Cementitious reagents, methods of manufacturing and uses thereof
Described are cementitious reagent materials produced from globally abundant inorganic feedstocks. Also described are methods for the manufacture of such cementitious reagent materials and forming the reagent materials as microspheroidal glassy particles. Also described are apparatuses, systems and methods for the thermochemical production of glassy cementitious reagents with spheroidal morphology. The apparatuses, systems and methods makes use of an in-flight melting/quenching technology such that solid particles are flown in suspension, melted in suspension, and then quenched in suspension. The cementitious reagents can be used in concrete to substantially reduce the CO 2 emission associated with cement production.
1. A method for producing a cementitious reagent from aluminosilicate materials, comprising the steps of:
providing a solid aluminosilicate material;
milling the solid aluminosilicate material to have a particle size distribution with D[3,2] of less than 20 μm;
melting, by in-flight melting, of the aluminosilicate material in a kiln; and
quenching, by in-flight quenching, of the aluminosilicate material to produce solid microspheroidal glassy particles.
2. The method of claim 1 , wherein the solid microspheroidal glassy particles having a mean roundness (R) of at least 0.8.
3. The method of claim 1 , wherein the cementitious reagent has a molar composition ratios of (Ca,Mg) 0-12 .(Na,K) 0.05-1 .(Al, Fe 3+ ) 1 .Si 1-20 .
4. The method of claim 1 , further comprising controlling an in-flight quenching profile to produce the solid microspheroidal glassy particles that are greater than 80% X-ray amorphous.
5. The method of claim 1 , wherein the aluminosilicate material includes one or more of the elements Ca, Na, K, Al, Fe, and Si and further comprising the step of adjusting a composition of the aluminosilicate material to modify a content of one or more of the elements Ca, Na, K, Al, Fe, and Si.
6. The method of claim 1 , further comprising the step of locating the kiln at an aggregate quarry.
7. The method of claim 1 , further comprising the step of locating the kiln at a concrete batch plant.
8. The method of claim 1 , further comprising the step of locating the kiln at a mine.