IP Library Granted Patent US 11,175,232
Granted Patent B2
US 11,175,232 · App. 16/225,786 · Granted Nov 16, 2021

Standoff ultra-compact micro-raman sensor

Inventors: M. Nural Abedin (Yorktown, VA); Arthur T. Bradley (Yorktown, VA); Anupam Kumar Misra (Honolulu, HI); Yingxin Bai (Yorktown, VA)
Assignee: UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR OF NASA
G01N21/65G01N21/6402G01N21/6458G01N2201/0221
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 11,175,232
App. No.
16/225,786
Granted
Nov 16, 2021
Kind
B2
Abstract

Standoff ultra-compact micro-Raman sensors configured to receive Raman scattering from a substance are disclosed. A laser device may be configured to transmit a laser at a first wavelength. The laser may be expanded to a predetermined size, focused through a lens, and made incident on an unknown substance. A filter may reflect the laser and Rayleigh scattering from the substance, but may permit Raman scattering and laser-induced fluorescence from the substance. One or more lenses and/or filters may receive and pass the Raman scattering and/or laser-induced fluorescence to a light sensor. The received Raman scattering and/or laser-induced fluorescence may be compared to known fingerprints of substances to determine an identity of the substance. The wavelength of the laser, the width of the laser, and other parameters may be varied based on the distance between the standoff ultra-compact micro-Raman sensor and the substance.

Claims (50)

1. A standoff Raman sensor comprising:

a laser device, configured to transmit a laser beam at a first wavelength;

a beam expander, configured to expand the laser beam to a predetermined size;

a first lens, configured to collimate the expanded laser beam;

a cylindrical lens, configured to modify the collimated expanded laser beam to a line laser beam and to focus the line laser beam for incidence on a substance, wherein the cylindrical lens is positioned between the first lens and the substance;

a filter, wherein the line laser beam is reflected by the filter, wherein Raman scattering from the substance is permitted to pass through the filter, wherein the Raman scattering is one or more second wavelengths different from the first wavelength, and wherein the Raman scattering is associated with the incidence of the line laser beam on the substance;

a second lens, configured to receive Raman scattering via the filter and transmit it to a holographic grating, wherein the second lens is configured to focus the Raman scattering on the holographic grating; and

a light sensor, configured to receive the Raman scattering via the holographic grating, wherein the light sensor is an intensified charge-coupled device (ICCD) camera.

2. The standoff Raman sensor of claim 1 , wherein the laser device includes a switch configured to control and pulse the laser beam, and wherein the light sensor is configured to use a frequency of the laser beam to isolate a Raman signal from ambient radiation.

3. The standoff Raman sensor of claim 1 , wherein the predetermined size is based on a distance between the cylindrical lens and the substance.

4. The standoff Raman sensor of claim 1 , wherein the first wavelength is selected from a plurality of wavelengths based on a prediction of an identity of the substance.

5. The standoff Raman sensor of claim 1 , wherein the standoff Raman sensor does not shield the substance from ambient radiation.

6. The standoff Raman sensor of claim 1 , wherein the light sensor is further configured to receive laser-induced fluorescence from the substance.

7. The standoff Raman sensor of claim 1 , wherein a distance between the cylindrical lens and the substance has a predetermined focal length.

8. The standoff Raman sensor of claim 1 , wherein the light sensor is communicatively coupled to a computing device having a processor and a non-transitory computer-readable medium having computer-executable instructions that when executed by the processor, perform at least:

receive from the light sensor, information corresponding to the Raman scattering; and

compare the information from the light sensor to one or more spectrograph fingerprints associated with a plurality of substances to determine an identity of the substance.

