Magnetic disc, aluminum alloy substrate for magnetic disc, and production method for aluminum alloy substrate
Provided are a magnetic disk and a method of fabricating the magnetic disk. The magnetic disk includes an aluminum alloy plate fabricated by a process involving a CC method and a compound removal process, and an electroless Ni—P plating layer disposed on the surface of the plate. The aluminum alloy plate is composed of an aluminum alloy containing 0.4 to 3.0 mass % (hereinafter abbreviated simply as “%”) of Fe, 0.1% to 3.0% of Mn, 0.005% to 1.000% of Cu, 0.005% to 1.000% of Zn, with a balance of Al and unavoidable impurities. In the magnetic disk, the maximum amplitude of waviness in a wavelength range of 0.4 to 5.0 mm is 5 nm or less, and the maximum amplitude of waviness in a wavelength range of 0.08 to 0.45 mm is 1.5 nm or less.
1. An aluminum alloy substrate for a magnetic disk, the substrate comprising:
an aluminum alloy provided with electroless Ni—P plating, wherein
the aluminum alloy comprises 0.4 to 3.0 mass % of Fe, 0.1 to 3.0 mass % of Mn, 0.005 to 1.0 mass % of Cu, and 0.005 to 1.0 mass % of Zn, with a balance of Al and unavoidable impurities,
a maximum amplitude of waviness in a wavelength range of 0.4 to 5.0 mm is 5.0 nm or less, and a maximum amplitude of waviness in a wavelength range of 0.08 to 0.45 mm is 1.5 nm or less on a surface of the aluminum alloy substrate, and
a yield stress after retention at 300° C. for three hours is 100 MPa or more.
2. The aluminum alloy substrate for a magnetic disk according to claim 1 , wherein the aluminum alloy further comprises one or more elements selected from a group comprising 0.1 to 0.4 mass % of Si, 0.1 to 3.0 mass % of Ni, 0.01 to 1.00 mass % of Cr, and 0.01 to 1.00 mass % of Zr.
3. The aluminum alloy substrate for a magnetic disk according to claim 1 , wherein the aluminum alloy further comprises one or more elements selected from a group comprising Ti, B, and V at a total content of 0.005 to 0.5 mass %.
4. A method of fabricating an aluminum alloy substrate for a magnetic disk, the method being applied to the aluminum alloy substrate according to claim 1 , the method comprising:
a casting process to produce an aluminum alloy cast plate;
a rolling process of cold rolling the aluminum alloy cast plate to produce an aluminum alloy plate;
a pressure annealing process of extracting an annular aluminum alloy plate from the aluminum alloy plate and annealing and flattening the annular aluminum alloy plate under a pressure;
a substrate preparing process comprising a grinding step and a stress-relieving heat treatment step in an order mentioned, the substrate preparing process being directed to the annular aluminum alloy plate after the pressure annealing process;
a plating pretreatment process comprising an alkaline degreasing step, an acid etching step, and at least one zincate treatment step in an order mentioned, the plating pretreatment process being directed to the annular aluminum alloy plate after the substrate preparing process; and
an electroless Ni—P plating process of providing electroless Ni—P plating to a surface of the annular aluminum alloy plate after the plating pretreatment process, wherein
the method further comprises a compound removal process at a timing after the grinding step of the substrate preparing process and before a first one of the at least one zincate treatment step of the plating pretreatment process,
the casting process involves continuous casting to produce the aluminum alloy cast plate, and
the compound removal process involves immersion of the annular aluminum alloy plate for 5 to 60 seconds into an HNO 3 /HF mixed solution, the mixed solution being a solution at a temperature of 10° C. to 30° C. having an HNO 3 concentration of 10 to 60 mass % and an HF concentration of 10 to 80 g/L.
5. The method of fabricating an aluminum alloy substrate for a magnetic disk according to claim 4 , further comprising a cutting step before the grinding step of the substrate preparing process.
6. A magnetic disk comprising
a magnetic medium that is disposed on the aluminum alloy substrate for a magnetic disk according to claim 1 and comprises magnetic layer,
wherein, a maximum amplitude of waviness in a wavelength range of 0.4 to 5.0 mm is 5.0 nm or less, and a maximum amplitude of waviness in a wavelength range of 0.08 to 0.45 mm is 1.5 nm or less on a surface of the magnetic disk.