Non-porous separator and use thereof
The present invention belongs to the technical fields of macromolecular materials and batteries, and particularly relates to a non-porous separator and the use thereof, more particularly to a non-porous separator having a gelation function and the use thereof. This non-porous separator is composed of two or more macromolecular materials, wherein at least one of the macromolecular materials can be gelled by an organic solvent. This non-porous separator can be used in batteries having an organic solvent-based electrolyte and a high energy density, such that not only can a micro-short circuit, generated due to the introduction of foreign matters such as metals, be prevented, leading to an improved qualification rate for the product, but also the safety performance and the cycle life of such a battery can be improved significantly.
1. A non-porous separator, characterized in that the non-porous separator comprises two or more separate macromolecular materials, wherein at least one of the macromolecular materials can be gelled by an organic solvent; the two or more macromolecular materials refer to any mixture of molecular, nanometer or micron scales; the separator is non-porous, and has a gas permeability of 0 ml/min.
2. The non-porous separator according to claim 1 , characterized in that the macromolecular material that can be gelled by an organic solvent is a synthetic macromolecular compound or a natural macromolecular compound, or a blend, copolymer, modified product and complex of a synthetic macromolecular compound and a natural macromolecular compound.
3. The non-porous separator according to claim 2 , characterized in that the synthetic macromolecular material is one member or a blend, copolymer, modified product and complex of two and more members selected from the group consisting of polyethers, polysiloxane, polyester, polyacrylonitrile, fluoropolymer, polymers of acrylic acid and its esters, polyvinyl chloride, polyvinyl acetate, phenolic resin, epoxy resin, polyurethane, polyarenes, polyamide, and polyimide.
4. The non-porous separator according to claim 2 , characterized in that the synthetic macromolecular material further comprise fillers and additives, and the weight proportion of the fillers and additives is 0.01 wt. % to 20 wt. % of the synthetic macromolecular material.
5. The non-porous separator according to claim 4 , characterized in that the weight proportion of the fillers and additives is 1 wt. % to 5 wt. % of the synthetic macromolecular material.
6. The non-porous separator according to claim 4 , characterized in that the fillers and additives comprise one member or a mixture of two and more members selected from the group consisting of alumina, silica, titania, zirconia, compounds composed of aLi 2 O-bAl 2 O 3 -cTiO 2 -dP 2 O 5 (where a, b, c, d are between 1 and 100), compounds composed of aLi 2 O-bLa 2 O 3 -cZrO 2 -dTa 2 O 5 (where a, b, c, d are between 1 and 100), compounds composed of aLi 2 S-bSiS 2 -cP 2 S 5 (where a, b, c are between 1 and 100), montmorillonite, and molecular sieves.
7. The non-porous separator according to claim 2 , characterized in that the natural macromolecular material is one member or a blend, modified product and complex of two and more members selected from the group consisting of cellulose, starch, chitin, chitosan, collagen, gelatin, natural silk, and spider silk.
8. The non-porous separator according to claim 7 , characterized in that the modified product of the natural macromolecular material is one member or a mixture of two and more members selected from the group consisting of their alkylates, carboxylates, sulfonated compounds, carboxymethyl compounds, grafted compounds, and crosslinked compounds.
9. The non-porous separator according to claim 7 , characterized in that the natural macromolecular material further comprise fillers and additives, and the weight proportion of the fillers and additives is 0.01 wt. % to 20 wt. % of the natural macromolecular material.
10. The non-porous separator according to claim 9 , characterized in that the weight proportion of the fillers and additives is 1 wt. % to 5 wt. % of the natural macromolecular material.
11. The non-porous separator according to claim 1 , characterized in that the thickness of the non-porous separator is 1-200 μm.
12. The non-porous separator according to claim 11 , characterized in that the thickness of the non-porous separator is 5-40 μm.
13. The non-porous separator according to claim 1 , characterized in that the non-porous separator further comprises, as matrix, at least one macromolecular material that cannot be gelled by an organic solvent.
14. The non-porous separator according to claim 13 , characterized in that the matrix is polyolefin; polyesters; polyimide; or polyvinylidene fluoride.
15. The non-porous separator according to claim 14 , characterized in that the polyesters is polyethylene terephthalate or polybutylene terephthalate.
16. The non-porous separator according to claim 15 , characterized in that the polyesters is polyethylene terephthalate.
17. The non-porous separator according to claim 14 , characterized in that the polyolefin is polyethylene, polypropylene or combinations thereof.
18. The non-porous separator according to claim 17 , characterized in that the polyolefin is polypropylene or polypropylene/polyethylene/polypropylene.
19. Use of the non-porous separator according to claim 1 , as a separator for primary or secondary batteries that employ an organic solvent type electrolyte.
20. A battery comprising the non-porous separator according to claim 1 .
21. A process for preparing a non-porous separator comprising two or more macromolecular materials, wherein at least one of the macromolecular materials can be gelled by an organic solvent, and at least one of the macromolecular materials cannot be gelled by an organic solvent, that is, a matrix; wherein the process comprises dissolving the macromolecular materials that can be gelled by an organic solvent in a solvent, thereby forming a solution; immersing the matrix into the solution, evaporating the solvent, allowing the macromolecular materials that can be gelled by an organic solvent to be precipitated from the solution and deposited on the matrix;
wherein the separator is non-porous, and has a gas permeability of 0 ml/min.