Method of lubricating a mechanical device with high pyrophosphate level lubricant
A lubricant composition is provided containing an oil of lubricating viscosity and a substantially sulfur-free alkyl phosphate amine salt, where at least 30 mole percent of the phosphorus atoms are in an alkyl pyrophosphate salt structure, along with either or both of a conventional phosphorous containing antiwear additive and a glycerol ester. In the phosphate amine salt, at least 80 mole percent of the alkyl groups are typically secondary alkyl groups of 3 to 12 carbon atoms. A method of improving wear over a wide temperature range in a mechanical device is also provided by employing the lubricant composition.
1. A lubricant composition comprising
a. an oil of lubricating viscosity;
b. an antiwear additive comprising a substantially sulfur-free alkyl phosphate amine salt wherein at least about 30 mole percent of the phosphorus atoms are in an alkyl pyrophosphate salt structure and at least about 80 mole percent of the alkyl groups are secondary alkyl groups of about 3 to about 12 carbon atoms; and
c. at least one of,
i. a hydrocarbyl amine salt of an alkylphosphoric acid ester,
ii. a glycerol ester, and
iii. mixtures of (i) and (ii).
2. The lubricant composition of claim 1 , wherein the antiwear additive is present from about 0.01 to about 5 percent by weight of the composition.
3. The lubricant composition of claim 1 , wherein the antiwear additive is present in the lubricant composition in an amount to deliver a phosphorous content of at least 200 ppm to 2000 ppm.
4. The lubricant composition of claim 1 , wherein the sulfur-free alkyl phosphate amine salt comprises a species represented by formula (I) or (II):
wherein each R 1 is independently a secondary alkyl group of about 4 to about 12 carbon atoms and each R 2 is independently hydrogen or a hydrocarbyl group or an ester-containing group, and at least one R 2 group is a hydrocarbyl group or an ester-containing group; or wherein the —OH group is replaced by an —OR 1 group, or wherein one or more —OR 1 groups are replaced by —OH groups, or wherein an R 1 group is replaced by a phosphorus-containing group.
5. The lubricant composition of claim 1 , wherein the glycerol ester is glycerol monooleate or a borated glycerol monooleate.
6. The lubricant composition of claim 1 , wherein the glycerol ester is present at least 0.01 weight percent.
7. The lubricant composition of claim 1 , wherein the glycerol ester is present at from 0.01 to 1 weight percent.
8. The lubricant composition of claim 1 , wherein the glycerol ester is present at from 1 to 3 weight percent.
9. The lubricant composition of claim 1 , wherein the alkylphosphoric acid of the hydrocarbyl amine salt of an alkylphosphoric acid ester is a dialkyldithiophosphoric acid.
10. The lubricant composition of claim 1 , wherein the hydrocarbyl amine in the hydrocarbyl amine salt of an alkylphosphoric acid ester is a C 8 to C 20 alkylamine.
11. The lubricant composition of claim 1 , wherein the hydrocarbyl amine salt of an alkylphosphoric acid ester is present at from 0.3 to 2 weight percent.
12. The lubricant composition of claim 1 wherein the oil of lubricating viscosity has a kinematic viscosity at 100° C. by ASTM D445 of about 1.5 to about 7.5 mm 2/ s.
13. The lubricant composition of claim 1 wherein the oil of lubricating viscosity comprises a poly alpha olefin having a kinematic viscosity at 100° C. by ASTM D445 of about 1.5 to about 7.5.
14. The lubricant composition of claim 1 , wherein the lubricant composition has a kinematic viscosity at 100° C. by ASTM D445 of about 3 to about 7.5.
15. A method of improving wear in a mechanical device, comprising supplying to the mechanical device the lubricant composition of claim 1 , and operating the mechanical device.
16. The method of claim 15 wherein the mechanical device comprises an axle.
17. The method of claim 15 , wherein the mechanical device comprises a bearing.
18. The method of claim 15 , wherein the mechanical device comprises a hypoid gear.
19. The method of claim 15 , where the method includes the step of operating the mechanical device at a temperature between about 40° C. to about 160° C.