Carbon dioxide electrolytic device
A carbon dioxide electrolytic device of an embodiment includes: an anode part including an anode which oxidizes water or hydroxide ions to produce oxygen; a cathode part including a cathode which reduces carbon dioxide to produce a carbon compound, a cathode solution flow path which supplies a cathode solution to the cathode, and a gas flow path which supplies carbon dioxide to the cathode; a separator which separates the anode part and the cathode part; and a differential pressure control unit which controls a differential pressure between a pressure of the cathode solution and a pressure of the carbon dioxide so as to adjust a production amount of the carbon dioxide produced by a reduction reaction in the cathode part.
1. A method for electrolyzing carbon dioxide, comprising:
supplying carbon dioxide to a carbon dioxide supply flow path in an electrolysis cell, supplying a cathode solution to a cathode solution flow path in the electrolysis cell, and supplying an anode solution to an anode solution flow path in the electrolysis cell, the electrolysis cell having an anode, a cathode, the carbon dioxide supply flow path which supplies the carbon dioxide to the cathode, the cathode solution flow path which supplies the cathode solution to the cathode, the anode solution flow path which supplies the anode solution to the anode, and a separator to separate the anode and the cathode;
supplying an electric current from a power supply connected to the anode and the cat ode, to reduce the carbon dioxide and thus produce a carbon compound in a vicinity of the cathode, and to oxidize water or hydroxide ions and thus produce oxygen in a vicinity of the anode:
detecting a production amount of the carbon compound produced by a reduction reaction in the cathode; and
controlling a differential pressure between a pressure of the cathode solution and a pressure or the carbon dioxide so as to adjust the production amount of the detected carbon compound,
wherein the cathode has a gas diffusion layer disposed so as to contact with the carbon dioxide flowing in the carbon dioxide supply flow path, a cathode catalyst layer disposed so as to contact with the cathode solution flowing in the cathode solution flow path, and a porous layer which has a pore size smaller than that of the gas diffusion layer, and is disposed between the gas diffusion layer and the cathode catalyst layer,
wherein the cathode catalyst layer contains at least one selected from the group consisting of gold, silver, copper, platinum, palladium, nickel, cobalt, iron, manganese, titanium, cadmium, zinc, indium, gallium, and lead, and
wherein the differential pressure is controlled so that the pressure of the carbon dioxide flowing in the carbon dioxide supply flow path is larger than the pressure of the cathode solution flowing in the cathode solution flow path, and the differential pressure is 0.1 kPa more to 10 kPa or less.
2. The method according to claim 1 , wherein
the carbon dioxide is reduced to produce the carbon compound while water is reduced to produce hydrogen M the vicinity of the cathode, and
the differential pressure is controlled so that a reduction reaction of the carbon dioxide preferentially occurs than a reduction reaction of the water.
3. The method according to claim 1 , wherein
the carbon dioxide is reduced to produce carbon monoxide while water is reduced to produce hydrogen in the vicinity of the cathode, and
the differential pressure is controlled so that Faraday's efficiency of the carbon monoxide is larger than Faraday's efficiency of the hydrogen.
4. The method according to claim 1 , wherein
the cathode has a first surface facing the cathode solution flow path and a second surface facing the carbon dioxide supply flow path, and the cathode solution flow path is disposed between the separator and the cathode so that the cathode solution is in contact with the separator and the cathode.
5. The method according to claim 1 , wherein
the anode solution and the cathode solution contain at least one ion selected from the group consisting of a hydroxide ion, a hydrogen ion, a potassium ion, a sodium ion, a lithium a chloride ion, a bromide ion, an iodide ion, a nitrate ion, a sulfate ion, a phosphate ion, a borate ion, and a hydrogen carbon ion.
6. The method according to claim 1 , wherein
the carbon compound to be produced by a reduction reaction of the carbon dioxide contains at least one selected from the group consisting of carbon monoxide, methane, ethane, ethylene, methanol, ethanol, and ethylene glycol.
7. The method according to claim 1 , wherein
the carbon dioxide supply flow path has a gas inlet port connected to a carbon dioxide supply unit and a gas outlet port connected to a product collection unit collecting a reduction product which is produced b the cathode.