Device for estimating degradation of secondary cell, and method for estimating degradation of secondary cell

1. A secondary battery deterioration estimation device estimating deterioration of a secondary battery, comprising:

a processor; and

a memory that stores executable instructions that, when executed by the processor, facilitate performance of operations, comprising:

receiving a first signal representing a discharging voltage from a voltage detector;

receiving a second signal representing a discharging current from a current detector;

calculating values of elements forming an equivalent circuit of the secondary battery;

calculating a state of health (SOH) of the secondary battery based on the values of the elements forming the equivalent circuit;

generating history information showing history of a use state of the secondary battery;

calculating the SOH of the secondary battery based on the history information;

determining a deterioration state of the secondary battery with reference to at least one of the SOH calculated by the values of the elements or the SOH calculated by the history information in accordance with a state of the secondary battery;

in response to determining that a value of the SOH based on the values of the elements forming the equivalent circuit or the SOH calculated by the history information has fallen below a threshold value, switching the SOH to be referred to in accordance with the deterioration state of the secondary battery; and

outputting data representing the deterioration state of the secondary battery.

2. The secondary battery deterioration estimation device according to claim 1 , wherein the operations further comprise:

determining the deterioration state of the secondary battery with reference to the SOH calculated by the values of the elements when the secondary battery is a new article, and the SOH calculated by the history information when the secondary battery deteriorates.

3. The secondary battery deterioration estimation device according to claim 2 , wherein the operations further comprise:

selecting the SOH calculated by the history information as a reference destination when it is determined that the secondary battery deteriorates based on the values of the elements forming the equivalent circuit or the history information.

4. The secondary battery deterioration estimation device according to claim 3 , wherein the operations further comprise:

switching the reference destination from the SOH calculated by the values of the elements to the SOH calculated by the history information when it is determined that there is a variation in deterioration among cells of the secondary battery.

5. The secondary battery deterioration estimation device according to claim 1 , wherein the operations further comprise:

determining the deterioration state of the secondary battery through correction of the SOH calculated by the values of the elements with the SOH calculated by the history information.

6. The secondary battery deterioration estimation device according to claim 5 , wherein the operations further comprise:

correcting the SOH calculated by the values of the elements based on the SOH calculated by the history information when it is determined that the secondary battery deteriorates based on the SOH calculated by the values of the elements.

7. The secondary battery deterioration estimation device according to claim 1 , wherein the operations further comprise:

generating information showing charge and discharge of the secondary battery based on a signal from a current sensor which detects a current flowing through the secondary battery, and calculates the SOH based on the generated history information.

8. The secondary battery deterioration estimation device according to claim 7 , wherein the secondary battery is mounted on a vehicle, and wherein the operations further comprise:

detecting a running time and a stop time of the vehicle;

generating the history information with reference to the detected running time and stop time; and

calculating the SOH based on the generated history information.

9. The secondary battery deterioration estimation device according to claim 8 , wherein the operations further comprise:

detecting an internal resistance and a decreased mass of solution of the secondary battery;

generating the history information with reference to the detected internal resistance and the decreased mass of solution; and

calculating the SOH based on the generated history information.

10. The secondary battery deterioration estimation device according to claim 1 , wherein the secondary battery is mounted on a vehicle, and wherein the operations further comprise:

detecting and setting at least one of a running time and a stop time of the vehicle, and a charge time, a discharge time, a charge amount, a discharge amount, an internal resistance, and a decreased mass of solution of the secondary battery as a first parameter;

detecting and setting at least one of a state of charge, an internal temperature, a temperature difference between an environmental temperature and the internal temperature, a quantity of stratification, a quantity of polarization, and a current change rate per a unit time as a second parameter;

calculating a correction coefficient based on the second parameter;

correcting the first parameter by using the correction coefficient; and

calculating the SOH based on multiplying the corrected first parameter by a weighting coefficient.

