Alignment film, liquid crystal panel, and method for producing liquid crystal panel

1. An alignment film comprising:

at least one selected from the group consisting of a polyamic acid containing at least one structure represented by the following formula (PA-1) and a polyimide containing at least one structure represented by the following formula (PI-1),

wherein Bs are the same as or different from each other and are each a divalent group containing at least one of the structures represented by the following formulae (B1-1) to (B1-11);

Xs are the same as or different from each other and are each a tetravalent group represented by the following formula (X-4) or (X-9); and p is an integer of 1 or greater,

wherein Rs are the same as or different from each other and are each a hydrogen atom or a C1-C12 alkyl group; Qs are the same as or different from each other and are each a hydrogen atom, a fluorine atom, a chlorine atom, or a bromine atom; and at least one hydrogen atom of an alkyl group is optionally replaced by a fluorine atom; and

a polymer that vertically aligns liquid crystal molecules or a polymer that horizontally aligns liquid crystal molecules,

wherein the polymer that vertically aligns liquid crystal molecules and the polymer that horizontally aligns liquid crystal molecules each contain at least one of the structures represented by the following formulae (PS-1) to (PS-3):

wherein as are the same as or different from each other and are each a hydrogen atom, a hydroxy group, or a C1-C5 alkoxy group; Bs are the same as or different from each other and are each a monovalent group containing a cinnamate group; and p, q, and r are each individually an integer of 1 or greater, with q and r satisfying 0<r/(q+r)<1

wherein βs are the same as or different from each other and are each a monovalent group containing a cinnamate group; γs are the same as or different from each other and are each a hydrogen atom or a C1-C5 alkyl group; and p, q, and r are each individually an integer of 1 or greater, with q and r satisfying 0<r/(q+r)<1.

2. The alignment film according to claim 1 , further comprising a different polymer containing a photo-alignment functional group,

wherein the photo-alignment functional group includes at least one group selected from the group consisting of cinnamate, azobenzene, coumarin, chalcone, and cyclobutene groups.

3. A liquid crystal panel comprising:

the alignment film according to claim 1 ;

a first substrate;

a second substrate facing the first substrate; and

a liquid crystal layer between the first substrate and the second substrate,

the alignment film being disposed on a surface of at least one substrate selected from the group consisting of the first substrate and the second substrate, the surface being adjacent to the liquid crystal layer.

4. The liquid crystal panel according to claim 3 ,

wherein the at least one substrate provided with the alignment film selected from the first substrate and the second substrate includes an insulation film containing at least one selected from the group consisting of a positive resist and a photo-reaction product thereof.

5. The liquid crystal panel according to claim 4 ,

wherein the positive resist contains a naphthoquinone diazide compound.

6. The liquid crystal panel according to claim 3 , further comprising a polymer layer.

7. The alignment film according to claim 6 ,

wherein the polymer layer is a layer formed by polymerizing a polymerizable monomer containing at least one of the structures represented by the following formulae (M1-1) to (M1-3):

8. The alignment film according to claim 1 ,

wherein the polyamic acid is a polymer represented by the following formula (PA-11), and

the polymer that vertically aligns liquid crystal molecules is a polymer represented by the following formula (PS-11),

wherein p is an integer of 1 or greater,

wherein p is an integer of 1 or greater.

9. An alignment film comprising:

at least one selected from the group consisting of a polyamic acid containing at least one structure represented by the following formula (PA-2) and a polyimide containing at least one structure represented by the following formula (PI-2),

wherein Bs are the same as or different from each other and are each a divalent group containing at least one of the structures represented by the following formulae (B1-1) to (B1-11);

Xs are the same as or different from each other and are each a tetravalent group represented by the following formula (X-4) or (X-9); Ys are the same as or different from each other and are each a divalent group represented by the following formulae (Y-1) to (Y-42); and m, n, and p are each individually an integer of 1 or greater, with m and n satisfying 0<m/(m+n)<1,

wherein Rs are the same as or different from each other and are each a hydrogen atom or a C1-C12 alkyl group; Qs are the same as or different from each other and are each a hydrogen atom, a fluorine atom, a chlorine atom, or a bromine atom; and at least one hydrogen atom of an alkyl group is optionally replaced by a fluorine atom,

a polymer that vertically aligns liquid crystal molecules or a polymer that horizontally aligns liquid crystal molecules,

wherein the polymer that vertically aligns liquid crystal molecules and the polymer that horizontally aligns liquid crystal molecules each contain at least one of the structures represented by the following respective formulae (PS-1) to (PS-3):

wherein αs are the same as or different from each other and are each a hydrogen atom, a hydroxy group, or a C1-C5 alkoxy group; βs are the same as or different from each other and are each a monovalent group containing a cinnamate group; and p, q, and r are each individually an integer of 1 or greater, with q and r satisfying 0<r/(q+r)<1,

wherein βs are the same as or different from each other and are each a monovalent group containing a cinnamate group; γs are the same as or different from each other and are each a hydrogen atom or a C1-C5 alkyl group; and p, q, and r are each individually an integer of 1 or greater, with q and r satisfying 0<r/(q+r)<1.

10. The alignment film according to claim 9 ,

wherein the polyamic acid is a polymer represented by the following formula (PA-12):

wherein m, n, and p are each individually an integer of 1 or greater, with m and n satisfying 0.2≤m/(m+n) <1.

11. The alignment film according to claim 9 ,

wherein the polyamic acid is a polymer represented by the following formula (PA-13):

wherein m, n, and p are each individually an integer of 1 or greater, with m and n satisfying 0.2≤m/(m+n)<1.

12. The alignment film according to claim 9 , further comprising a different polymer containing a photo-alignment functional group,

wherein the photo-alignment functional group includes at least one group selected from the group consisting of cinnamate, azobenzene, coumarin, chalcone, and cyclobutene groups.

13. A liquid crystal panel comprising:

the alignment film according to claim 9 ;

a first substrate;

a second substrate facing the first substrate; and

a liquid crystal layer between the first substrate and the second substrate,

the alignment film being disposed on a surface of at least one substrate selected from the group consisting of the first substrate and the second substrate, the surface being adjacent to the liquid crystal layer.

14. The liquid crystal panel according to claim 13 ,

wherein the at least one substrate provided with the alignment film selected from the first substrate and the second substrate includes an insulation film containing at least one selected from the group consisting of a positive resist and a photo-reaction product thereof.

15. The liquid crystal panel according to claim 14 , wherein the positive resist contains a naphthoquinone diazide compound.

16. The liquid crystal panel according to claim 13 , further comprising a polymer layer.

17. The alignment film according to claim 16 ,

wherein the polymer layer is a layer formed by polymerizing a polymerizable monomer containing at least one of the structures represented by the following formulae (M1-1) to (M1-3):