Producing thin films of nanoscale thickness by spraying precursor and supercritical fluid
Embodiments relate to forming a thin film of nanoscale thickness by depositing a mixture of a precursor and a supercritical fluid onto a surface of a substrate and removing the supercritical fluid from the surface of the substrate. The mixture is sprayed onto the surface by a spraying module. A layer of the precursor is formed on at least a portion of the surface. Molecules of the supercritical fluid is removed from the surface. The surface is exposed to plasma radical to transform the layer of the precursor into a solid thin film. In some embodiments, molecules of the precursor chemically bond with molecules of the supercritical fluid in the mixture. The molecules of the supercritical fluid can be decoupled from the molecules of the precursor before the layer of the precursor is formed.
1. A method for depositing a material onto a substrate, the method comprising:
spraying, by a spraying module, a mixture of a precursor for the material and a carrier fluid of a nonpolar material onto a surface of the substrate, wherein the carrier fluid is in a supercritical fluid state;
forming a layer of the precursor on the surface of the substrate, at least a portion of the surface coated with the layer of the precursor;
after forming the layer of the precursor on the surface, injecting pulses of the carrier fluid in the supercritical fluid state onto the layer of the precursor on the surface of the substrate, the pulses of the carrier fluid being in a gas state at the layer of the precursor on the surface of the substrate and driving molecules of the material of the carrier fluid to move away from the surface of the substrate; and
exposing the surface of the substrate to plasma radicals to transform the layer of the precursor to a solid film of the material.
2. The method of claim 1 , wherein the non-polar material of the carrier fluid is selected from a group consisting of: carbon dioxide, methane, ethane, propane, and ethylene.
3. The process of claim 1 , further comprising:
injecting an entraining gas through an opening of the spraying module, the injected entraining gas having a momentum for further driving the molecules of the supercritical fluid to move away from the surface.
4. The method of claim 3 , wherein the entraining gas comprises Nitrogen or Argon.
5. The method of claim 1 , wherein the precursor is selected from a group consisting of: DiMethylAluminum Isopropoxide (DMAI), 3-((Dimethylanimo)Propyl)Aluminumum) (DMPA), Dopamine-hydrochride, Methylene Diphenyl Diisocyanate (MDI), 4-Aminoethanol, Zinc Acetate Dihydrate, Terephthalic Acid, Triphenylene, 4-Aminothiolphenol, 4-Mercaptonphenol, Dimethylzinc (DMZ), and Trimethyl aluminum (TMA).
6. The method of claim 1 , wherein the layer of the precursor is a monolayer.
7. The method of claim 1 , wherein the solid film of the material has a thickness in a range from 1 nm to 100 nm.
8. The method of claim 1 , wherein the spraying module is placed under atmosphere pressure.
9. A method for depositing a material onto a substrate, the method comprising:
spraying, by a spraying module, a mixture of a precursor for the material and a supercritical fluid of a polar material onto a surface of the substrate, molecules of the precursor chemically bonding with molecules of the supercritical fluid;
exposing the mixture of the precursor and the supercritical fluid to charged particles or radiation, the charged particles or radiation decoupling chemical bonds between the molecules of the supercritical fluid and the molecules of the precursor;
after exposing the mixture of the precursor and the supercritical fluid to the charged particles or radiation, forming a layer of the precursor on the surface, at least a portion of the surface coated with the layer of the precursor; and
exposing the surface of the substrate to plasma radicals to transform the layer of the precursor to a solid film of the material.
10. The method of claim 9 , wherein the polar material of the supercritical fluid is selected from a group consisting of: oxidane, methanol, ethanol, and acetone.
11. The method of claim 9 , wherein decoupling the molecules of the supercritical fluid from the molecules of the precursor comprises:
exposing the mixture to charged particles, the charged particles breaking chemical bonds between the molecules of the supercritical fluid from the molecules of the precursor.
12. The method of claim 11 , wherein the charged particles comprise electrons, ions, or charged plasma radicals.
13. The method of claim 9 , wherein decoupling the molecules of the supercritical fluid from the molecules of the precursor comprises:
exposing the mixture to radiation, the radiation breaking chemical bonds between the molecules of the supercritical fluid from the molecules of the precursor.
14. The method of claim 13 , wherein the radiation is ultraviolet or microwave.
15. The method of claim 9 , further comprising removing the molecules of the material of the supercritical fluid from the surface by injecting an entraining gas or pulses of the supercritical fluid onto the surface, the entraining gas or pulses of the supercritical fluid driving the molecules of the supercritical fluid to move away from the surface.
16. The method of claim 9 , wherein the precursor is selected from a group consisting of: DiMethylAluminum Isopropoxide (DMAI), 3-((Dimethylanimo)Propyl)Aluminumum) (DMPA), Dopamine-hydrochride, Methylene Diphenyl Diisocyanate (MDI), 4-Aminoethanol, Zinc Acetate Dihydrate, Terephthalic Acid, Triphenylene, 4-Aminothiolphenol, 4-Mercaptonphenol, Dimethylzinc (DMZ), and Trimethyl aluminum (TMA).
17. The method of claim 9 , wherein the spraying module is placed under atmosphere pressure.