Method for preparing a magnetic chain structure
A method for preparing a magnetic chain structure is provided. The method comprises providing a plurality of magnetic particles; dispersing the plurality of magnetic particles in a solution comprising a dopamine-based material to form a reaction mixture; applying a magnetic field across the reaction mixture to align the magnetic particles in the reaction mixture; and polymerizing the dopamine-based material on the aligned magnetic particles to obtain the magnetic chain structure. A magnetic chain structure prepared by the method is also provided.
1. A method for preparing a magnetic chain structure, the method comprising
a) providing a plurality of magnetic particles;
b) dispersing the plurality of magnetic particles in a solution comprising a dopamine-based material to form a reaction mixture;
c) applying a magnetic field across the reaction mixture to align the magnetic particles in the reaction mixture; and
d) polymerizing the dopamine-based material on the aligned magnetic particles to obtain the magnetic chain structure.
2. The method according to claim 1 , wherein the magnetic particle has a core-shell structure, the core comprising a magnetic material, and the shell comprising a material selected from the group consisting of a polymer, silica, a metal, a metal-organic framework, and combinations thereof, surrounding the core.
3. The method according to claim 1 , wherein the magnetic particle comprises a magnetic material selected from the group consisting of a ferromagnetic material, a superparamagnetic material, and combinations thereof.
4. The method according to claim 1 , wherein the magnetic particle comprises a superparamagnetic material.
5. The method according to claim 4 , wherein the superparamagnetic material is selected from the group consisting of a superparamagnetic metal, a superparamagnetic metal oxide, a heterogeneous structure comprising a superparamagnetic metal and/or a superparamagnetic metal oxide, and combinations thereof.
6. The method according to claim 5 , wherein the superparamagnetic metal is selected from the group consisting of Fe, Co, Ni, FeAu, FePt, FePd, CoPt, and alloys thereof.
7. The method according to claim 5 , wherein the superparamagnetic metal oxide is selected from the group consisting of Fe 2 O 3 , Fe 3 O 4 , CoO, NiO, CoFe 2 O 4 , MnFe 2 O 4 , and combinations thereof.
8. The method according to claim 5 , wherein the heterogeneous structure comprising a superparamagnetic metal and/or a superparamagnetic metal oxide is selected from the group consisting of Au—Fe 2 O 3 , Ag—Fe 3 O 4 , a quantum dot-Fe 2 O 3 nanostructure, and combinations thereof.
9. The method according to claim 2 , wherein the polymer is selected from the group consisting of polystyrene, polymethacrylate, phenol formaldehyde resin, copolymers thereof, and combinations thereof.
10. The method according to claim 1 , wherein the magnetic particle has a core-shell structure, the core comprising Fe 3 O 4 and the shell comprising polystyrene surrounding the core.
11. The method according to claim 1 , wherein the solution has a pH in the range of about 7.1 to about 12.
12. The method according to claim 1 , wherein the dopamine-based material is selected from the group consisting of dopamine, norepinephrine, L-3,4-dihydroxyphenylalanine, and combinations thereof.
13. The method according to claim 1 , wherein concentration of the dopamine-based material in the reaction mixture is in the range of about 0.08 mg/ml to about 0.5 mg/ml.
14. The method according to claim 1 , wherein amount of the magnetic particles in the reaction mixture is in the range of about 0.001 wt % to about 0.5 wt %.
15. The method according to claim 1 , wherein applying a magnetic field across the reaction mixture is carried out in a reaction chamber comprising one or more channels having a width corresponding to a length of the magnetic chain structure.
16. The method according to claim 1 , further comprising polymerizing the dopamine-based material on the magnetic particles prior to applying a magnetic field across the reaction mixture to align the magnetic particles in the reaction mixture.
17. The method according to claim 1 , further comprising agitating the reaction mixture comprising the aligned magnetic particles prior to polymerizing the dopamine-based material on the aligned magnetic particles.
18. The method according to claim 1 , further comprising dispersing the obtained magnetic chain structure in a second solution comprising a second dopamine-based material, and polymerizing the second dopamine-based material on the magnetic chain structure.
19. The method according to claim 1 , further comprising attaching a moiety selected from the group consisting of a polymer, a metal nanoparticle, a metal oxide nanoparticle, a biomolecule, a metal-organic framework material, and combinations thereof, to the magnetic nanochain.