IP Library Granted Patent US 11,188,002
Granted Patent B2
US 11,188,002 · App. 16/839,151 · Granted Nov 30, 2021

Electrophotographic photoreceptor, electrophotographic photoreceptor cartridge and image forming apparatus

Inventors: Takahiro Choda (Tokyo, JP); Atsushi Yoshizawa (Tokyo, JP)
Assignee: Mitsubishi Chemical Corporation
G03G5/047G03G5/0539G03G5/0564G03G5/0672G03G15/75
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 11,188,002
App. No.
16/839,151
Granted
Nov 30, 2021
Kind
B2
Abstract

The present invention relates to an electrophotographic photoreceptor including a conductive support and a photosensitive layer on the conductive support, and the photosensitive layer contains a polymer A containing a repeating structural unit represented by a specific formula, and a polymer B containing a repeating structural unit represented by a specific formula. In addition, the present invention relates to an electrophotographic photoreceptor cartridge and an image forming apparatus including the electrophotographic photoreceptor.

Claims (25)

1. An electrophotographic photoreceptor comprising: a conductive support; and a photosensitive layer on the conductive support, wherein

the photosensitive layer comprises a polymer A containing a repeating structural unit represented by Formula (1) and a repeating structural unit represented by Formula (2), and a polymer B not containing the repeating structural unit of Formula (1) but containing the repeating structural unit of Formula (2):

wherein

R 1 represents a hydrogen atom or a methyl group; R 2 represents a single bond, a divalent hydrocarbon group which may have an ether moiety, or a divalent polyether group which may have a substituent; and R 3 represents a polycarbonate residue or a polyester residue;

wherein,

R 4 represents a hydrogen atom or a methyl group; R 5 represents a single bond, or a divalent hydrocarbon group which may have an ether moiety; and Rf 1 represents a linear perfluoroalkyl group having 2 to 6 carbon atoms, a branched perfluoroalkyl group having 2 to 6 carbon atoms, an alicyclic perfluoroalkyl group having 2 to 6 carbon atoms, or a group of Formula (3); and

wherein,

Rf 2 and Rf 3 each independently represent a fluorine atom or a trifluoromethyl group;

Rf 4 represents a linear perfluoroalkyl group having 1 to 6 carbon atoms or a branched perfluoroalkyl group having 1 to 6 carbon atoms, and n 1 represents an integer of 1 to 3.

2. The electrophotographic photoreceptor according to claim 1 , wherein the polymer B further comprises a repeating structural unit of Formula (10):

wherein X 1 , X 2 and X 3 each independently represent a hydrogen atom, a hydrocarbon group which may have a substituent, or a group represented by Formula (11); R 11 , R 12 , R 15 and R 16 each independently represent a hydrogen atom, or a hydrocarbon group which may have a substituent; R 14 represents a hydrocarbon group which may have a substituent or a group represented by Formula (13); Z represents a hydrogen atom or a group derived from a radical polymerization initiator, and n 0 represents an integer of 1 or more;

wherein,

R 21 represents a hydrogen atom, a hydrocarbon group which may have a substituent, or a heterocyclic group which may have a substituent; and

wherein,

n 31 , n 32 , n 33 , and n 34 , each independently represent 0 or an integer of 1 or more; R 31 represents an alkylene group, a halogen-substituted alkylene group, —(C m H 2m-1 (OH))— or a single bond; and R 32 represents an alkylene group, a halogen-substituted alkylene group, —S—,—O—, —NH— or a single bond, and m represents an integer of 1 or more.

3. The electrophotographic photoreceptor according to claim 1 , wherein the polymer A further comprises a repeating structural unit of Formula (10).

4. The electrophotographic photoreceptor according to claim 1 , wherein a content ratio of the polymer A to the polymer B in the photosensitive layer is 4:1 to 1:4 in terms of mass ratio.

5. The electrophotographic photoreceptor according to claim 1 wherein the photosensitive layer contains a filler.

6. The electrophotographic photoreceptor according to claim 5 , wherein the filler comprises fluorine atom-containing resin particles.

7. The electrophotographic photoreceptor according to claim 5 , wherein a total content of the polymer A and the polymer B is 1 mass % or more and 20 mass % or less relative to a mass of the filler.

8. The electrophotographic photoreceptor according to claim 1 , wherein the photosensitive layer is an outermost surface layer.

9. The electrophotographic photoreceptor according to claim 1 , wherein the photosensitive layer is a lamination type photosensitive layer in which a charge generation layer and a charge transport layer are sequentially laminated from the conductive support side.

10. The electrophotographic photoreceptor according to claim 9 , wherein the photosensitive layer contains a filler, and the polymer A, the polymer B, and the filler are all contained in the charge transport layer.

11. An electrophotographic photoreceptor cartridge comprising the electrophotographic photoreceptor according to claim 1 .

12. An image forming apparatus comprising the electrophotographic photoreceptor according to claim 1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 3, 2020
From: CHODA, TAKAHIRO; YOSHIZAWA, ATSUSHI
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 052302/0834 →
Priority Claims (1)
JP JP2017-194629 · Oct 4, 2017 · national
Continuity (2)
Continuation PCTJP2018037110 · Oct 3, 2018
Related Publication 20200233322A1 · Jul 23, 2020