IP Library Granted Patent US 11,078,086
Granted Patent B2
US 11,078,086 · App. 16/346,319 · Granted Aug 3, 2021

Method for producing lithium hydroxide anhydride and rotary kiln to be used therefor

Inventors: Manabu Yamamoto (Sanyoonoda, JP); Osamu Sasaki (Sanyoonoda, JP); Noriyasu Kimura (Sanyoonoda, JP); Kenichi Nishimura (Itoigawa, JP); Wataru Koyanagi (Itoigawa, JP); Toru Kuwahara (Itoigawa, JP)
Assignees: BASF TODA BATTERY MATERIALS LLC; TANABE CORPORATION
C01D15/02F27B7/08F27B7/36F27B7/362F27D7/06H01M4/483H01M10/0525F27B2007/365H01M2004/028
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Quick Facts
Patent No.
US 11,078,086
App. No.
16/346,319
Granted
Aug 3, 2021
Kind
B2
Abstract

The object of the present invention is to improve production efficiency of lithium hydroxide anhydride in a method for producing lithium hydroxide anhydride from lithium hydroxide hydrate by using a rotary kiln. The method for producing lithium hydroxide anhydride comprises steps of: supplying the lithium hydroxide hydrate to a region between a heating part which is the part of the furnace core tube surrounded by the heating furnace and one end of the furnace core tube; delivering the supplied lithium hydroxide hydrate toward the other end of the furnace core tube; feeding a drying gas with a temperature of 100° C. or higher to the region between the one end and the heating part of the furnace core tube, when the lithium hydroxide hydrate is supplied; and heating and dehydrating the lithium hydroxide hydrate by the heating furnace which is set to 230-450° C. during the lithium hydroxide delivering step, to form lithium hydroxide anhydride.

Claims (10)

1. A method for producing lithium hydroxide anhydride from lithium hydroxide hydrate by using a rotary kiln which has a furnace core tube and a heating furnace surrounding a certain part of the furnace core tube in the axial direction, wherein the method comprises the steps of:

supplying the lithium hydroxide hydrate to a region between a heating part which is the part of the furnace core tube surrounded by the heating furnace and one end of the furnace core tube;

delivering the supplied lithium hydroxide hydrate toward the other end of the furnace core tube;

feeding a drying gas with a temperature of 100° C. or higher to the region between the one end and the heating part of the furnace core tube, when the lithium hydroxide hydrate is supplied; and

heating and dehydrating the lithium hydroxide hydrate by the heating furnace which is set to 230-450° C. during the lithium hydroxide delivering step, to form lithium hydroxide anhydride.

2. The method according to claim 1 , wherein the amount of the supplied lithium hydroxide hydrate is from 5 to 15% by volume, based on the volume of the furnace core tube.

3. The method according to claim 1 , wherein the time for heating the lithium hydroxide in the heating part of the furnace core tube is from 30 min to 2 hours.

4. The method according to claim 1 , wherein an insulating material is provided on the outside surface of a region between the one end and the heating part of the furnace core tube.

5. The method according to claim 1 , wherein the rotary kiln comprises an exhaust pipe for discharging the heated drying gas to the outside of the furnace core tube,

wherein the method further comprises a step of discharging the heated drying gas to the outside of the furnace core tube via the exhaust pipe.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 1, 2019
From: YAMAMOTO, MANABU; SASAKI, OSAMU; KIMURA, NORIYASU; NISHIMURA, KENICHI; KOYANAGI, WATARU; KUWAHARA, TORU
To: BASF TODA BATTERY MATERIALS LLC; TANABE CORPORATION
Reel/Frame 049044/0936 →
Priority Claims (1)
JP JP2016-214053 · Nov 1, 2016 · national
Continuity (1)
Related Publication 20200055739A1 · Feb 20, 2020