IP Library › Granted Patent US 11,208,579
Granted Patent B2
US 11,208,579 · App. 16/319,352 · Granted Dec 28, 2021

Curable resin composition and adhesive for bonding structural material using composition

Inventors: Mitsunori Ide (Saitama, JP); Keisuke Ota (Saitama, JP); Tamotsu Nagamatsu (Saitama, JP)
Assignee: ADEKA CORPORATION
C09J163/00C08G18/58C08G18/80C08G59/14C08G59/20C09J11/06C09J175/04
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Quick Facts
Patent No.
US 11,208,579
App. No.
16/319,352
Granted
Dec 28, 2021
Kind
B2
Abstract

To show a curable resin composition suitable as an adhesive for bonding a structural material having good adhesiveness to aluminum in particular. A curable resin composition containing (A1) phosphoric acid-modified epoxy resin obtained by reacting a phosphoric acid (a1) and an epoxy compound (a2) (excluding a urethane-modified epoxy resin and a urethane-modified chelate epoxy resin); and (A2) an epoxy resin (excluding component (A1)); (B) a block urethane; and (C) a latent curing agent, in which a phosphorus content in a total mass of component (A1) and component (A2) is 0.01 to 2.0% by mass.

Claims (10)

1. A curable resin composition comprising:

(A1) a phosphoric acid-modified epoxy resin obtained by reacting a phosphoric acid (a1) and an epoxy compound (a2) excluding a urethane-modified epoxy resin and a urethane-modified chelate epoxy resin; and

(A2) an epoxy resin excluding component (A1);

(B) a blocked urethane, which is a compound obtained by further reacting a blocking agent (b4) with a polyurethane resin (b3) obtained by reacting a polyol (b1) and a polyisocyanate (b2), wherein the blocking agent (b4) is at least one compound selected from the group consisting of active methylene compounds, oxime compounds, monohydric alcohols, glycol derivatives, amine compounds, phenols and ε-caprolactams; and

(C) a latent curing agent, wherein the latent curing agent (C) is at least one compound selected from the group consisting of dicyandiamide, hydrazides, 4,4′-diaminodiphenylsulfone, boron trifluoride amine complex salt and ureas,

wherein a phosphorus content in a total mass of component (A1) and component (A2) is 0.01 to 2.0% by mass.

2. The curable resin composition according to claim 1 ,

wherein the epoxy compound (a2) is a bisphenol epoxy resin.

3. An adhesive for bonding a structural material, which uses the curable resin composition according to claim 1 .

4. The adhesive for bonding a structural material according to claim 3 , which is used for bonding aluminum materials.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 1, 2019
From: IDE, MITSUNORI; OTA, KEISUKE; NAGAMATSU, TAMOTSU
To: ADEKA CORPORATION
Reel/Frame 048215/0108 →
Priority Claims (1)
JP JP2016-150275 · Jul 29, 2016 · national
Continuity (1)
Related Publication 20190249047A1 · Aug 15, 2019