claim 1 , wherein an amount of the additive is about 0.1 wt % to about 3 wt % based on a total weight of the electrolyte.
3. The electrolyte for a rechargeable lithium battery of claim 1 , wherein an amount of the additive is about 1 wt % to about 2 wt % based on the total weight of the electrolyte.
4. The electrolyte for a rechargeable lithium battery of claim 1 , wherein the substituted alkyl group is a fluorine-substituted alkyl group.
5. The electrolyte for a rechargeable lithium battery of claim 1 , wherein the electrolyte further comprises a second additive selected from fluoroethylene carbonate, vinylene carbonate, succinonitrile, hexane tricyanide, LiBF 4 , and combinations thereof.
6. The electrolyte for a rechargeable lithium battery of claim 5 , wherein an amount of the second additive is about 5 wt % to about 20 wt % based on a total weight of the electrolyte.
7. The electrolyte for a rechargeable lithium battery of claim 1 , wherein X1 is CH.
8. The electrolyte for a rechargeable lithium battery of claim 1 , wherein X1 is N.
9. The electrolyte for a rechargeable lithium battery of claim 1 , wherein Ra is a substituted or unsubstituted methyl group, a substituted or unsubstituted ethyl group, a substituted or unsubstituted propyl group, a substituted or unsubstituted butyl group, a substituted or unsubstituted pentyl group, and a substituted or unsubstituted hexyl group, a substituted or unsubstituted heptyl group, a substituted or unsubstituted octyl group, a substituted or unsubstituted nonyl group, a substituted or unsubstituted decyl group, a substituted or unsubstituted dodecyl group, a substituted or unsubstituted isopropyl group, a substituted or unsubstituted sec-butyl group, a substituted or unsubstituted isobutyl group, a substituted or unsubstituted neopentyl group, or a substituted or unsubstituted isopentyl group.
10. The electrolyte for a rechargeable lithium battery of claim 1 , wherein the additive is further represented by Chemical Formula 1a:
11. The electrolyte for a rechargeable lithium battery of claim 1 , wherein the additive is further represented by Chemical Formula 1b:
12. A rechargeable lithium battery comprising:
a negative electrode comprising a negative active material layer comprising a negative active material;
a positive electrode including a positive active material layer comprising a positive active material; and
the electrolyte of claim 1 .
13. The rechargeable lithium battery of claim 12 , wherein the negative electrode further comprises a stable passivation film on the surface of the negative active material layer in contact with the electrolyte, the stable passivation film comprising a reduction-decomposition product of the additive.