Latent heat storage material composition
In a latent heat storage material composition prepared by mixture of a latent heat storage material with an additive that adjusts the physical properties of the latent heat storage material, the latent heat storage material includes an inorganic salt hydrate containing nw (2≤nw) molecules of hydration water. The additive is a melting point modifier for adjusting the melting point of the latent heat storage material and is a substance belonging to a sugar alcohol, and is a substance having the physical property of producing negative dissolution heat upon dissolution in hydration water contained in the latent heat storage material. In a whole amount of the latent heat storage material composition, the substance belonging to a sugar alcohol has a concentration that satisfies formulae (1) and (2) per 1 mole of water of hydration of the latent heat storage material. Formula (2): 0.01≤xs≤1.
1. A latent heat storage material composition prepared by a mixture of a latent heat storage material capable of storing or releasing heat and an additive capable of adjusting a property of the latent heat storage material, wherein
the latent heat storage material comprises at least one inorganic salt hydrate containing n w molecules of hydration water, wherein 2≤n w ,
the additive is a melting point modifier configured to adjust a melting point of the latent heat storage material, the melting point modifier being a substance having a property to generate negative dissolution heat upon dissolution in the latent heat storage material,
the melting point modifier contains at least a substance belonging to a sugar alcohol as a first additive and a sulfate salt as a second additive that is different from the first additive,
a melt of the latent heat storage material composition is a mixture of the latent heat storage material with the melting point modifier which is produced as a result of dissolution of the sugar alcohol and the sulfate salt contained in the melting point modifier in the hydration water contained in the latent heat storage material, and
the substance belonging to a sugar alcohol has a concentration that satisfies formulae (1) and (2) per 1 mol of the hydration water in the latent heat storage material in a whole amount of the latent heat storage material composition:
x s =( m s /M s )/Σ k=1 N ( n wk ×m ak /M ak ) Formula (1)
0.01≤ x s ≤1 Formula (2)
wherein:
x s : the number of moles of the “substance belonging to a sugar alcohol” per 1 mol of hydration water [mol/mol];
m s : the mass of the “substance belonging to a sugar alcohol” contained in the latent heat storage material composition [g];
M s : the molecular weight of the “substance belonging to a sugar alcohol” [g/mol];
N: the total number of the latent heat storage materials constituting the latent heat storage material composition;
n wk : the hydration number of the latent heat storage material (k=1, 2, . . . , N);
m ak : the mass of the latent heat storage material contained in the latent heat storage material composition [g] (k=1, 2, . . . , N); and
M ak : the molecular weight of the latent heat storage material [g/mol] (k=1, 2, . . . , N), and
the sulfate salt has a concentration that satisfies formulae (3) and (4) per 1 mol of the hydration water in the latent heat storage material in a whole amount of the latent heat storage material composition,
the substance belonging to a sugar alcohol comprises at least one of erythritol (C 4 H 10 O 4 ), xylitol (C 5 H 12 O 5 ), and mannitol (C 6 H 14 O 6 ):
x t ( m t /M t )/Σ k=1 N ( n wk ×m ak /M ak ) Formula (3)
0< x t ≤0.1 Formula (4)
wherein:
x t : the number of moles of the sulfate salt per 1 mol of hydration water [mol/mol];
m t : the mass of the sulfate salt contained as the second additive in the latent heat storage material composition [g];
M t : the molecular weight of the sulfate salt that serves as the second additive [g/mol];
N: the total number of the latent heat storage materials constituting the latent heat storage material composition;
n wk : the hydration number of the latent heat storage material (k=1, 2, . . . , N);
m ak : the mass of the latent heat storage material contained in the latent heat storage material composition [g] (k=1, 2, . . . , N); and
M ak : the molecular weight of the latent heat storage material [g/mol] (k=1, 2, . . . , N).
2. The latent heat storage material composition according to claim 1 , wherein the sulfate salt is ammonium sulfate ((NH 4 ) 2 SO 4 ).
3. The latent heat storage material composition according to claim 1 , wherein the inorganic salt hydrate is a hydroxymethanesulfinate salt.
4. The latent heat storage material composition according to claim 3 , wherein the hydroxymethanesulfinate salt is sodium hydroxymethanesulfinate dihydrate (CH 3 NaO 3 S.2H 2 O).
5. The latent heat storage material composition according to claim 1 , wherein the inorganic salt hydrate is an acetate salt.
6. The latent heat storage material composition according to claim 5 , wherein the acetate salt is sodium acetate trihydrate (CH 3 COONa.3H 2 O).
7. The latent heat storage material composition according to claim 1 , wherein the inorganic salt hydrate is a diphosphate salt or a phosphate salt.
8. The latent heat storage material composition according to claim 7 , wherein the diphosphate salt is sodium diphosphate decahydrate (Na 4 P 2 O 7 .10H 2 O).
9. The latent heat storage material composition according to claim 1 , wherein the inorganic salt hydrate is alum hydrate.
10. The latent heat storage material composition according to claim 9 , wherein the alum hydrate is ammonia alum dodecahydrate (AlNH 4 (SO 4 ) 2 .12H 2 O) or potassium alum dodecahydrate (AlK(SO 4 ) 2 .12H 2 O).
11. The latent heat storage material composition according to claim 1 , wherein the inorganic salt hydrate is a sulfate hydrate.
12. The latent heat storage material composition according to claim 11 , wherein the sulfate hydrate is aluminum sulfate hydrate (Al 2 (SO 4 ) 3 .nH 2 O), wherein 2 n.