IP Library Granted Patent US 11,099,136
Granted Patent B2
US 11,099,136 · App. 16/229,919 · Granted Aug 24, 2021

3D graphene optical sensors and methods of manufacture

Inventors: Kriti Agarwal (Uttar Pradesh, IN); Chunhui Dai (Minneapolis, MN); Jeong-Hyun Cho (Woodbury, MN)
Assignee: Regents of the University of Minnesota
G01N21/9009B82Y30/00C01B32/182C01B32/194G01N21/554G01N21/8806G01N21/9036H01L31/0203C01B2204/06G01N2021/869
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Quick Facts
Patent No.
US 11,099,136
App. No.
16/229,919
Granted
Aug 24, 2021
Kind
B2
Abstract

3D graphene optical sensors, such as microstructure sensors and nanostructure sensors. The 3D optical sensors include one or more graphene panels shaped to surround an interior, open volume. Graphene plasmons couple across the interior, open volume. The 3D optical sensors can have a polygonal shape or a cylindrical shape.

Claims (32)

1. An optical sensor for detecting the presence of a foreign material, the sensor comprising:

a plurality of panels each including a graphene membrane supported by a frame;

wherein the panels are arranged relative to one another to define a shape having an open, interior volume;

a plurality of joints, wherein respective ones of the joints interconnect opposing edges of immediately adjacent ones of the panels in the shape;

wherein graphene plasmons couple across the interior, open volume, and wherein plasmon in each of the membranes are coupled to one another.

2. The optical sensor of claim 1 , wherein the optical sensor is a microstructure.

3. The optical sensor of claim 1 , wherein the optical sensor is a nanostructure.

4. The optical sensor of claim 1 , wherein the graphene membrane includes at least one graphene layer.

5. The optical sensor of claim 1 , wherein each of the joints comprises a polymer material.

6. The optical sensor of claim 5 , wherein the polymer material has a reflow temperature in the range of approximately 100-170° C.

7. The optical sensor of claim 1 , wherein each of the frames comprises a polymer material.

8. The optical sensor of claim 1 , wherein at least one of the panels further comprises a metal pattern formed on the corresponding membrane.

9. The optical sensor of claim 1 , wherein the optical sensor has a shape selected from the group consisting of a multi-face cube, multi-faced pyramid, and single panel nanotube.

10. A method of fabricating an optical sensor, the method comprising:

forming a 2D net including panels each having a frame supporting a graphene membrane; and

subjecting the 2D net to thermal energy, causing the 2D net to self-transition into a 3D graphene sensor having an interior, open volume;

wherein the 3D graphene sensor includes a plurality of joints, wherein respective ones of the joints interconnect opposing edges of immediately adjacent ones of the panels in the shape;

wherein graphene plasmons couple across the interior, open volume and wherein plasmon in each of the membranes are coupled to one another.

11. The method of claim 10 , wherein each of the graphene membranes comprises graphene layers.

12. The method of claim 10 , wherein each of the joints comprises a polymer.

13. The method of claim 12 , wherein the step of heating includes subjecting the 2D net to a temperature of not greater than 200° C.

14. The method of claim 10 , wherein each of the frames comprises an epoxy.

15. The method of claim 10 , wherein prior to the step of heating, the method further comprising:

forming a metal pattern on the membrane of at least one of the panels.

16. The method of claim 10 , wherein the step of forming a 2D net further comprises:

depositing a protection layer over a sacrificial layer; and

depositing graphene over the protection layer so as to define the membrane of each of the panels.

17. The method of claim 16 , wherein the protection layer comprises a Cr sub-layer and an Al 2 O 3 sub-layer.

18. The method of claim 16 , wherein the step of forming a 2D net further comprises:

lifting the 2D net off of the sacrificial layer.

19. The method of claim 10 , wherein the step of forming a 2D net comprises defining a bottom protection layer on a substrate, depositing a graphene membrane onto the bottom protection layer, forming a top protection layer over the graphene membrane, and forming a sacrificial layer over the top protection layer; and further wherein the step of subjecting the 2D net to thermal energy comprises causing the sacrificial layer to melt and generate surface tension forces to curve the 2D net into a 3D cylinder.

20. The method of claim 19 , wherein the 3D cylinder has a shape selected from the group consisting of a partially curved cylinder, a nearly completely curved cylinder, and a completely curved cylinder.

Assignments (5)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 14, 2020
From: AGARWAL, KRITI
To: REGENTS OF THE UNIVERSITY OF MINNESOTA
Reel/Frame 053203/0724 →
CONFIRMATORY LICENSE Recorded Feb 27, 2020
From: UNIVERSITY OF MINNESOTA
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 052044/0951 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 28, 2019
From: DAI, CHUNHUI
To: REGENTS OF THE UNIVERSITY OF MINNESOTA
Reel/Frame 049623/0448 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 6, 2019
From: CHO, JEONG-HYUN
To: REGENTS OF THE UNIVERSITY OF MINNESOTA
Reel/Frame 049088/0516 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 13, 2019
From: AGARWAL, KRITI; DAI, CHUNHUI; CHO, JEONG-HYUN
To: REGENTS OF THE UNIVERSITY OF MINNESOTA
Reel/Frame 048588/0526 →
Continuity (2)
Provisional Application 62609813 · Dec 22, 2017
Related Publication 20190195809A1 · Jun 27, 2019
Cited By (1)
US 12,286,354