9. A method comprising:

emitting, using a laser device, a laser beam at a first wavelength;

expanding, using a beam expander, the laser beam to a predetermined size;

collimating, using a first lens, the expanded laser beam;

modifying, using a cylindrical lens, the collimated expanded laser beam to a line laser beam;

focusing, using the cylindrical lens, the line laser beam for incidence on a substance;

reflecting, using a filter, the focused line laser beam;

passing, using the filter, Raman scattering from the substance onto a second lens, wherein the Raman scattering is one or more second wavelengths different from the first wavelength, and wherein the Raman scattering is associated with the incidence of the line laser beam on the substance;

focusing, using the second lens, the Raman scattering received via the filter onto a holographic grating; and

receiving, using a light sensor and via the second lens, the Raman scattering, wherein the light sensor is an intensified charge-coupled device (ICCD) camera.

10. The method of claim 9 , wherein emitting the laser beam includes using a switch on the laser device to control and pulse the laser beam, and wherein the light sensor is configured to use a frequency of the laser beam to isolate a Raman signal from ambient radiation.

11. The method of claim 9 , wherein focusing the line laser beam for incidence on a substance includes modifying, using the cylindrical lens, a laser beam width.

12. The method of claim 9 , wherein the first wavelength is selected from a plurality of wavelengths based on a prediction of an identity of the substance.

13. The method of claim 9 , wherein ambient radiation is permitted to encounter the substance.

14. The method of claim 9 , wherein the light sensor is further configured to receive laser-induced fluorescence from the substance.

15. The method of claim 9 , wherein a distance between the cylindrical lens and the substance has a predetermined focal length.

16. A system comprising:

a standoff Raman sensor, configured to:

emit, using a laser device, a laser beam at a first wavelength;

expand, using a beam expander, the laser beam to a predetermined size;

collimate, using a first lens, the expanded laser beam;

modifying, using a cylindrical lens, the collimated expanded laser beam to a line laser beam;

focus, using the cylindrical lens, the line laser beam for incidence on a substance, wherein the cylindrical lens is positioned between the first lens and the substance;

reflect, using a filter, the focused line laser beam;

pass, using the filter, Raman scattering from the substance onto a second lens, wherein the Raman scattering is one or more second wavelengths different from the first wavelength, and wherein the Raman scattering is associated with the incidence of the line laser beam on the substance;

focus, using the second lens, the Raman scattering received via the filter onto a holographic grating; and

receive, using a light sensor and via the second lens, the Raman scattering, wherein the light sensor is an intensified charge-coupled device (ICCD) camera; and a computing device, configured to:

receive, from the light sensor, information corresponding to the Raman scattering; and

determine, based on the information, an identity of the substance.

17. The system of claim 16 , wherein the laser device includes a switch configured to control and pulse the laser beam, and wherein the light sensor is configured to use a frequency of the laser beam to isolate a Raman signal from ambient radiation.

18. The system of claim 16 , wherein focusing the line laser beam for incidence on the substance includes modifying, using the cylindrical lens, a laser beam width.

19. The system of claim 16 , wherein the first wavelength is selected from a plurality of wavelengths based on a prediction of the identity of the substance.

20. The system of claim 16 , wherein the system does not shield the substance from ambient radiation.

Assignments (5)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 14, 2021
From: ABEDIN, M. NURAL; BRADLEY, ARTHUR T.
To: UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR OF NASA
Reel/Frame 057790/0869 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 14, 2021
From: BAI, YINGXIN
To: SCIENCE SYSTEMS AND APPLICATIONS, INC.
Reel/Frame 057791/0247 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 14, 2021
From: SCIENCE SYSTEMS AND APPLICATIONS, INC.
To: UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR OF NASA
Reel/Frame 057791/0325 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 14, 2021
From: MISRA, ANUPAM
To: UNIVERSITY OF HAWAII SYSTEMS
Reel/Frame 057803/0816 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 14, 2021
From: UNIVERSITY OF HAWAII SYSTEMS
To: UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR OF NASA
Reel/Frame 057803/0884 →
Continuity (2)
Provisional Application 62617684 · Jan 16, 2018
Related Publication 20190219510A1 · Jul 18, 2019