UV-curable ink jet ink composition
A UV-curable ink jet ink composition includes: 10.00% by mass or more and 60.00% by mass or less, relative to a total mass of the ink composition, of a compound represented by formula (A); 10.00% by mass or more and 50.00% by mass or less, relative to the total mass of the ink composition, of one or more monofunctional monomers having an alicyclic hydrocarbon group or a cyclic ether group; 0.05% by mass or more and 0.50% by mass or less, relative to the total mass of the ink composition, of one or more fluorescent brighteners including a compound represented by formula (b1), (b2), (b3), or (b4); and 3.00% by mass or more and 8.00% by mass or less, relative to the total mass of the ink composition, of one or more acylphosphine oxide polymerization initiators.
1. A UV-curable ink jet ink composition comprising:
10.00% by mass or more and 60.00% by mass or less, relative to a total mass of the ink composition, of a compound represented by the following formula (A):
CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 (A)
wherein R 1 is a hydrogen atom or a methyl group, R 2 is a divalent organic residue having 2 to 20 carbon atoms, and R 3 is a hydrogen atom or a monovalent organic residue having 1 to 11 carbon atoms;
10.00% by mass or more and 50.00% by mass or less, relative to the total mass of the ink composition, of one or more monofunctional monomers having an alicyclic hydrocarbon group or a cyclic ether group;
0.05% by mass or more and 0.50% by mass or less, relative to the total mass of the ink composition, of one or more fluorescent brighteners including a compound represented by the following formula (b1), (b2), (b3), or (b4):
and
3.50% by mass or more and 6.00% by mass or less, relative to the total mass of the ink composition, of one or more acylphosphine oxide polymerization initiators.
2. The UV-curable ink jet ink composition according to claim 1 , wherein the monofunctional monomers having an alicyclic hydrocarbon group or a cyclic ether group include isobornyl (meth)acrylate, tetrahydrofurfuryl (meth)acrylate, cyclic trimethylolpropane formal (meth)acrylate, or 3,3,5-trimethylcyclohexyl (meth)acrylate.
3. The UV-curable ink jet ink composition according to claim 1 , further comprising:
5.00% by mass or more and 40.00% by mass or less, relative to the total mass of the ink composition, of a monomer having a hydroxy group.
4. The UV-curable ink jet ink composition according to claim 1 , wherein the fluorescent brighteners include a compound represented by the formula (b1) or (b2).
5. The UV-curable ink jet ink composition according to claim 1 , wherein the fluorescent brighteners include a compound represented by the formula (b1).
6. The UV-curable ink jet ink composition according to claim 1 , wherein the acylphosphine oxide polymerization initiators include a bisacylphosphine oxide polymerization initiator.
7. The UV-curable ink jet ink composition according to claim 1 , further comprising:
3.00% by mass or more and 10.00% by mass or less, relative to the total mass of the ink composition, of a urethane (meth)acrylate oligomer.
8. The UV-curable ink jet ink composition according to claim 1 , further comprising a colored colorant.
9. The UV-curable ink jet ink composition according to claim 1 , further comprising a sensitizer having a molecular weight of 700 or more.
10. An ink jet recording method comprising:
a discharge step of discharging the UV-curable ink jet ink composition according to claim 1 onto a recording medium from a head; and
a curing step of curing the UV-curable ink jet ink composition attached to the recording medium by irradiating with UV from a UV light-emitting diode having a peak wavelength within a range of 360 nm or more and 420 nm or less.