IP Library Granted Patent US 11,223,017
Granted Patent B2
US 11,223,017 · App. 15/744,508 · Granted Jan 11, 2022

Organic light emitting device

Inventors: Tae Yoon Park (Daejeon, KR); Sang Young Jeon (Daejeon, KR); Min Seung Chun (Daejeon, KR); Seong Mi Cho (Daejeon, KR); Dong Hoon Lee (Daejeon, KR)
Assignee: LG CHEM, LTD.
H01L51/006C07C211/54C07C211/61C07D209/82C07D209/86C07D251/24C07D307/91C07D403/04C07D403/10C07D405/14C09K11/06H01L51/00H01L51/0052H01L51/0058H01L51/0061H01L51/0067H01L51/0072H01L51/0073H01L51/0085H01L51/50H01L51/504H01L51/5008C07C2603/18C07C2603/97C09K2211/1007C09K2211/1011C09K2211/1014C09K2211/1018C09K2211/1029C09K2211/1033C09K2211/185H01L51/0056H01L51/5016H01L51/5056H01L51/5072H01L2251/5384
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Quick Facts
Patent No.
US 11,223,017
App. No.
15/744,508
Granted
Jan 11, 2022
Kind
B2
Abstract

The present disclosure provides an organic light emitting device having improved driving voltage, efficiency and life time.

Claims (68)

1. An organic light emitting device comprising:

a first electrode;

a hole transport layer;

a first light emitting layer;

a second light emitting layer;

a third light emitting layer;

an electron transport layer; and

a second electrode,

wherein the first light emitting layer comprises a 1-1 host and a 1-2 host,

the second light emitting layer comprises a 2-1 host and a 2-2 host,

the hole transport layer comprises the same material as the 1-1 host,

the 1-1 host and the 2-2 host are different materials from each other,

wherein the third light emitting layer is disposed between the second light emitting layer and the electron transport layer, and comprises a 3-1 host and a 3-2 host,

the 1-2 host, the 2-1 host and the 3-1 host are the same materials, and

wherein the 1-2 host is a compound represented by Chemical Formula 2:

in Chemical Formula 2,

Ar 5 and Ar 6 are each independently a substituted or unsubstituted C 6-60 aryl.

2. The organic light emitting device of claim 1 ,

wherein the 1-1 host is a compound represented by Chemical Formula 1:

in Chemical Formula 1,

R 1 and R 2 are each independently hydrogen; deuterium; halogen; nitrile; nitro; amino; a substituted or unsubstituted C 1 -60 alkyl; a substituted or unsubstituted C 3-60 cycloalkyl; a substituted or unsubstituted C 2-60 alkenyl; a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heterocyclic group containing at least one of 0, N, Si and S,

L 1 and L 2 are each independently a bond, or a substituted or unsubstituted C 6-60 arylene, and

Ar 1 and Ar 2 are each independently a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2 -60 heteroaryl containing at least one of 0, N, Si and S.

3. The organic light emitting device of claim 2 ,

wherein the compound represented by the Chemical Formula 1 is any one selected from the group consisting of:

4. The organic light emitting device of claim 1 ,

wherein the 1-1 host is a compound represented by Chemical Formula 1′:

in Chemical Formula 1′,

R 3 and R 4 are each independently hydrogen; deuterium; halogen; nitrile; nitro; amino; a substituted or unsubstituted C 1 -60 alkyl; a substituted or unsubstituted C 3-60 cycloalkyl; a substituted or unsubstituted C 2-60 alkenyl; a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heterocyclic group containing at least one of 0, N, Si and S,

L 3 is a bond, or a substituted or unsubstituted C 6 -60 arylene, and

Ar 3 and Ar 4 are each independently a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2 -60 heteroaryl containing at least one of 0, N, Si and S.

5. The organic light emitting device of claim 4 ,

wherein the compound represented by the Chemical Formula 1′ is a following compound:

6. The organic light emitting device of claim 1 ,

wherein the compound represented by the Chemical Formula 2 is any one selected from the group consisting of:

7. The organic light emitting device of claim 1 ,

wherein the 2-2 host is a compound represented by Chemical Formula 3:

in Chemical Formula 3,

L 4 is a bond; a substituted or unsubstituted C 6-60 arylene; or a substituted or unsubstituted C 2-60 heteroarylene containing at least one of 0, N, Si and S,

Ar 7 and Ar 8 are each independently a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heteroaryl containing at least one of 0, N, Si and S, and

Ar 9 is a substituted or unsubstituted C 2-60 heteroaryl containing at least one N.

8. The organic light emitting device of claim 7 ,

wherein the compound represented by the Chemical Formula 3 is any one selected from the group consisting of:

9. The organic light emitting device of claim 2 ,

wherein the 3-2 host is a compound represented by Chemical Formula 3:

in Chemical Formula 3,

L 4 is a bond; a substituted or unsubstituted C 6-60 arylene; or a substituted or unsubstituted C 2 -60 heteroarylene containing at least one of O, N, Si and S,

Ar 7 and Ar 8 are each independently a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heteroaryl containing at least one of O, N, Si and S, and

Ar 9 is a substituted or unsubstituted C 2-60 heteroaryl containing at least one N.

10. The organic light emitting device of claim 9 ,

wherein the compound represented by the Chemical Formula 3 is any one selected from the group consisting of:

11. The organic light emitting device of claim 1 ,

wherein the first light emitting layer further comprises a compound represented by Chemical Formula 4:

in Chemical Formula 4,

n1 is 1 or 2,

R 5 to R 8 are each independently hydrogen; a substituted or unsubstituted C 1-60 alkyl; or a substituted or unsubstituted C 6-60 aryl; provided that one or more of R 5 to R 8 are a branched alkyl containing 4 or more carbons, and

X—Y is an auxiliary ligand.

12. The organic light emitting device of claim 1 ,

wherein the second light emitting layer further comprises a compound represented by Chemical Formula 5:

in Chemical Formula 5,

n2 is 1 or 2,

a is an integer of 0 to 4, and

Ar 10 and Ar 11 are each independently a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heteroaryl containing at least one of O, N, Si and S.

13. The organic light emitting device of claim 2 ,

wherein the third light emitting layer further comprises a compound represented by Chemical Formula 6:

in Chemical Formula 6,

n3 is 1 or 2, and

R 8 to R 11 are each independently hydrogen; deuterium; halogen; nitrile; nitro; amino; a substituted or unsubstituted C 1 -60 alkyl; a substituted or unsubstituted C 3-60 cycloalkyl; a substituted or unsubstituted C 2-60 alkenyl; a substituted or unsubstituted C 6-60 aryl; or a substituted or unsubstituted C 2-60 heterocyclic group containing at least one of O, N, Si and S.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 12, 2018
From: PARK, TAE YOON; JEON, SANG YOUNG; CHUN, MIN SEUNG; CHO, SEONG MI; LEE, DONG HOON
To: LG CHEM, LTD.
Reel/Frame 044610/0900 →
Priority Claims (1)
KR 10-2016-0114284 · Sep 6, 2016 · national
Continuity (1)
Related Publication 20190006590A1 · Jan 3, 2019