Gel with PU matrix and vegetable oil
An elastic gel includes a solid component and a liquid component. The solid component is a polyurethane polymer matrix. The liquid component is a plasticizer. The liquid component includes one or more vegetable oils or chemical derivatives of vegetable oils or a mixture thereof and is comprised in cells of the polyurethane polymer matrix.
1. An elastic gel, comprising:
a solid component, the solid component being polyurethane polymer matrix; and
a liquid component, the liquid component being a plasticizer, the plasticizer being a chemical derivative of one or more vegetable oils, the plasticizer being a polyester generated in a transesterification from the one or more vegetable oils comprising triglycerides, molecules of the polyester respectively comprising at least four fatty acids, wherein a glycerol of the triglycerides is replaced by an alcohol comprising more than three carbon atoms or by a polyoxymethylene (POM) resin, wherein the molecules of the polyester respectively comprise a carbon atom backbone and the at least four fatty acids are covalently linked to the carbon atom backbone, the liquid component being comprised in cells of the polyurethane polymer matrix.
2. The gel of claim 1 , wherein the at least four fatty acids are respectively bound to the carbon atom backbone by an ester bond, the carbon atom backbone comprising at least four carbon atoms.
3. The gel of claim 1 , whereby at least 90% of the liquid component consists of the one or more vegetable oils or the chemical derivative of the one or more vegetable oils or a mixture thereof.
4. The gel of claim 1 , wherein at least 1% by weight of the plasticizer is covalently bound to the polyurethane polymer matrix.
5. The gel of claim 4 , wherein the plasticizer that is covalently bound to the polyurethane polymer matrix is a vegetable oil that comprises one or more functional groups in at least one fatty acid chain of the vegetable oil, the one or more functional groups having reacted with an isocyanate in a polyurethane reaction mixture, the polyurethane reaction mixture being used to form the polyurethane polymer matrix, covalent bonds connecting the at least one fatty acid chain with the polyurethane polymer matrix.
6. The gel of claim 1 , having a height of 1 mm to 800 mm.
7. The gel of claim 1 , wherein more than 50% by weight of the one or more vegetable oils consists of unsaturated triglycerides.
8. The gel of claim 1 , the one or more vegetable oils comprising soy bean oil.
9. The gel of claim 1 , the one or more vegetable oils comprising castor oil.
10. The gel of claim 1 , wherein at least 95% by weight of the plasticizer is covalently bound to the polyurethane polymer matrix.
11. The gel of claim 1 , wherein the polyester is generated in an enzymatic transesterification from the one or more vegetable oils comprising triglycerides.