Organic light emitting device
The present disclosure provides an organic light emitting device having improved driving voltage, efficiency and life time.
1. An organic light emitting device comprising:
a first electrode;
a hole transport layer;
a first light emitting layer;
a second light emitting layer;
a third light emitting layer;
an electron transport layer; and
a second electrode,
wherein the first light emitting layer comprises a 1-1 host and a 1-2 host,
the second light emitting layer comprises a 2-1 host and a 2-2 host,
the hole transport layer comprises the same material as the 1-1 host,
the 1-1 host and the 2-2 host are different materials from each other,
wherein the third light emitting layer is disposed between the second light emitting layer and the electron transport layer, and comprises a 3-1 host and a 3-2 host,
the 1-2 host, the 2-1 host and the 3-1 host are the same materials, and
wherein the 1-2 host is a compound represented by Chemical Formula 2:
in Chemical Formula 2,
Ar 5 and Ar 6 are each independently a substituted or unsubstituted C 6-60 aryl.
2. The organic light emitting device of claim 1 ,
wherein the 1-1 host is a compound represented by Chemical Formula 1:
in Chemical Formula 1,
R 1 and R 2 are each independently hydrogen; deuterium; halogen; nitrile; nitro; amino; a substituted or unsubstituted C 1 -60 alkyl; a substituted or unsubstituted C 3-60 cycloalkyl; a substituted or unsubstituted C 2-60 alkenyl; a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heterocyclic group containing at least one of 0, N, Si and S,
L 1 and L 2 are each independently a bond, or a substituted or unsubstituted C 6-60 arylene, and
Ar 1 and Ar 2 are each independently a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2 -60 heteroaryl containing at least one of 0, N, Si and S.
3. The organic light emitting device of claim 2 ,
wherein the compound represented by the Chemical Formula 1 is any one selected from the group consisting of:
4. The organic light emitting device of claim 1 ,
wherein the 1-1 host is a compound represented by Chemical Formula 1′:
in Chemical Formula 1′,
R 3 and R 4 are each independently hydrogen; deuterium; halogen; nitrile; nitro; amino; a substituted or unsubstituted C 1 -60 alkyl; a substituted or unsubstituted C 3-60 cycloalkyl; a substituted or unsubstituted C 2-60 alkenyl; a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heterocyclic group containing at least one of 0, N, Si and S,
L 3 is a bond, or a substituted or unsubstituted C 6 -60 arylene, and
Ar 3 and Ar 4 are each independently a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2 -60 heteroaryl containing at least one of 0, N, Si and S.
5. The organic light emitting device of claim 4 ,
wherein the compound represented by the Chemical Formula 1′ is a following compound:
6. The organic light emitting device of claim 1 ,
wherein the compound represented by the Chemical Formula 2 is any one selected from the group consisting of:
7. The organic light emitting device of claim 1 ,
wherein the 2-2 host is a compound represented by Chemical Formula 3:
in Chemical Formula 3,
L 4 is a bond; a substituted or unsubstituted C 6-60 arylene; or a substituted or unsubstituted C 2-60 heteroarylene containing at least one of 0, N, Si and S,
Ar 7 and Ar 8 are each independently a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heteroaryl containing at least one of 0, N, Si and S, and
Ar 9 is a substituted or unsubstituted C 2-60 heteroaryl containing at least one N.
8. The organic light emitting device of claim 7 ,
wherein the compound represented by the Chemical Formula 3 is any one selected from the group consisting of:
9. The organic light emitting device of claim 2 ,
wherein the 3-2 host is a compound represented by Chemical Formula 3:
in Chemical Formula 3,
L 4 is a bond; a substituted or unsubstituted C 6-60 arylene; or a substituted or unsubstituted C 2 -60 heteroarylene containing at least one of O, N, Si and S,
Ar 7 and Ar 8 are each independently a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heteroaryl containing at least one of O, N, Si and S, and
Ar 9 is a substituted or unsubstituted C 2-60 heteroaryl containing at least one N.
10. The organic light emitting device of claim 9 ,
wherein the compound represented by the Chemical Formula 3 is any one selected from the group consisting of:
11. The organic light emitting device of claim 1 ,
wherein the first light emitting layer further comprises a compound represented by Chemical Formula 4:
in Chemical Formula 4,
n1 is 1 or 2,
R 5 to R 8 are each independently hydrogen; a substituted or unsubstituted C 1-60 alkyl; or a substituted or unsubstituted C 6-60 aryl; provided that one or more of R 5 to R 8 are a branched alkyl containing 4 or more carbons, and
X—Y is an auxiliary ligand.
12. The organic light emitting device of claim 1 ,
wherein the second light emitting layer further comprises a compound represented by Chemical Formula 5:
in Chemical Formula 5,
n2 is 1 or 2,
a is an integer of 0 to 4, and
Ar 10 and Ar 11 are each independently a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heteroaryl containing at least one of O, N, Si and S.
13. The organic light emitting device of claim 2 ,
wherein the third light emitting layer further comprises a compound represented by Chemical Formula 6:
in Chemical Formula 6,
n3 is 1 or 2, and
R 8 to R 11 are each independently hydrogen; deuterium; halogen; nitrile; nitro; amino; a substituted or unsubstituted C 1 -60 alkyl; a substituted or unsubstituted C 3-60 cycloalkyl; a substituted or unsubstituted C 2-60 alkenyl; a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heterocyclic group containing at least one of O, N, Si and S.