Laser welded body and method for manufacturing same
Provided is a laser welded body which can be manufactured without undergoing complicated steps and maintain the characteristics of a resin contained in a resin member, which exhibits high welding strength even when scanned with a laser beam at a high speed, and which can be manufactured at high production efficiency. The laser welded body 10 comprises a first resin member 1 which is a laser-irradiated subject which contains a thermoplastic resin and nigrosine sulfate and has an absorbance a 1 of 0.09 to 0.9; and a second resin member 2 which contains a thermoplastic resin as the same kind as or different kind from the thermoplastic resin and a laser beam absorbent, and has an absorbance a 2 of 3.0 to 15, wherein the first resin member 1 and the second resin member 2 are laser-welded at a part at which the both resin members are overlapped and/or butted.
1. A laser welded body comprising:
a first resin member which is a laser-irradiated subject, contains a thermoplastic resin and nigrosine sulfate and has an absorbance a 1 of 0.09 to 0.9 and
a second resin member which contains a thermoplastic resin as the same kind as or different kind from the thermoplastic resin and a laser beam absorbent and has an absorbance a 2 of 3.0 to 15,
wherein the first resin member and the second resin member are laser-welded at a part at which the both resin members are overlapped and/or butted and
a sulfate ion concentration of the nigrosine sulfate is 0.3 to 5.0% by mass.
2. The laser welded body according to claim 1 , wherein an absorbance ratio a 2 /a 1 of the absorbance a 2 to the absorbance a 1 is 5 to 70.
3. The laser welded body according to claim 1 , wherein the laser beam absorbent is nigrosine sulfate and/or carbon black.
4. The laser welded body according to claim 1 , wherein volume resistivity of the nigrosine sulfate is 5.0×10 9 to 7.0×10 11 Ω·cm.
5. The laser welded body according to claim 3 , wherein the carbon black has 12 to 40 nm of a primary particle size, and 150 to 380 m 2 /g of a nitrogen adsorption specific surface area.
6. The laser welded body according to claim 1 , wherein the thermoplastic resin is at least one selected from the group consisting of a polyamide resin, a polycarbonate resin, a polyphenylene sulfide resin, a polyethylene terephthalate resin, a polybutylene terephthalate resin and a polypropylene resin.
7. The laser welded body according to claim 1 , wherein the first resin member and/or the second resin member contain a coloring agent containing anthraquinone.
8. The laser welded body according to claim 7 , wherein the anthraquinone is an anthraquinone salt-forming dye.
9. The laser welded body according to claim 8 , wherein the anthraquinone salt-forming dye is represented by A − B + (A − is an anion from the anthraquinone and B + is a cation from an organic ammonium compound) or AB (A is a residue of the anthraquinone and B is a residue of an organic ammonium compound).
10. A method for producing a laser welded body comprising:
forming a faced part by overlapping and/or butting a first resin member which contains a thermoplastic resin and nigrosine sulfate of which a sulfate ion concentration is 0.3 to 5.0% by mass and has an absorbance a 1 of 0.09 to 0.9, and a second resin member which contains a thermoplastic resin as the same kind as or different kind from the thermoplastic resin and a laser beam absorbent and has an absorbance a 2 of 3.0 to 15 and
melting at least a part of the first resin member and the second resin member at the faced part by irradiating with a laser beam from a side of the first resin member to weld the first resin member and the second resin member.
11. The method for producing the laser welded body according to claim 10 comprising irradiating with the laser beam at a scan speed of 100 to 300 mm/second.