Nanocellulose composite, and method for manufacturing same
Provided are nanocellulose composite and preparation method thereof. The method comprises preparing cellulose nanofiber, mixing the cellulose nanofiber with a silica precursor in a solvent to attach silica particles to the surface of the cellulose nanofiber, or to form a silica coating layer on the surface of the cellulose nanofiber, and mixing the cellulose nanofiber with the silica particles or the silica coating layer with a polymer. According to the present invention, by using surface vitrification-treated nano cellulose, nanocellulose polymer composites that exhibits high mechanical properties such as impact resistance as well as excellent heat resistance can be prepared.
1. A method for preparing nanocellulose polymer composite, the method comprising:
preparing a cellulose nanofiber;
mixing the cellulose nanofiber with a silica precursor in a solvent to form silica on at least a portion of the surface of the cellulose nanofiber; and
mixing the cellulose nanofiber with the silica on the surface with a polymer to produce the nanocellulose polymer composite which includes a polymer matrix and the cellulose nanofibers with the silica on the surface dispersed in the polymer matrix,
wherein the cellulose nanofibers are separated from each other due to the silica formed on the surface in the polymer matrix and the polymer matrix is disposed between the silica.
2. The method according to claim 1 , wherein the silica is silica particles attached to the surface of the cellulose nanofiber.
3. The method according to claim 2 , wherein, to attach the silica particles to the surface of the cellulose nanofiber, the cellulose nanofiber is mixed with the silica precursor in an organic solvent.
4. The method according to claim 2 , wherein the silica particles have an average diameter of 0.1 to 5 times the diameter of the cellulose nanofibers.
5. The method according to claim 1 , wherein the silica is a silica coating layer formed on the surface of the cellulose nanofiber.
6. The method according to claim 5 , wherein, to form the silica coating layer on the surface of the cellulose nanofiber, the cellulose nanofiber is mixed with the silica precursor in water.
7. The method according to claim 6 , wherein, a polar organic solvent is further added to the mixture of the cellulose nanofiber and the silica precursor in water.
8. The method according to claim 5 , wherein the silica coating layer formed on the cellulose nanofiber surface has a bumpy surface.
9. The method according to claim 1 , further comprising drying the cellulose nanofiber with the silica before mixing the cellulose nanofiber with the polymer, and
wherein the polymer is in a molten state when mixed with the dried cellulose nanofibers.