Thermally conductive composition, thermally conductive sheet, and method for producing thermally conductive sheet
To provide a thermally conductive sheet that has high thermal conductivity. A method for producing a thermally conductive sheet S includes a step of obtaining a thermally conductive composition by mixing a reactive liquid resin, which forms a rubbery or gelatinous matrix when crosslinked, a volatile liquid having a boiling point 10° C. or more higher than a curing temperature of the reactive liquid resin, and a thermally conductive filler; a step of forming a molded body by crosslinking and curing the reactive liquid resin at a temperature 10° C. or more lower than the boiling point of the volatile liquid; and a step of evaporating the volatile liquid by heating the molded body, in which these steps are performed sequentially.
1. A method for producing a thermally conductive sheet, the method comprising:
a step of obtaining a thermally conductive composition by mixing a reactive liquid resin, which forms a rubbery or gelatinous matrix when crosslinked, a volatile liquid having a boiling point 10° C. or more higher than a curing temperature of the reactive liquid resin, and a thermally conductive filler containing carbon fibers;
a step of orienting the carbon fibers in a same direction;
a step of forming a block-shaped molded body having a thickness larger than a desired sheet thickness by crosslinking and curing the reactive liquid resin at a temperature 10° C. or more lower than the boiling point of the volatile liquid;
a step of slicing the block-shaped molded body to obtain a molded body of the desired sheet thickness; and
a step of evaporating the volatile liquid from sliced faces having no skin layer of the molded body of the desired sheet thickness by heating the molded body of the desired sheet thickness, wherein these steps are performed sequentially.
2. The method for producing a thermally conductive sheet according to claim 1 , wherein, in the slicing step, the block-shaped molded body is sliced at a plane substantially perpendicular to a direction in which the carbon fibers are oriented so that a molded body having the desired sheet thickness and containing the carbon fibers oriented in a thickness direction is obtained.
3. The method for producing a thermally conductive sheet according to claim 1 , wherein in the step of orienting the carbon fibers, the same direction is the fiber axis directions of more than 50% of the carbon fibers being oriented within a 15° range with respect to a certain direction.
4. A thermally conductive sheet comprising a rubbery or gelatinous matrix having a crosslinked structure, and a thermally conductive filler,
wherein the thermally conductive filler includes carbon fibers having fiber axis directions oriented in a sheet thickness direction,
wherein the thermally conductive sheet exhibits a rate of increase in weight of 0.1 to 1% when immersed in isopropyl alcohol for 3 minutes,
wherein the matrix is formed of a cured body of a reactive liquid resin that forms a rubbery or gelatinous matrix when crosslinked, and contains a non-volatile liquid having a boiling point exceeding 200° C.
5. The thermally conductive sheet according to claim 4 , wherein the matrix is formed of a cured body of an addition-reaction silicone.