IP Library Granted Patent US 11,158,786
Granted Patent B2
US 11,158,786 · App. 16/582,762 · Granted Oct 26, 2021

MRAM device formation with controlled ion beam etch of MTJ

Inventors: Ashim Dutta (Menands, NY); Chih-Chao Yang (Glenmont, NY); Lijuan Zou (Slingerlands, NY); John Arnold (North Chatham, NY)
Assignee: International Business Machines Corporation
H01L43/12H01L27/222H01L43/02H01L43/10
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Quick Facts
Patent No.
US 11,158,786
App. No.
16/582,762
Granted
Oct 26, 2021
Kind
B2
Abstract

Controlled IBE techniques for MRAM stack patterning are provided. In one aspect, a method of forming an MRAM device includes: patterning an MRAM stack disposed on a dielectric into individual memory cells using IBE landing on the dielectric while dynamically adjusting an etch time to compensate for variations in a thickness of the MRAM stack, wherein each of the memory cells includes a bottom electrode, an MTJ, and a top electrode; removing foot flares from the bottom electrode of the memory cells which are created during the patterning of the MRAM stack; removing residue from sidewalls of the memory cells which includes metal redeposited during the patterning of the MRAM stack and during the removing of the foot flares; and covering the memory cells in a dielectric encapsulant. An MRAM device is also provided.

Claims (32)

1. A method of forming a magnetic random access memory (MRAM) device, the method comprising:

patterning an MRAM stack disposed on a dielectric into individual memory cells using ion beam etching (IBE) landing on the dielectric while endpoint detection is used for dynamically adjusting an etch time to compensate for variations in a thickness of the MRAM stack, wherein each of the memory cells as-patterned comprises a bottom electrode disposed on the dielectric, a magnetic tunnel junction (MTJ) disposed on the bottom electrode, and a top electrode disposed on the MTJ;

removing foot flares from the bottom electrode of the memory cells, wherein the foot flares are created during the patterning of the MRAM stack;

removing residue from sidewalls of the memory cells, wherein the residue comprises metal redeposited during the patterning of the MRAM stack and during the removing of the foot flares; and

covering the memory cells in a dielectric encapsulant.

2. The method of claim 1 , further comprising:

monitoring an optical emission signal while the MRAM stack is being patterned.

3. The method of claim 1 , wherein the dielectric comprises a silicon (Si)-containing dielectric.

4. The method of claim 3 , wherein the Si-containing dielectric is selected from the group consisting of: silicon carbonitride (SiCN(H)), silicon oxide (SiOx), silicon nitride (SiN), silicon oxycarbide (SiCOH), and combinations thereof.

5. The method of claim 3 , further comprising:

monitoring an optical emission signal while the MRAM stack is being patterned; and

endpointing the IBE when a change in the optical emission signal is detected corresponding to an optical emission wavelength of Si.

6. The method of claim 5 , wherein the optical emission wavelength of Si is from about 250.6 nm to about 252.8 nm, and ranges therebetween.

7. The method of claim 1 , wherein the foot flares are removed from the bottom electrode of the memory cells using an IBE overetch.

8. The method of claim 7 , wherein the IBE overetch is performed using a fixed etch time.

9. The method of claim 1 , wherein the residue is removed from the sidewalls of the memory cells using a clean-up IBE.

10. The method of claim 1 , further comprising:

depositing a conformal dielectric over the memory cells;

etching back the conformal dielectric to form an encapsulant along the sidewalls of the memory cells; and

burying the memory cells in an interlayer dielectric (ILD), wherein the encapsulant and the ILD form the dielectric encapsulant covering the memory cells.

11. The method of claim 10 , wherein the conformal dielectric and the ILD each comprises a material selected from the group consisting of: SiCN(H), SiOx, SiN, SiCOH, and combinations thereof.

12. A method of forming an MRAM device, the method comprising:

patterning an MRAM stack disposed on an Si-containing dielectric into individual memory cells using IBE landing on the Si-containing dielectric while dynamically adjusting an etch time to compensate for variations in a thickness of the MRAM stack by monitoring an optical emission signal while the MRAM stack is being patterned, and endpointing the IBE when a change in the optical emission signal is detected corresponding to an optical emission wavelength of Si, wherein each of the memory cells as-patterned comprises a bottom electrode disposed on the Si-containing dielectric, an MTJ disposed on the bottom electrode, and a top electrode disposed on the MTJ;

removing foot flares from the bottom electrode of the memory cells, wherein the foot flares are created during the patterning of the MRAM stack;

removing residue from sidewalls of the memory cells, wherein the residue comprises metal redeposited during the patterning of the MRAM stack and during the removing of the foot flares; and

covering the memory cells in a dielectric encapsulant.

13. The method of claim 12 , wherein the Si-containing dielectric is selected from the group consisting of: SiCN(H), SiOx, SiN, SiCOH, and combinations thereof.

14. The method of claim 12 , wherein the optical emission wavelength of Si is from about 250.6 nm to about 252.8 nm, and ranges therebetween.

15. The method of claim 12 , further comprising:

depositing a conformal dielectric over the memory cells;

etching back the conformal dielectric to form an encapsulant along the sidewalls of the memory cells; and

burying the memory cells in an ILD, wherein the encapsulant and the ILD form the dielectric encapsulant covering the memory cells.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 25, 2019
From: DUTTA, ASHIM; YANG, CHIH-CHAO; ZOU, LIJUAN; ARNOLD, JOHN
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 050490/0125 →
Continuity (1)
Related Publication 20210091306A1 · Mar 25, 2021