Pre-lithiation method of negative electrode for secondary battery
A method of pre-lithiating an electrode for a secondary battery, the method including: a first step of bringing a lithium metal into direct contact with an electrode in an electrolyte and applying pressure to the electrode to prepare a pre-lithiated electrode; and a second step of removing the lithium metal and then applying pressure to the pre-lithiated electrode to perform a stabilization process. The electrode for the secondary battery after going through the pre-lithiation can relieve volume change of the electrode and reduce contact loss of the electrode.
1. A method of pre-lithiating an electrode for a secondary battery, the method comprising:
a first step of bringing a lithium metal into direct contact with an electrode in an electrolyte and applying pressure to the electrode and the lithium metal for 0.5 to 3 hours to prepare a pre-lithiated electrode; and
a second step of removing the lithium metal and then applying pressure to the pre-lithiated electrode for 2 to 6 hours for perform a stabilization process; wherein the pressure applied in the first step is in a range of 20 to 50 kgf and the pressure applied in the second step is in a range of 20 to 50 kgf.
2. The method of claim 1 , wherein the first step comprises placing the lithium metal on the electrode and tightening a jig to apply pressure to the lithium metal and electrode.
3. The method of claim 1 , wherein the applying pressure of the second step comprises tightening the pre-lithiated electrode on a jig to apply pressure.
4. The method of claim 1 , wherein the electrode is a negative electrode.
5. The method of claim 1 , wherein the electrode comprises silicon oxide.
6. The method of claim 1 , further comprising wetting the electrode by immersing the electrode in an electrolyte before the first step.
7. The method of claim 6 , wherein the electrode is wetted with the electrolyte for 1 to 48 hours.
8. The method of claim 1 , wherein the second step is performed in an electrolyte.
9. A method of preparing an electrode for a secondary battery, the method comprising:
mixing an electrode active material, a conductive material and a binder to prepare a slurry;
coating the slurry on an electrode current collector;
pressing the coated electrode current collector with a roller and punching the electrode current collector to prepare unit electrodes and drying the unit electrodes; and
pre-lithiating the dried unit electrodes according to the pre-lithiation method according to claim 1 .