Positive electrode active material particle powder for non-aqueous electrolyte secondary battery, method for producing same, and non-aqueous electrolyte secondary battery
Positive electrode active material particle powder includes lithium manganese oxide particle powder having Li and Mn as main components and a cubic spinel structure with an Fd-3m space group. The lithium manganese oxide particle powder is composed of secondary particles, which are aggregates of primary particles, an average particle diameter (D50) of the secondary particles being from 4 μm to 20 μm, and at least 80% of the primary particles exposed on surfaces of the secondary particles each have a polyhedral shape in which each (111) plane thereof is adjacent to at least one (100) plane thereof.
1. A method of producing positive electrode active material particle powder for a non-aqueous electrolyte secondary battery, the method comprising:
mixing trimanganese tetroxide, a lithium compound, and a niobium compound or a molybdenum compound as a crystal plane growth suppressor to form a mixture; and
firing the mixture in an oxidizing atmosphere at a temperature from 700° C. to 950° C.,
wherein in X-ray diffraction analysis of the positive electrode active material particle powder, a cubic spinel phase composed of Li and Mn, and a phase of a compound of Nb and Li, or Mo and Li are present.
2. The method of claim 1 , wherein
the trimanganese tetroxide is composed of secondary particles, which are aggregates of primary particles, an average particle diameter (D50) of the secondary particles being from 3 μm to 20 μm, and crystallite size of the primary particles being from 50 nm to 150 nm.
3. The method of claim 1 , wherein
an amount of the crystal plane growth suppressor is from 0.3 mol % to 0.6 mol %.
4. The method of claim 1 , wherein
the positive electrode active material particle powder for a non-aqueous electrolyte secondary battery is a lithium manganate particle powder.
5. The method of claim 1 , wherein
in the mixing, the niobium compound or the molybdenum compound as the crystal plane growth suppressor reduces a ratio of a growth rate of planes other than a (111) plane to a growth rate of the (111) plane of lithium manganate particles having a cubic spinel structure.
6. The method of claim 1 , wherein
the positive electrode active material particle powder comprises a lithium manganese oxide particle powder having Li and Mn and a cubic spinel structure with an Fd-3m space group.