Amine-based compound and organic light emitting device comprising same
The present specification provides a compound of Chemical Formula 1, and an organic light emitting device including the same. The compound of Chemical Formula 1 used in one or more organic material layers of an organic light emitting device provides enhanced efficiency, lowered driving voltage, and increased lifetime of the device.
1. A compound represented by the following Chemical Formula 1:
wherein, in Chemical Formula 1,
R1 to R4 are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a silyl group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted alkoxy group; a substituted or unsubstituted thioalkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted heterocyclic group;
n1 to n3 are each an integer of 0 to 4;
when n1 to n3 are each 2 or greater, substituents in the parentheses are the same as or different from each other;
n4 is an integer of 0 to 2;
when n4 is 2, substituents in the parentheses are the same as or different from each other;
p1 to p3 are each an integer of 0 to 3;
when p1 to p3 are each 2 or greater, substituents in the parentheses are the same as or different from each other;
L, L1 and L2 are the same as or different from each other, and each independently a direct bond; a substituted or unsubstituted arylene group; or a substituted or unsubstituted divalent heterocyclic group;
Ar1 is triphenylene;
Ar2 is hydrogen; deuterium; a substituted or unsubstituted aryl group; a substituted or unsubstituted arylalkyl group; a substituted or unsubstituted arylalkenyl group; or a substituted or unsubstituted heterocyclic group; and
X1 is a substituted or unsubstituted aryl group; a substituted or unsubstituted arylalkyl group; a substituted or unsubstituted arylalkenyl group; or a substituted or unsubstituted heterocyclic group.
2. The compound of claim 1 , wherein the compound represented by Chemical Formula 1 is represented by one of the following Chemical Formulae 2 to 4:
wherein, in Chemical Formulae 2 to 4,
R1 to R4, X1, L, L1, L2, n1 to n4, p1 to p3, Ar1 and Ar2 have the same definitions as in Chemical Formula 1.
3. The compound of claim 1 , wherein —(L) p1 —N[(L1) p2 Ar1][(L2) p3 Ar2] is represented by the following Chemical Formula 5:
wherein, in Chemical Formula 5,
L, L2, p1, p3 and Ar2 have the same definitions as in Chemical Formula 1.
4. The compound of claim 1 , wherein L is a direct bond or any one selected from the following structures:
wherein, in the structures,
R17 to R19 are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a silyl group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted alkoxy group; a substituted or unsubstituted alkenyl group; a substituted or unsubstituted boron group; a substituted or unsubstituted amine group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted heterocyclic group.
5. The compound of claim 1 , wherein X1 is a substituted or unsubstituted aryl group; or a substituted or unsubstituted heterocyclic group.
6. The compound of claim 1 , wherein X1 is any one selected from the following structures:
wherein, in the structures,
R11 to R13 are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a silyl group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted alkoxy group; a substituted or unsubstituted alkenyl group; a substituted or unsubstituted boron group; a substituted or unsubstituted amine group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted heterocyclic group, or adjacent substituents bond to each other to form a substituted or unsubstituted ring.
7. The compound of claim 1 , wherein Ar2 is any one selected from the following structures:
wherein, in the structures,
R14 to R16 are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a silyl group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted alkoxy group; a substituted or unsubstituted alkenyl group; a substituted or unsubstituted boron group; a substituted or unsubstituted amine group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted heterocyclic group, or adjacent substituents bond to each other to form a substituted or unsubstituted ring.
8. The compound of claim 1 , wherein L1 and L2 are the same as or different from each other, and each independently a direct bond; or any one selected from the following structures:
wherein, in the structures,
R17 to R19 are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a silyl group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted alkoxy group; a substituted or unsubstituted alkenyl group; a substituted or unsubstituted boron group; a substituted or unsubstituted amine group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted heterocyclic group.
9. The compound of claim 1 , wherein the compound represented by Chemical Formula 1 is any one selected from the following structures:
10. An organic light emitting device comprising:
a first electrode;
a second electrode; and
one or more organic material layers disposed between the first electrode and the second electrode,
wherein one or more layers of the one or more organic material layers comprise the compound of claim 1 .
11. The organic light emitting device of claim 10 , wherein the one or more organic material layers comprise a hole injection layer or a hole transfer layer, and the hole injection layer or the hole transfer layer comprises the compound of Chemical Formula 1.
12. The organic light emitting device of claim 10 , wherein the one or more organic material layers comprise a light emitting layer, and the light emitting layer comprises the compound of Chemical Formula 1.
13. The organic light emitting device of claim 10 , wherein the one or more organic material layers comprise an electron injection layer or an electron transfer layer, and the electron injection layer or the electron transfer layer comprises the compound of Chemical Formula 1.
14. The organic light emitting device of claim 10 , wherein the one or more organic material layers comprise an electron blocking layer, and the electron blocking layer comprises the compound of Chemical Formula 1.
15. The organic light emitting device of claim 10 , further comprising one, two or more layers selected from the group consisting of a hole injection layer, a hole transfer layer, an electron transfer layer, an electron injection layer, an electron blocking layer and a hole blocking layer.