Colloids of inorganic nanocrystals in molten media and related methods
Colloids comprising inorganic nanocrystals dispersed in a molten salt or a liquid metal are provided. The molten salt may comprise an ion which is a Lewis acid or a Lewis base in the presence of the inorganic nanocrystals. Solid composites formed from the colloids are also provided. Methods of using the colloids as media for inducing chemical transformations using the inorganic nanocrystals are also provided.
1. A colloid comprising inorganic nanocrystals dispersed in a molten metal salt comprising an ion which is a Lewis acid or a Lewis base in the presence of the inorganic nanocrystals, wherein the molten metal salt does not comprise a nitrate salt or a nitrite salt or a combination thereof.
2. The colloid of claim 1 , wherein the molten metal salt has a melting point of below 350° C.
3. The colloid of claim 1 , wherein the molten metal salt is a metal halide; a mixture of metal halides and optionally, an amount of a salt additive; or a mixture of metal thiocyanates and optionally, an amount of a salt additive.
4. The colloid of claim 1 , wherein the nanocrystals are metal nanocrystals, metal alloy nanocrystals, semiconductor nanocrystals, metal oxide nanocrystals, metalloid oxide nanocrystals, or a combination thereof.
5. The colloid of claim 1 , wherein the colloid is substantially free of organic capping ligands.
6. The colloid of claim 1 , wherein the nanocrystals comprise no more than about 10 weight % of the colloid.
7. The colloid of claim 1 , wherein the molten metal salt is selected from the group consisting of: a mixture of AlCl 3 , NaCl, and KCl; a mixture of LiAlBr 4 , NaAlCl 4 , KAlCl 4 and an amount of AlBr 3 as a salt additive; a mixture of NaAlCl 4 and KAlCl 4 and an amount of AlrBr 3 or AlCl 3 as a salt additive; AlBr 3 ; a mixture of LiCl, LiBr, and KBr; a mixture of LiCl, LiI, and KI; a mixture of CsBr, LiBr, and KBr and optionally, an amount of GaI 3 as a salt additive; a mixture of ZnCl 2 , NaCl, and KCl and optionally, an amount of GaI 3 as a salt additive; a mixture of KSCN and NaSCN; and GaI 3 .
8. A method comprising heating the colloid of claim 1 to a temperature and for a time sufficient to induce a chemical transformation of the inorganic nanocrystals.
9. The method of claim 8 , wherein the temperature is at least about 300° C.
10. The method of claim 8 , further comprising adding a shell precursor to the colloid, wherein the temperature and the time are sufficient to form a shell over the inorganic nanocrystals, thereby providing core-shell nanocrystals.
11. The method of claim 10 , wherein the molten metal salt is selected to provide a first component of the shell and the shell precursor is selected to provide a second component of the shell.
12. The method of claim 8 , wherein the temperature and the time are sufficient to at least partially remove defects in the crystal structure of the inorganic nanocrystals.
13. The method of claim 8 , further comprising adding an ion exchange additive to the colloid, wherein the temperature and the time are sufficient to induce an exchange of ions of the ion exchange additive with ions of the inorganic nanocrystals, thereby changing the chemical composition of the inorganic nanocrystals.
14. A colloid comprising inorganic nanocrystals dispersed in a molten metal salt comprising an ion which is a Lewis acid or a Lewis base in the presence of the inorganic nanocrystals, wherein the nanocrystals are metal nanocrystals, metal alloy nanocrystals, semiconductor nanocrystals, metal oxide nanocrystals, metalloid oxide nanocrystals, or a combination thereof.
15. The colloid of claim 14 , wherein the nanocrystals have an average largest cross-sectional dimension of no greater than 100 nm.
16. The colloid of claim 14 , wherein the molten metal salt is a metal halide; a mixture of metal halides and optionally, an amount of a salt additive; or a mixture of metal thiocyanates and optionally, an amount of a salt additive.
17. The colloid of claim 14 , wherein the molten metal salt is selected from the group consisting of: a mixture of AlCl 3 , NaCl, and KCl; a mixture of LiAlBr 4 , NaAlCl 4 , KAlCl 4 and an amount of AlBr 3 as a salt additive; a mixture of NaAlCl 4 and KAlCl 4 and an amount of AlrBr 3 or AlCl 3 as a salt additive; AlBr 3 ; a mixture of LiCl, LiBr, and KBr; a mixture of LiCl, LiI, and KI; a mixture of CsBr, LiBr, and KBr and optionally, an amount of GaI 3 as a salt additive; a mixture of ZnCl 2 , NaCl, and KCl and optionally, an amount of GaI 3 as a salt additive; a mixture of KSCN and NaSCN; and GaI 3 .
18. A method comprising heating the colloid of claim 14 to a temperature and for a time sufficient to induce a chemical transformation using the inorganic nanocrystals.