Developing member, process cartridge and electrophotographic apparatus
An electrophotographic developing member includes an electro-conductive support and an electro-conductive layer provided on the support, wherein the electro-conductive layer has a matrix containing a first rubber and a plurality of domains dispersed in the matrix, and the domain contains a second rubber and an electronic conductive agent and when a frequency is log-log-plotted on a horizontal axis and an impedance is log-log-plotted on a vertical axis with respect to an impedance measured by applying an alternating current voltage having an amplitude of 1 V on the electro-conductive layer while changing a frequency between 1.0×10 −2 Hz to 1.0×10 7 Hz under a specific environment, an inclination of an impedance on a high frequency side is −0.8 or more and −0.3 or less and an impedance on a low frequency side is 1.0×10 4 Ω to 1.0×10 11 Ω.
1. An electrophotographic developing member comprising:
a support having an electro-conductive outer surface; and
an electro-conductive layer on the electro-conductive outer surface of the support, the electro-conductive layer having a matrix comprising a first rubber and domains dispersed in the matrix,
the domain each comprising a second rubber and an electronic conductive agent, wherein
assuming that a metal film is provided on an outer surface of the developing member, and an impedance is measured by applying an alternating current voltage having an amplitude of 1 V between the electro-conductive outer surface of the support and the metal film while varying a frequency between 1.0×10 −2 Hz to 1.0×10 −7 Hz under an environment of a temperature of 23° C. and a relative humidity of 50%, in a double logarithmic plot with a frequency on an abscissa and an impedance on an ordinate, a slope at a frequency of 1.0×10 6 Hz to 1.0×10 7 Hz is −0.8 or more and −0.3 or less, and an impedance at a frequency of 1.0×10 −2 Hz to 1.0×10 0 Hz is 1.0×10 4 Ω to 1.0×10 11 Ω.
2. The electrophotographic developing member according to claim 1 , wherein the electro-conductive layer is provided directly on the outer surface of the support.
3. The electrophotographic developing member according to claim 1 , further comprising an electro-conductive resin layer between the electro-conductive layer and the outer surface of the support, wherein
assuming that a metal film is provided on an outer surface of the resin layer, and an impedance is measured by applying an AC voltage having an amplitude of 1 V between the electro-conductive outer surface of the support and the metal film while varying a frequency between 1.0×10 −2 Hz to 1.0×10 7 Hz under an environment of a temperature of 23° C. and a relative humidity of 50%, in a double logarithmic plot with a frequency on an abscissa and an impedance on an ordinate, an impedance at a frequency of 1.0×10 −2 Hz to 1.0×10 0 Hz is 1.0×10 −5 Ω to 1.0×10 1 Ω.
4. The electrophotographic developing member according to claim 1 , wherein the matrix has a volume resistivity that is higher than 1.0×10 12 Ω·cm and is 1.0×10 17 Ω·cm or less.
5. The electrophotographic developing member according to claim 1 , wherein an arithmetic mean value Dm of inter-domain distances is 0.2 μm or more and 2.0 μm or less.
6. The electrophotographic developing member according to claim 1 , wherein the support is a cylindrical support, and the electro-conductive layer is provided on an outer surface of the cylindrical support.
7. The electrophotographic developing member according to claim 6 , wherein the electro-conductive layer has a thickness T of 100 μm or more, and wherein
assuming that three cross sections of the electroconductive layer in a thickness direction thereof at a center in the longitudinal direction of the electroconductive layer, and L/4 from both ends of the electroconductive layer toward the center, are obtained, where L represents a length of the electroconductive layer in the longitudinal direction of the cylindrical support, and
assuming that at each of the cross sections, an 15-μm square observation area is placed at arbitrary three positions in a thickness region from 0.1 T to 0.9 T in depth from the outer surface of the electroconductive layer,
among domains observed in each of the nine observation areas, 80% by number or more of the domains satisfy the following requirements (1) and (2):
(1) A ratio of a cross-sectional area of the electronic conductive agent contained in the domain to a cross-sectional area of the domain is 20% or more; and
(2) When defying a perimeter of the domain as A, and defining an envelope perimeter of the domain as B, A/B is 1.00 or more and 1.10 or less.
8. The developing member according to claim 1 , wherein when a mean value of ratios of cross-sectional areas of the electronic conductive agents contained in each of the domains to cross-sectional areas of each of the domains appearing in a cross section of the electro-conductive layer in the thickness direction is defined as μ, and a standard deviation of the ratios is defined as σ, σ/μ is 0 or more and 0.4 or less, and μ is 20% or more and 40% or less, and
at least eight of nine sample cubes sampled from any nine places of the electro-conductive layer, having one side of 9 and having a cubic shape satisfy the following requirement (3):
(3) When one sample cube is divided into 27 unit cubes whose one side is 3 μm and a volume Vd of the domains included in each of the unit cubes is calculated, the number of unit cubes in which Vd is 2.7 μm 3 to 10.8 μm 3 is at least 20.
9. An electrophotographic process cartridge comprising an electrophotographic developing member comprising: a support having an electro-conductive outer surface and an electro-conductive layer on the electro-conductive outer surface of the support,
the electro-conductive layer having a matrix comprising a first rubber and domains dispersed in the matrix, the domain each comprising a second rubber and an electronic conductive agent, wherein
assuming that a metal film is provided on an outer surface of the developing member, and an impedance is measured by applying an alternating current voltage having an amplitude of 1 V between the electro-conductive outer surface of the support and the metal film while varying a frequency between 1.0×10 −2 Hz to 1.0×10 7 Hz under an environment of a temperature of 23° C. and a relative humidity of 50%, in a double logarithmic plot with a frequency on an abscissa and an impedance on an ordinate, a slope at a frequency of 1.0×10 6 Hz to 1.0×10 7 Hz is −0.8 or more and −0.3 or less, and an impedance at a frequency of 1.0×10 −2 Hz to 1.0×10 0 Hz is 1.0×10 4 Ω to 1.0×10 11 Ω.
10. An electrophotographic image forming apparatus comprising a process cartridge comprising an electrophotographic developing member: comprising a support having an electro-conductive outer surface and an electro-conductive layer on the electro-conductive outer surface of the support,
the electro-conductive layer having a matrix comprising a first rubber and domains dispersed in the matrix, the domain each comprising a second rubber and an electronic conductive agent, wherein
assuming that a metal film is provided on an outer surface of the developing member, and an impedance is measured by applying an alternating current voltage having an amplitude of 1 V between the electro-conductive outer surface of the support and the metal film while varying a frequency between 1.0×10 −2 Hz to 1.0×10 7 Hz under an environment of a temperature of 23° C. and a relative humidity of 50%, in a double logarithmic plot with a frequency on an abscissa and an impedance on an ordinate, a slope at a frequency of 1.0×10 6 Hz to 1.0×10 7 Hz is −0.8 or more and −0.3 or less, and an impedance at a frequency of 1.0×10 −2 Hz to 1.0×10 0 Hz is 1.0×10 4 Ω to 1.0×10 11 Ω.