Silicon oxide composite for lithium secondary battery negative electrode material and method for manufacturing the same
A silicon oxide composite for a secondary battery negative electrode material and a method for manufacturing the same, more particularly, a silicon oxide composite for a secondary battery negative electrode material and a method for manufacturing the same are disclosed. The silicon oxide composite includes MgSiO 3 (enstatite) crystals and silicon particles, of which crystal size is from 1 to 25 nm, in a silicon oxide (SiOx, 0<x<2), and a carbon film placed on a surface.
1. A silicon oxide composite for a secondary battery negative electrode material, the silicon oxide composite comprising:
(a) a silicon oxide (SiOx, 0<x<2), and
(b) a carbon film on a surface of the silicon oxide,
in which (a) the silicon oxide (SiOx, 0<x<2) includes;
(i) an MgSiO 3 (enstatite) crystal; and
(ii) a silicon particle with a crystal size of from 1 to 25 nm; and
wherein the MgSiO 3 (enstatite) crystals and silicon particles are uniformly mixed inside the silicon oxide (SiOx, 0<x<2), and
wherein the silicon oxide does not include Mg 2 SiO 4 (forsterite) crystal, or when Mg 2 SiO 4 (forsterite) crystal is futher included, the content of the Mg 2 SiO 4 (forsterite) crystal is smaller than the content of the MgSiO 3 (enstatite) crystal.
2. The silicon oxide composite of claim 1 , wherein in X-ray diffraction pattern analysis, a peak belonging to a Si crystal appears in a range of a diffraction angle 28°<20<29°, and wherein a peak belonging to a MgSiO 3 crystal appears in a range of a diffraction angle 30.5°<20<31.5°.
3. The silicon oxide composite of claim 1 , wherein Mg weight per part by the total silicon oxide composite 100 weight is contained in a ratio of 2 to 20 in part by weight.
4. The silicon oxide composite of claim 1 , wherein carbon per part by the total silicon oxide composite 100 weight is contained in a ratio of 1 to 20 in part by weight.
5. The silicon oxide composite of claim 1 , wherein an average thickness of the carbon film is from 5 to 100 nm.
6. The silicon oxide composite of claim 1 , wherein the carbon film includes one or more selected from a group of a carbon nanofiber, a graphene, a graphene oxide, and a reduced graphene oxide.
7. The silicon oxide composite of claim 1 , wherein specific gravity of the silicon oxide composite is from 2.3 to 3.2.
8. The silicon oxide composite of claim 1 , wherein an average particle diameter of the silicon oxide composite is from 0.1 to 15 μm.
9. The silicon oxide composite of claim 1 , wherein a specific surface area of the silicon oxide composite is from 1 to 40 m 2 /g.
10. A lithium secondary battery negative electrode comprising a silicon oxide composite for a secondary battery negative electrode material of claim 1 .
11. A lithium secondary battery comprising a lithium secondary battery negative electrode including a silicon oxide composite for a secondary battery negative electrode material of claim 10 .