Methods for making compositions containing multiple populations of microcapsules

1. A method of making a consumer product that provides multiple blooms of fragrance, the method comprising:

combining a first adjunct material, a first population of microcapsules, and a second population of microcapsules to form the consumer product;

wherein the first population has a first median volume weighted particle size and comprises microcapsules comprising a partitioning modifier and a first perfume oil at a first weight ratio; and

wherein the second population of microcapsules has a second median volume weighted particle size and comprises microcapsules comprising the partitioning modifier and a second perfume oil at a second weight ratio;

wherein the first median volume weighted particle size and the second median volume weighted particle size are different.

2. The method of claim 1 , wherein at least one of the first population of microcapsules and the second population of microcapsules is contained in a slurry prior to combining with the adjunct material.

3. The method of claim 2 , wherein the slurry includes one or more processing aids selected from the group consisting of a carrier, an aggregate inhibiting material, a deposition aid, a particle suspending polymer, and mixtures thereof.

4. The method of claim 1 , wherein at least one of the first population of microcapsules and the second population of microcapsules is spray dried prior to combining with the adjunct material.

5. The method of claim 1 , wherein the first weight ratio is a weight ratio of from 2:3 to 3:2 of the partitioning modifier to the first perfume oil; and wherein the second weight ratio is a weight ratio of greater than 0 to less than 2:3 of the partitioning modifier to the second perfume oil.

6. The method of claim 1 , wherein a weight ratio of the first population of microcapsules to the second population of microcapsules is greater than 0 to less than 1:1.

7. The method of claim 1 , wherein a weight ratio of the first population of microcapsules to the second population of microcapsules exceeds 1:1.

8. The method of claim 1 , wherein the first and second median volume-weighted particle size is from 2 microns to 80 microns.

9. The method of claim 8 , wherein the first and second median volume-weighted particle size is from 9 microns to 15 microns.

10. The method of claim 1 , wherein the first population of microcapsules and the second population of microcapsules have a wall thickness of from 10 nm to 200 nm.

11. The method of claim 1 , wherein the adjunct material comprises a non-encapsulated perfume oil.

12. The method of claim 11 , wherein the non-encapsulated perfume oil is different from the first and second perfume oil.

13. The method of claim 1 , wherein the partitioning modifier is selected from the group consisting of isopropyl myristate, mono-, di-, and tri-esters of C 4 -C 24 fatty acids, castor oil, mineral oil, soybean oil, hexadecanoic acid, methyl ester isododecane, isoparaffin oil, polydimethylsiloxane, brominated vegetable oil, and mixtures thereof.

14. The method of claim 1 , wherein the microcapsule further comprises a shell material selected from the group consisting of polyacrylates, polyethylenes, polyamides, polystyrenes, polyisoprenes, polycarbonates, polyesters, polyureas, polyurethanes, polyolefins, polysaccharides, epoxy resins, vinyl polymers, urea cross-linked with formaldehyde or gluteraldehyde, melamine cross-linked with formaldehyde; gelatin-polyphosphate coacervates optionally cross-linked with gluteraldehyde; gelatin-gum Arabic coacervates; cross-linked silicone fluids; polyamine reacted with polyisocyanates; acrylate monomers polymerized via free radical polymerization, silk, wool, gelatine, cellulose, proteins, and mixtures thereof.

15. The method of claim 1 , wherein the microcapsule further comprises a shell material comprising a reaction product of a first substance in the presence of a second substance comprising an emulsifier, the first substance comprising a reaction product of i) an oil soluble or dispersible amine with ii) a multifunctional acrylate or methacrylate monomer or oligomer, an oil soluble acid and an initiator, the emulsifier comprising a water soluble or water dispersible acrylic acid alkyl acid copolymer, an alkali or alkali salt, and optionally a water phase initiator.

16. The method of claim 1 , wherein the consumer product is a fabric and home care composition.

17. The method of claim 1 , wherein the consumer product is a personal care composition.

18. The method of claim 1 , wherein the consumer product further comprises a malodor reducing agent selected from the group consisting of pantothenic acid, petrolatum, menthyl acetate, uncomplexed cyclodextrin, talc, silica, and mixtures thereof.

19. The method of claim 1 , wherein the first population of microcapsules and the second population of microcapsules have different partitioning modifiers.

20. The method of claim 1 , wherein the adjunct material comprises a surfactant.

21. The method of claim 1 , wherein the first perfume oil and the second perfume oil comprise at least one different material.

22. The method of claim 1 , wherein the first population and second population comprise different shell materials.

23. The method of claim 1 , wherein the first perfume oil and the second perfume oil are the same.

24. The method of claim 1 , wherein at least one of the first population of microcapsules and the second population of microcapsules is contained in an agglomerate prior to combining with the adjunct material.