IP Library Granted Patent US 11,034,838
Granted Patent B2
US 11,034,838 · App. 16/483,149 · Granted Jun 15, 2021

Composite material and composite product

Inventors: Duncan Mayes (Helsinki, FI); Janne Pynnonen (Lempaala, FI); Christopher H. West (Detroit, ME); Douglas J. Gardner (Brewer, ME); Yousoo Han (Bangor, ME)
Assignees: Stora Enso OYJ; University of Maine System Board of Trustees
C08L97/02B27K5/0085B27N1/02B27N3/002C08L25/08B27K2200/10B27K2200/15B27N3/28C08L2205/025C08L2205/03
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Quick Facts
Patent No.
US 11,034,838
App. No.
16/483,149
Granted
Jun 15, 2021
Kind
B2
Abstract

The present invention is directed to a composite material comprising a cellulosic material, high impact polystyrene (HIPS) and styrene maleic anhydride (SMA). The cellulosic material may be thermally modified prior to being incorporated into the composite material. The present invention is also directed to a composite product that comprises the composite material according to the invention.

Claims (23)

1. A composite material comprising:

at least 20% by weight of a cellulosic material,

at least 1% by weight and less than 20% by weight of styrene maleic anhydride, and

from 5% to 50% by weight of a high impact polystyrene,

wherein the cellulosic material is a thermally modified cellulose material, and

wherein the cellulosic material has been thermally modified by heat treatment either at a temperature between 160-250° C. at atmospheric pressure or at a temperature above 120° C. at an elevated pressure.

2. The composite material according to claim 1 , wherein the composite material comprises from 2% to 15% by weight of styrene maleic anhydride.

3. The composite material according to claim 2 , wherein the composite material comprises from 5% to 10% by weight of styrene maleic anhydride.

4. The composite material according to claim 1 , comprising 25-75% by weight of a cellulosic material.

5. The composite material according to claim 4 , comprising 40-65% by weight of a cellulosic material.

6. The composite material according to claim 5 , comprising 45-65% by weight of a cellulosic material.

7. The composite material according to claim 6 , comprising 50-60% by weight of a cellulosic material.

8. The composite material according to claim 1 , comprising 35-50% by weight high impact polystyrene.

9. The composite material according to claim 1 , wherein the cellulosic material has a particle size below 1 mm.

10. The composite material according to claim 1 , wherein the cellulosic material is in the form of a powder.

11. A composite product comprising a composite material according to claim 1 .

12. A process for producing a composite product which process comprises the steps of:

a) providing a cellulosic material, high impact polystyrene (HIPS) and styrene maleic anhydride (SMA), wherein the cellulosic material is a thermally modified cellulose material, and

wherein the cellulosic material has been thermally modified by heat treatment at a temperature between 160-250° C. at atmospheric pressure or at a temperature above 120° C. at elevated pressure;

b) feeding said cellulosic material, HIPS and SMA to an extruder; and

c) extruding the composite product.

13. The composite material according to claim 1 wherein the cellulosic material has been thermally modified by heat treatment at a temperature between 200-230° C. at atmospheric pressure.

14. The composite material according to claim 1 wherein the cellulosic material has been thermally modified by heat treatment at a temperature above 120° C. at an elevated pressure.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 16, 2024
From: STORA ENSO OYJ
To: UNIVERSITY OF MAINE SYSTEM BOARD OF TRUSTEES
Reel/Frame 067115/0153 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 18, 2019
From: MAYES, DUNCAN; PYNNÖNEN, JANNE; WEST, CHRISTOPHER H; GARDNER, DOUGLAS J; HAN, YOUSOO
To: STORA ENSO OYJ; UNIVERSITY OF MAINE SYSTEM BOARD OF TRUSTEES
Reel/Frame 050410/0746 →
Continuity (2)
Provisional Application 62454110 · Feb 3, 2017
Related Publication 20200239690A1 · Jul 30, 2020