Direct metal printing with stereolithography
View Patent ↗An additive manufacturing process for forming a metallic layer on the surface of the substrate includes fabricating a substrate from a polymerizable composition by a stereolithographic process, and contacting the reactive surface with an aqueous solution including a metal precursor. The metal precursor includes a metal, and the polymerizable composition includes a multiplicity of multifunctional components. Each multifunctional component includes a reactive moiety extending from a surface of the substrate to form a reactive surface. An interface between the reactive surface and the aqueous solution is irradiated to form nanoparticles including the metal. The nanoparticles are chemically coupled to the reactive surface by reactive moieties, thereby forming a metallic layer on the surface of the substrate.
1. A method of additive manufacturing, the method comprising:
fabricating a substrate from a polymerizable composition by a stereolithographic process, wherein the polymerizable composition comprises a multiplicity of multifunctional components, each multifunctional component comprising a reactive moiety, and each reactive moiety extends from a surface of the substrate to form a reactive surface; wherein
the multifunctional component comprises allylamine; and
the reactive moiety comprises amine;
contacting the reactive surface with an aqueous solution comprising a metal precursor, wherein the metal precursor comprises a metal;
irradiating an interface between the reactive surface and the aqueous solution to form nanoparticles comprising the metal; and
chemically coupling the nanoparticles to the reactive surface by the reactive moieties, thereby forming a metallic layer comprising the metal on the surface of the substrate.
2. The method of claim 1 , wherein the polymerizable composition comprises an acrylate monomer.
3. The method of claim 2 , wherein the acrylate monomer comprises a diacrylate monomer.
4. The method of claim 3 , wherein the diacrylate monomer comprises 1,6-hexanediol diacrylate.
5. The method of claim 1 , wherein the polymerizable composition comprises a photoinitiator.
6. The method of claim 5 , wherein the photoinitiator comprises phenylbis(2,4,6-trimethylbenzoyl) phosphine oxide.
7. The method of claim 1 , wherein the metal is a transition metal.
8. The method of claim 7 , wherein the metal is silver.
9. The method of claim 1 , wherein the aqueous solution further comprises a chelating agent.
10. The method of claim 9 , wherein the chelating agent comprises citrate.
11. The method of claim 1 , further comprising forming an additional metallic layer on the surface.
12. The method of claim 1 , wherein a conductance of the metallic layer is the same order of magnitude as a conductance of the metal in bulk form.
13. The method of claim 1 , wherein the metallic layer forms a continuous film on the substrate.
14. The method of claim 13 , wherein the continuous film comprises a multiplicity of nanoparticles, nanoparticle aggregates, or both.
15. The method of claim 14 , wherein a dimension of the continuous film exceeds a dimension of the nanoparticles by at least a factor of 1000.
16. The method of claim 14 , wherein a dimension of the metallic layer is at least 1 cm.
17. The method of claim 1 , wherein a resolution of the metallic layer is up to 10 μm.
18. The method of claim 1 , wherein the metallic layer is formed under ambient conditions.
19. The method of claim 1 , wherein the substrate is an organic polymer or a hydrogel.