11. The secondary battery deterioration estimation device according to claim 1 , wherein the operations further comprise:

outputting a warning when a value of the SOH obtained is smaller than a predetermined threshold value.

12. A secondary battery deterioration estimation device estimating deterioration of a secondary battery, comprising:

a unit which calculates values of elements forming an equivalent circuit of the secondary battery;

a unit which calculates a state of health (SOH) of the secondary battery based on the values of the elements forming the equivalent circuit;

a unit which generates history information showing history of a use state of the secondary battery;

a unit which calculates the SOH of the secondary battery based on the history information;

a unit which determines a deterioration state of the secondary battery with reference to at least one of the SOH calculated by the values of the elements or the SOH calculated by the history information in accordance with a state of the secondary battery; and

a unit which, in response to determining that a value of the SOH based on the values of the elements forming the equivalent circuit or the SOH calculated by the history information has fallen below a threshold value, switches the SOH to be referred to in accordance with the deterioration state of the secondary battery.

13. A secondary battery deterioration estimation method estimating deterioration of the secondary battery, comprising:

receiving, by a programmable processor connected to a voltage sensor detecting a discharging voltage of the secondary battery and to a current sensor detecting a discharging current of the secondary battery, a first signal representing the discharging voltage from the voltage sensor;

receiving, by the programmable processor, a second signal representing the discharging current from the current sensor;

calculating, by the programmable processor, values of elements forming an equivalent circuit of the secondary battery based on the first and second signals;

calculating, by the programmable processor, a state of health (SOH) of the secondary battery based on the values of the elements forming the equivalent circuit;

generating, by the programmable processor, history information showing history of a use state of the secondary battery;

calculating, by the programmable processor, the SOH of the secondary battery based on the history information;

determining, by the programmable processor, a deterioration state of the secondary battery with reference to at least one of the SOH calculated by the values of the elements or the SOH calculated by the history information in accordance with a state of the secondary battery;

in response to determining, by the programmable processor, that a value of the SOH based on the values of the elements forming the equivalent circuit or the SOH calculated by the history information has fallen below a threshold value, switching the SOH to be referred to in accordance with the deterioration state of the secondary battery; and

outputting, by the programmable processor, data representing the deterioration state of the secondary battery.

14. The secondary battery deterioration estimation device according to claim 1 , wherein the operations further comprise:

performing the switching of the SOH to be referred to in accordance with the state of the secondary battery when it is determined that there is a variation in deterioration among cells of the secondary battery.

15. The secondary battery deterioration estimation device according to claim 12 , wherein:

the unit which switches the SOH to be referred to in accordance with the state of the secondary battery performs the switching when it is determined that there is a variation in deterioration among cells of the secondary battery.

16. The secondary battery deterioration estimation device according to claim 15 , wherein:

the unit which determines the deterioration state of the secondary battery performs the determining with reference to the SOH calculated by the values of the elements when the secondary battery is a new article, and the SOH calculated by the history information when the secondary battery deteriorates.

17. The secondary battery deterioration estimation device according to claim 15 , wherein

the unit which switches the SOH to be referred to in accordance with the state of the secondary battery selects the SOH calculated by the history information as a reference destination when it is determined that the secondary battery deteriorates based on the values of the elements forming the equivalent circuit or the history information.

18. The secondary battery deterioration estimation method according to claim 13 , further comprising:

performing, by the programmable processor, the switching the of the SOH to be referred to in accordance with the state of the secondary battery when it is determined that there is a variation in deterioration among cells of the secondary battery.

19. The secondary battery deterioration estimation method according to claim 18 , wherein:

performing, by the programmable processor, the determining of the deterioration state of the secondary battery with reference to the SOH calculated by the values of the elements when the secondary battery is a new article, and the SOH calculated by the history information when the secondary battery deteriorates.

20. The secondary battery deterioration estimation method according to claim 18 , wherein

selecting, by the programmable processor, the SOH by the history information as a reference destination when it is determined that the secondary battery deteriorates based on the values of the elements forming the equivalent circuit or the history information.