Chemical compounds with perfluoroaryl groups that can facilitate post-synthesis functionalization
Techniques regarding chemical compounds comprising perfluoroaryl groups that can facilitate post-synthesis functionalization are provided. For example, one or more embodiments described herein can comprise a chemical compound. The chemical compound can comprise a molecular backbone. The chemical compound can also comprise a pendent functional group bonded to the molecular backbone. The pendent functional group can comprise a perfluoroaryl group and a methylene group.
1. A chemical compound comprising:
a molecular backbone comprising a plurality of urethane groups; and
a pendent functional group covalently bonded to an amine group of at least one of the plurality of urethane groups via a methylene group, the pendent functional group comprising a perfluoroaryl group.
2. The chemical compound of claim 1 , wherein the molecular backbone further comprises a carbamate group.
3. The chemical compound of claim 1 , wherein the pendent functional group is a perfluorobenzyl group.
4. The chemical compound of claim 2 , wherein the carbamate group is derived from an isocyanate.
5. A polymer comprising:
a molecular backbone comprising a polyurethane structure; and
a pendent functional group covalently bonded to an amino group of the molecular backbone via a methylene group, the pendent functional group comprising a perfluoroaryl group and a methylene group.
6. The polymer of claim 5 , wherein the molecular backbone further comprises a carbamate group.
7. The polymer of claim 5 , wherein the polymer is characterized by a chemical formula:
wherein n is an integer greater than or equal to two and less than or equal to one thousand.
8. The polymer of claim 6 , wherein the pendent functional group is a perfluorobenzyl group.
9. The polymer of claim 8 , wherein the carbamate group is derived from an isocyanate.
10. The polymer of claim 5 , wherein the polymer is characterized by a chemical formula:
wherein n is an integer greater than or equal to two and less than or equal to one thousand, and wherein R 2 comprises one or more functional groups.
11. The polymer of claim 10 , wherein R 2 comprises a functional group selected from the group consisting of: an alkyl structure, an aryl structure, a carboxyl group, a carbonyl group, an amine group, an amide group, an ether group, an ester group, a ketone group, a hydroxyl group, an alkenyl group, an aldehyde group, and an alkene group.
12. The polymer of claim 10 , wherein R 2 comprises undecane.
13. The chemical compound of claim 1 , wherein the pendent functional group comprises the methylene group.
14. The chemical compound of claim 1 , wherein the chemical compound is characterized by a chemical formula:
wherein n is an integer greater than or equal to two and less than or equal to one thousand.
15. The chemical compound of claim 1 , wherein the chemical compound is characterized by a chemical formula:
wherein n is an integer greater than or equal to two and less than or equal to one thousand, and wherein R 2 comprises one or more functional groups.
16. The chemical compound of claim 15 , wherein R 2 comprises a functional group selected from the group consisting of: an alkyl structure, an aryl structure, a carboxyl group, a carbonyl group, an amine group, an amide group, an ether group, an ester group, a ketone group, a hydroxyl group, an alkenyl group, an aldehyde group, and an alkene group.
17. The chemical compound of claim 15 , wherein R 2 comprises undecane.