Method of preparing carbon aerogel precursor, carbon aerogel precursor prepared thereby, and carbon aerogel
The present invention relates to a carbon aerogel precursor, a preparation method thereof and a carbon aerogel prepared thereby and, more particularly, to a carbon aerogel precursor which can be converted into a carbon aerogel that exhibits excellent specific surface area and physical properties by using a binder that has a low carbonization ratio and is capable of performing phase conversion while using a carbon material having physical properties such as diameter, length and the like that are not adjusted, a preparation method thereof, and a carbon aerogel prepared thereby.
1. A method of preparing a carbon aerogel precursor, the method comprising the steps of:
mixing a carbon material and a dispersant with a solvent to prepare a carbon material dispersion;
adjusting concentration of the carbon material dispersion;
mixing a binding agent with the carbon material dispersion to provide a mixed solution;
dispersing the mixed solution to obtain a gelated mixed solution; and
dipping the gelated mixed solution in ethanol to remove the dispersant,
wherein adjusting the concentration of the carbon material dispersion comprises evaporating the solvent, and
wherein the binding agent is at least one of gelatin, cellulose or chitosan.
2. The method of claim 1 , wherein the carbon material is selected from the group consisting of a carbon nanotube, a graphene, an oxide graphene, and a carbon fiber.
3. The method of claim 1 , wherein the carbon material has a diameter of 0.8 nm or more and a length of 100 nm or more, and a carbon material dispersion comprising the carbon material has a concentration of 0.001 to 30 wt %.
4. The method of claim 1 , wherein the solvent is water or an organic solvent selected from the group consisting of methyl alcohol (MeOH), ethyl alcohol (EtOH), propyl alcohol (PA), isopropyl alcohol (IPA), butyl alcohol, ethylene glycol (EG), 1,2-dichlorobenzene, dimethyl formamide (DMF), dimethyl acetamide (DMAc), methyl ethyl ketone (MEK), methyl isobutyl ketone (MIBK), butyl cellosolve (BC), butyl cellosolve acetate (BCA), n-methyl-2-pyrrolidone (NMP), ethyl acetate (EA), butyl acetate (BA), acetone, cyclohexanone, and toluene.
5. The method of claim 1 , wherein the dispersant is an anionic dispersant selected from the group consisting of sodium dodecyl sulfate (SDS), lithium dodecyl sulfate (LDS), sodium dodecyl sulfate (NaDDS), sodium dodecyl sulfonate (SDSA) and sodium dodecylbenzene sulfonate (SDBS) that are alkyl sulfate-based compounds, or a cationic dispersant selected from the group consisting of cetyltrimethyl ammonium chloride (CTAC), cetyltrimethyl ammonium bromide (CTAB), and dodecyl-trimethyl ammonium bromide (DTAB), or a nonionic dispersant selected from the group consisting of glycerol monostearate, sorbitan monooleate, polyvinyl alcohol (PVA), polymethyl acrylate (PMA), methyl cellulose (MC), carboxyl methyl cellulose (CMC), Gum Arabic (GA), polysaccharide, polyethyleneimine (PEI), polyvinylpyrrolidone (PVP), and polyethylene oxide (PEO)-poly(ethylene oxide)-poly(butylene oxide) terpolymer.
6. The method of claim 1 , wherein the binding agent is mixed in an amount of 50 to 300 parts by weight per the total weight of the carbon material dispersion of 100 parts by weight.
7. The method of claim 1 , wherein the binding agent has a carbon yield upon carbonization of 5 to 40%.
8. The method of claim 1 , wherein the step of mixing the binding agent with the carbon material dispersion further comprises additionally mixing a carbon precursor with the binding agent and the carbon material dispersion.
9. The method of claim 8 , wherein the carbon precursor is selected from the group consisting of (i) a saccharide selected from the group consisting of a monosaccharide, a disaccharide, an oligosaccharide, derivatives thereof, and a random combination thereof, (ii) a polymer carbohydrate, derivatives of the polymer carbohydrate, a non-carbohydrate synthetic polymer or a random combination thereof, and polydopamine.
10. The method of claim 8 , wherein the carbon precursor is a monosaccharide selected from the group consisting of glucose, fructose, hydrates thereof, syrups thereof, and combinations thereof.
11. The method of claim 8 , wherein the carbon precursor is a polysaccharide selected from the group consisting of maltose, sucrose, hydrates thereof, syrups thereof, and combinations thereof.
12. A method of preparing a carbon aerogel, the method comprising the steps of:
preparing a carbon material dispersion by mixing a carbon material and a dispersant with a solvent;
adjusting concentration of the carbon material dispersion;
providing a mixed solution by mixing a binding agent with the carbon material dispersion;
obtaining a gelated carbon aerogel precursor by dispersing the mixed solution;
removing the dispersant and obtaining a dispersant-removed carbon aerogel precursor by dipping the gelated carbon aerogel precursor in ethanol; and
obtaining a dried carbon aerogel by drying the dispersant-removed carbon aerogel precursor.
13. The method of claim 12 , further comprising the step of carbonizing the carbon material and the binding agent by heat-treating the carbon aerogel dried in the step of drying the dispersant-removed carbon aerogel precursor.
14. A method of producing a carbon aerogel graphene composite, the method comprising the steps of:
preparing a carbon material dispersion by mixing a carbon material and a dispersant with a solvent;
providing a mixed solution by mixing a binding agent with the carbon material dispersion;
obtaining a gelated carbon aerogel precursor by dispersing the mixed solution;
mixing a graphene oxide with the gelated carbon aerogel precursor to prepare a mixed solution;
performing a spinning process of the mixed solution, thereby spinning the mixed solution to manufacture a nanofiber; and
heat-treating the nanofiber.
15. The method of claim 14 , further comprising the step of adjusting concentration of the carbon material dispersion before the step of providing a mixed solution by mixing a binding agent with the carbon material dispersion.
16. The method of claim 14 , further comprising the step of removing the dispersant and obtaining a dispersant-removed carbon aerogel precursor by dipping the gelated carbon aerogel precursor in ethanol before the step of mixing a graphene oxide with the carbon aerogel precursor to prepare a mixed solution.
17. The method of claim 14 , wherein the binding agent has a carbon yield upon carbonization of 5 to 40% during carbonization.
18. The method of claim 14 , wherein the carbon precursor is additionally mixed in an amount ratio of 0.1 to 1,000 parts by weight per 100 parts by weight of the carbon material dispersion in the step of providing a mixed solution by mixing a binding agent with the carbon material dispersion.