Process of making a water soluble pouch

1. A process of making a water soluble pouch comprising the steps of:

providing a first mold comprising a first cavity, wherein said first cavity comprises a first porous face;

providing a water soluble first web carried on said first mold;

forming said water soluble first web to form a compartment by applying a first pressure difference across said water soluble first web with said water soluble first web at a first maximum temperature and subsequently applying a second pressure difference across said water soluble first web, wherein said second pressure difference is greater than or equal to said first pressure difference;

placing a substrate treatment agent on said water soluble first web;

providing a water soluble second web; and

sealing said first web and said second web to one another to form an enclosed pouch having a chamber containing said substrate treatment agent;

wherein said water soluble first web is at a second maximum temperature when said second pressure difference is applied;

wherein said second maximum temperature is greater than said first maximum temperature; and

wherein said first maximum temperature is from about 40° C. to about 100° C.

2. The process of making a water soluble pouch according to claim 1 , wherein said second maximum temperature is from about 100° C. to about 120° C.

3. The process of making a water soluble pouch according to claim 1 , wherein said first pressure difference is applied by applying a first negative gage pressure to said first porous face and wherein said second pressure difference is applied by applying a second negative gage pressure to said first porous face, wherein said second negative gage pressure is less than or equal to said first negative gage pressure.

4. The process of making a water soluble pouch according to claim 3 , wherein the step of forming said water soluble first web to form said compartment is performed by thermoforming said water soluble first web to form said compartment.

5. The process of making a water soluble pouch according to claim 4 , wherein the step of placing said substrate treatment agent on said water soluble first web is performed by placing said substrate treatment agent in said compartment.

6. The process of making a water soluble pouch according to claim 3 , wherein said first negative gage pressure is from about 10 mbar to about 90 mbar below atmospheric pressure.

7. The process of making a water soluble pouch according to claim 3 , wherein said second negative gage pressure is from about 150 mbar to about 260 mbar below atmospheric pressure.

8. The process of making a water soluble pouch according to claim 3 , wherein said first cavity has a surface area of from about 20 cm 2 to about 80 cm 2 .

9. The process of making a water soluble pouch according to claim 3 , wherein said first negative gage pressure and said second negative gage pressure are individually applied for from about 1 s to about 10 s.

10. The process of making a water soluble pouch according to claim 3 , wherein said first web is provided at a thickness of from about 20 μm to about 150 μm.

11. The process of making a water soluble pouch according to claim 3 , wherein said substrate treatment agent is a liquid, powder, or gel and said substrate treatment agent is selected from the group consisting of laundry detergent, laundry additive, dishwashing detergent, hard surface cleaner, and dishwashing additive.

12. The process of making a water soluble pouch according to claim 3 , further comprising the steps of:

providing a second mold comprising a second cavity, wherein said second cavity comprises a second porous face;

providing a water soluble third web carried on said second mold;

forming said water soluble third web to form a second compartment by applying a third pressure difference across said water soluble third web;

placing a second substrate treatment agent on said water soluble third web;

sealing said second web to said water soluble third web to form an enclosed pouch having a second chamber containing said second substrate treatment agent.

13. The process of making a water soluble pouch according to claim 12 , wherein said third pressure difference is applied by applying a third negative gage pressure to said second porous face.

14. The process of making a water soluble pouch according to claim 13 , wherein said step of forming said second compartment by applying said third pressure difference across said water soluble third web is performed by thermoforming with said water soluble third web at a temperature of from about 100° C. to about 135° C.

15. The process of making a water soluble pouch according to claim 3 , wherein said pouch comprises a plurality of printed characters or an aversive agent having a foul taste.

16. A process of making a water soluble pouch comprising the steps of:

providing a first mold comprising a first cavity, wherein said first cavity comprises a first porous face;

providing a water soluble first web carried on said first mold;

forming said water soluble first web to form a compartment by applying a first pressure difference across said water soluble first web with said water soluble first web at a first maximum temperature and subsequently applying a second pressure difference across said water soluble first web, wherein said second pressure difference is greater than or equal to said first pressure difference;

placing a substrate treatment agent on said water soluble first web;

providing a water soluble second web; and

sealing said first web and said second web to one another to form an enclosed pouch having a chamber containing said substrate treatment agent;

wherein said water soluble first web is at a second maximum temperature when said second pressure difference is applied and wherein said second maximum temperature is greater than said first maximum temperature;

wherein the first maximum temperature is from about 40° C. to about 100° C. and said second maximum temperature is from about 100° C. to about 120° C.;

wherein said first pressure difference is applied by applying a first negative gage pressure to said first porous face and wherein said second pressure difference is applied by applying a second negative gage pressure to said first porous face, wherein said second negative gage pressure is less than or equal to said first negative gage pressure; and

wherein the step of forming said water soluble first web to form said compartment is performed by thermoforming said water soluble first web to form said compartment.

17. The process of making a water soluble pouch according to claim 16 , further comprising the steps of:

providing a second mold comprising a second cavity, wherein said second cavity comprises a second porous face;

providing a water soluble third web carried on said second mold;

forming said water soluble third web to form a second compartment by applying a third pressure difference across said water soluble third web;

placing a second substrate treatment agent on said water soluble third web;

sealing said second web to said water soluble third web to form an enclosed pouch having a second chamber containing said second substrate treatment agent.